百科

(1S,3R,7R,8S,11S)-9-<(benzyloxy)carbonyl>-11-chloro-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

(1S,3R,7R,8S,11S)-9-<(benzyloxy)carbonyl>-11-chloro-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

CAS号：98944-19-5

英文名：(1S,3R,7R,8S,11S)-9-<(benzyloxy)carbonyl>-11-chloro-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

分子式：C17H20ClNO5

分子量：353.797

合成路线

3-azido-3-deoxy-1,2-O-isopropylidene-5,6-di-O-mesyl-α-D-glucofuranose

3-azido-3-deoxy-1,2-O-isopropylidene-5,6-di-O-mesyl-α-D-glucofuranose

(1S,3R,7R,8S,11S)-9-<(benzyloxy)carbonyl>-11-chloro-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

(1S,3R,7R,8S,11S)-9-<(benzyloxy)carbonyl>-11-chloro-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

(1S,3R,7R,8S,11R)-11-<(methylsulfonyl)oxy>-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

(1S,3R,7R,8S,11R)-11-<(methylsulfonyl)oxy>-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

(1S,3R,7R,8S,11S)-9-<(benzyloxy)carbonyl>-11-chloro-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

(1S,3R,7R,8S,11S)-9-<(benzyloxy)carbonyl>-11-chloro-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

(1S,3R,7R,8S,11R)-9-<(benzyloxy)carbonyl>-11-<(methylsulfonyl)oxy>-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

(1S,3R,7R,8S,11R)-9-<(benzyloxy)carbonyl>-11-<(methylsulfonyl)oxy>-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

(1S,3R,7R,8S,11S)-9-<(benzyloxy)carbonyl>-11-chloro-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

(1S,3R,7R,8S,11S)-9-<(benzyloxy)carbonyl>-11-chloro-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

上游原料

3-azido-3-deoxy-1,2-O-isopropylidene-5,6-di-O-mesyl-α-D-glucofuranose (1S,3R,7R,8S,11R)-9-<(benzyloxy)carbonyl>-11-<(methylsulfonyl)oxy>-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane (1S,3R,7R,8S,11R)-11-<(methylsulfonyl)oxy>-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane

下游产品

(1R,3S,4R,5S)-5-<(benzyloxy)carbonyl>-3-methoxy-2-oxa-6-azabicyclo<3.3.0>octan-4-ol (1R,3R,4R,5S)-5-<(benzyloxy)carbonyl>-3-methoxy-2-oxa-6-azabicyclo<3.3.0>octan-4-ol (1R,3R,7R,8S)-9-<(benzyloxy)carbonyl>-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.03,7>undecane (1R,3R,4R,5S)-4-(benzyloxy)-5-<(benzyloxy)carbonyl>-3-methoxy-2-oxa-6-azabicyclo<3.3.0>octane (1R,3S,4R,5S)-4-(benzyloxy)-5-<(benzyloxy)carbonyl>-3-methoxy-2-oxa-6-azabicyclo<3.3.0>octane