十羰基二铼

十羰基二铼

CAS号：14285-68-8

英文名：RHENIUM CARBONYL

分子式

C10O10Re2

熔点

170°C (dec.)(lit.)

密度

2,87 g/cm3

分子量

652.515

沸点

303.3ºC at 760mmHg

溶解度

信号词

Warning

危险品标志

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化合物简介

Dirhenium decacarbonyl is the inorganic compound with the chemical formula Re2(CO)10 . Commercially available, it is used as a starting point for the synthesis of many rhenium carbonyl complexes. It was first reported in 1941 by Walter Hieber, who prepared it by reductive carbonylation of rhenium. The compound consists of a pair of square pyramidal Re(CO)5 units joined via a Re-Re bond, which produces a homoleptic carbonyl complex.

基本信息

中文名称

十羰基二铼

英文名称

RHENIUM CARBONYL

中文别名

羰化錸、羰基铼

英文别名

decacarbonyldirhenium (Re-Re)、dirhenium dodecacarbonyl、[Re2(CO)10]、DODECACARBONYLDIRHENIUM、Decacarbonyldirhenium、Dirhenium decacarbonyl、DECACARBONYLDIRHENIUM、decacarbonyl dirhenium(0)、RHENIUM DECACARBONYL、Rheniumcarbonyl、Rhenium,decacarbonyldi、Rhenium carbonyl

CAS号

14285-68-8

分子式

C10O10Re2

分子量

652.515

精确质量

653.861

PSA

0.0

LOGP

-2.08

编号系统

EINECS号

238-202-8

PubChem号

24854726

MDL号

MFCD00011198

物化性质

密度

2,87 g/cm3

沸点

303.3ºC at 760mmHg

熔点

170°C (dec.)(lit.)

闪点

130.7ºC

蒸汽压

0.000936mmHg at 25°C

安全信息

安全说明

S36

WGK Germany

3

危险类别码

R20

危险品运输编码

UN 3466 6.1/PG 3

危险类别

6.1

包装等级

III

危险品标志

Xn

危险性描述

H332

危险标志

GHS07

信号词

Warning

合成路线

共找到32条合成路线 >

methanone,rhenium

methanone,rhenium

十羰基二铼

十羰基二铼

上游原料

共找到53个上游原料 >

tris(1,10-phenanthroline)cobalt(III) perchlorate

tris(1,10-phenanthroline)cobalt(III) perchlorate

H2RhRe2Cp*(CO)9

H2RhRe2Cp*(CO)9

(3-η1-1-tert-butyl-2-deuteriocyclopropenyl)pentacarbonylrhenium

(3-η1-1-tert-butyl-2-deuteriocyclopropenyl)pentacarbonylrhenium

羰基镁

2-methylisoquinolin-2-ium trifluoromethanesulfonate

2-methylisoquinolin-2-ium trifluoromethanesulfonate

(η5-C5H5)Fe(CO)2(CCl3)

(η5-C5H5)Fe(CO)2(CCl3)

下游产品

共找到17个下游商品 >

{Cu(Me2pyo{14}trieneN4)}(+)

{Cu(Me2pyo{14}trieneN4)}(+)

methanone,rhenium

methanone,rhenium

三羰基五甲基环戊二烯基铼

三羰基五甲基环戊二烯基铼

Re2(μ-I)2(CO)8

Re2(μ-I)2(CO)8

五羰基溴铼(I)

五羰基溴铼(I)

(OC)4Re=Re(CO)5

(OC)4Re=Re(CO)5

上游原料

tris(1,10-phenanthroline)cobalt(III) perchlorate H2RhRe2Cp*(CO)9 (3-η1-1-tert-butyl-2-deuteriocyclopropenyl)pentacarbonylrhenium 羰基镁 2-methylisoquinolin-2-ium trifluoromethanesulfonate (η5-C5H5)Fe(CO)2(CCl3) μ-1.2-propanediylbis(pentacarbonylrhenium) (OC)5ReRe(CO)3(o-phenanthroline) carbon monoxide (CO)4Re{trans-μ-HCC(CO2Me)}Re(CO)5 三氟氯乙烯甲苯 decacarbonylmanganeserhenium 亚硝基叔丁烷 pentacarbonylrhenium(1-) Methyl rhenium pentacarbonyl 五羰基溴化锰(I) sodium[rhenium(pentacarbonate)] 五羰基氯铼(I) 锌 nonacarbonyl(triphenylphosphine)dirhenium pentacarbonylhydro-Rhenium [bis(triphenylphospine)nitrogen(1+)][Re(CO)5] Mn(CO)5Re(CO)3(i-Pr-pyridine-2-carbaldehyde) carbanide,tetrakis(oxomethylidene)osmium Re(CO)5Mn(CO)3(4,4'-dimethyl-2,2'-bipyridine) Re2(CO)9(η1-(S)-3,5-dimethylbenzothiophene) cobalt(III) tris(1,10-phenanthroline) hexafluorophosphate (OC)4Re=Re(CO)5 苯 bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) N,N-diethyl-N'-p-tolyl-thiourea ((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylrhenium methanone,rhenium 五羰基溴铼(I) 高铼酸钾 hexacarbonylmanganese(I) tetrafluoroborate 2-(三氟乙酰基)吡咯 bis(μ3-carbondioxide-C,O:O')-bis(pentacarbonylrhenium)bis(tetracarbonylrhenium) [Re2(CO)9(acetonitrile)] [Re2(H2O)(CO)9]

下游产品

{Cu(Me2pyo{14}trieneN4)}(+) methanone,rhenium 三羰基五甲基环戊二烯基铼 Re2(μ-I)2(CO)8 五羰基溴铼(I) (OC)4Re=Re(CO)5 五羰基氯铼(I) eq-Re2(CO)9(carbon tetrachloride) tris(2,2'-bipyridyl)cobalt(II) 乙基苯三羰基铬 cis-[CF2=CF(CO)Re(CO)4Br]Na pentacarbonylrhenium(1-) 铼五羰基碘化物 [(CO)3Re(μ-Cl)3Re(CO)3](1-)