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伪单胞菌酸C

伪单胞菌酸C

CAS号：71980-98-8

英文名：9-[(E)-4-[(2S,3R,4R,5S)-3,4-dihydroxy-5-[(E,4R,5S)-5-hydroxy-4-methylhex-2-enyl]oxan-2-yl]-3-methylbut-2-enoyl]oxynonanoic acid

分子式

C26H44O8

熔点

密度

1.125g/cm3

分子量

484.623

沸点

656.193ºC at 760 mmHg

溶解度

信号词

危险品标志

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化合物简介

Pseudomonic Acid C, is the analogue of Pseudomonic Acid D which is an antibiotic isolated from Pseudomonas fluorescens.

基本信息

中文名称

伪单胞菌酸C

英文名称

9-[(E)-4-[(2S,3R,4R,5S)-3,4-dihydroxy-5-[(E,4R,5S)-5-hydroxy-4-methylhex-2-enyl]oxan-2-yl]-3-methylbut-2-enoyl]oxynonanoic acid

中文别名

英文别名

Mupirocin calcium impurity B [EP]、(+)-pseudomonic acid C、9-(((2E)-4-((2S,3R,4R,5S)-3,4-Dihydroxy-5-((2E,4R,5S)-5-hydroxy-4-methylhex-2-enyl)tetrahydro-2H-pyran-2-yl)-3-methylbut-2-enoyl)oxy)nonanoic acid、UNII-O6M926DF2R、L-TALO-NON-2-enonic acid,5,9-anhydro-2,3,4,8-tetradeoxy-8-(5-hydroxy-4-methyl-2-hexen-1-yl)-3-methyl-,8-carboxyoctyl ester,(2E)

CAS号

71980-98-8

分子式

C26H44O8

分子量

484.623

精确质量

484.304

PSA

133.52

LOGP

3.3813

物化性质

密度

1.125g/cm3

沸点

656.193ºC at 760 mmHg

闪点

210.281ºC

折射率

1.516

合成路线

[2S-[2α(E),3β,4β,5α(2E,4S*,5R*)]]-9-[[3-methyl-1-oxo-4-[tetrahydro-3,4-dihydroxy-5-(5-hydroxy-4-methyl-2-hexenyl)-2H-pyran-2-yl]-2-butenyl]oxy]nonanoic acid methyl ester

[2S-[2α(E),3β,4β,5α(2E,4S*,5R*)]]-9-[[3-methyl-1-oxo-4-[tetrahydro-3,4-dihydroxy-5-(5-hydroxy-4-methyl-2-hexenyl)-2H-pyran-2-yl]-2-butenyl]oxy]nonanoic acid methyl ester

伪单胞菌酸C

伪单胞菌酸C

上游原料

共找到72个上游原料 >

(E)-4-((2S,3S,4R,5S)-3,4-bis(benzyloxy)-5-((4R,5S,E)-5-((benzyloxy)methoxy)-4-methylhex-2-en-1-yl)tetrahydro-2H-pyran-2-yl)-3-methylbut-2-enal

(E)-4-((2S,3S,4R,5S)-3,4-bis(benzyloxy)-5-((4R,5S,E)-5-((benzyloxy)methoxy)-4-methylhex-2-en-1-yl)tetrahydro-2H-pyran-2-yl)-3-methylbut-2-enal

(2R,3R,E)-2-((tert-butyldimethylsilyl)oxy)-6-((3aS,4S,7S,7aR)-4-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-7-yl)-3-methylhex-4-en-1-ol

(2R,3R,E)-2-((tert-butyldimethylsilyl)oxy)-6-((3aS,4S,7S,7aR)-4-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-7-yl)-3-methylhex-4-en-1-ol

(3aS-(3aα,4α,7aα,7α(3E,2S*)))-tetrahydro-2,2-dimethyl-4-(2-(((1,1-dimethylethyl)diphenylsilyl)oxy)ethyl)-α-(1-propenyl)-4H-1,3-dioxolo(4,5-c)pyran-7-ethanol

(3aS-(3aα,4α,7aα,7α(3E,2S*)))-tetrahydro-2,2-dimethyl-4-(2-(((1,1-dimethylethyl)diphenylsilyl)oxy)ethyl)-α-(1-propenyl)-4H-1,3-dioxolo(4,5-c)pyran-7-ethanol

[2S-[2α(E),3β,4β,5α(2E,4S*,5R*)]]-9-[[3-methyl-1-oxo-4-[tetrahydro-3,4-dihydroxy-5-(5-hydroxy-4-methyl-2-hexenyl)-2H-pyran-2-yl]-2-butenyl]oxy]nonanoic acid methyl ester

[2S-[2α(E),3β,4β,5α(2E,4S*,5R*)]]-9-[[3-methyl-1-oxo-4-[tetrahydro-3,4-dihydroxy-5-(5-hydroxy-4-methyl-2-hexenyl)-2H-pyran-2-yl]-2-butenyl]oxy]nonanoic acid methyl ester

(3aR-(3aα,4α,7α,7aα))-tetrahydro-N,N,2,2-tetramethyl-4-(2-(((1,1-dimethylethyl)diphenylsilyl)oxy)ethyl)-4H-1,3-dioxolo(4,5-c)pyran-7-acetamide

(3aR-(3aα,4α,7α,7aα))-tetrahydro-N,N,2,2-tetramethyl-4-(2-(((1,1-dimethylethyl)diphenylsilyl)oxy)ethyl)-4H-1,3-dioxolo(4,5-c)pyran-7-acetamide

2-((3S,4R,5R,6S)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4,5-dihydroxytetrahydro-2H-pyran-3-yl)-N,N-dimethylacetamide

2-((3S,4R,5R,6S)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4,5-dihydroxytetrahydro-2H-pyran-3-yl)-N,N-dimethylacetamide

上游原料

(E)-4-((2S,3S,4R,5S)-3,4-bis(benzyloxy)-5-((4R,5S,E)-5-((benzyloxy)methoxy)-4-methylhex-2-en-1-yl)tetrahydro-2H-pyran-2-yl)-3-methylbut-2-enal (2R,3R,E)-2-((tert-butyldimethylsilyl)oxy)-6-((3aS,4S,7S,7aR)-4-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-7-yl)-3-methylhex-4-en-1-ol (3aS-(3aα,4α,7aα,7α(3E,2S*)))-tetrahydro-2,2-dimethyl-4-(2-(((1,1-dimethylethyl)diphenylsilyl)oxy)ethyl)-α-(1-propenyl)-4H-1,3-dioxolo(4,5-c)pyran-7-ethanol [2S-[2α(E),3β,4β,5α(2E,4S*,5R*)]]-9-[[3-methyl-1-oxo-4-[tetrahydro-3,4-dihydroxy-5-(5-hydroxy-4-methyl-2-hexenyl)-2H-pyran-2-yl]-2-butenyl]oxy]nonanoic acid methyl ester (3aR-(3aα,4α,7α,7aα))-tetrahydro-N,N,2,2-tetramethyl-4-(2-(((1,1-dimethylethyl)diphenylsilyl)oxy)ethyl)-4H-1,3-dioxolo(4,5-c)pyran-7-acetamide 2-((3S,4R,5R,6S)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4,5-dihydroxytetrahydro-2H-pyran-3-yl)-N,N-dimethylacetamide methyl 9-(2-diethoxyphosphorylacetyl)oxynonanoate 2,7-dioxabicyclo[4.3.0]non-4-en-8-one 2-((3S,4R,5R,6S)-4,5-bis(benzyloxy)-6-(((tert-butyldiphenylsilyl)oxy)methyl)tetrahydro-2H-pyran-3-yl)acetaldehyde 9-羟基正壬酸甲酯 L-(+)-阿拉伯糖 (2S,3S,4R,5S)-3,4-bis(benzyloxy)-5-((4R,5S,E)-5-((benzyloxy)methoxy)-4-methylhex-2-en-1-yl)-2-((E)-2-methyl-4-((tetrahydro-2H-pyran-2-yl)oxy)but-2-en-1-yl)tetrahydro-2H-pyran tert-butyl(((2S,3S)-4-iodo-3-methylbutan-2-yl)oxy)dimethylsilane 2-((3aS,4S,7S,7aR)-7-((4R,5S,E)-5-((tert-butyldimethylsilyl)oxy)-4-methylhex-2-en-1-yl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-4-yl)acetaldehyde 2-((3aR,7S,7aR)-4-(benzyloxy)-2,2-dimethyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-7-yl)ethan-1-ol (2S-cis)-5,6-dihydro-N,N-dimethyl-2-[2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]ethyl]-2H-pyran-5-acetamide (3aS,7R,7aR)-7-iodohexahydro-2H-furo[3,2-b]pyran-2-one (R)-1-{(3aS,4S,7S,7aR)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl}-pent-3-yn-2-ol (((2S,3R,4R,5S)-3,4-bis(benzyloxy)-5-(3-methylbut-2-en-1-yl)tetrahydro-2H-pyran-2-yl)methoxy)(tert-butyl)diphenylsilane ethyl (2S,3S)-3-hydroxy-2-methylbutanoate (2R)-S-phenyl 2-((1R,2R)-2-(benzyloxy)-2-(2,2-dimethyl-1,3-dioxolan-4-yl)-1-hydroxyethyl)-5-methylhex-4-enethioate (3aS)-(3aα,4α,7aα,7α))-1-(tetrahydro-2,2-dimethyl-4-(2-(((1,1-dimethylethyl)diphenylsilyl)oxy)ethyl)-1,3-dioxolo(4,5-c)pyran-7-yl)-3-pentyn-2-one (2R,3R,4R,5S)-3,4-bis(benzyloxy)-5-((4R,5S,E)-5-((benzyloxy)methoxy)-4-methylhex-2-en-1-yl)tetrahydro-2H-pyran-2-carbaldehyde D-核糖 (2S,3R,4R,5S)-3-(benzyloxy)-2-(hydroxymethyl)-5-(3-methylbut-2-en-1-yl)tetrahydro-2H-pyran-4-ol (S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-methyl-1-butanol 4-methylbenzenesulfonate <3aS-<3aα,4α,7aα,7α(3E,2R*)>>-6-<tetrahydro-2,2-dimethyl-4-<2-<<(1,1-dimethylethyl)diphenylsilyl>oxy>ethyl>-4H-1,3-dioxolo<4,5-c>pyran-7-yl>-2-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-3-methyl-4-hexenoic acid methyl ester <3aS-<3aα,4α,7aα,7α(3E,2S*)>>-tetrahydro-2,2-dimethyl-4-<2-<<(1,1-dimethylethyl)diphenylsilyl>oxy>ethyl>-α(1-propenyl)-4H-1,3-dioxolo<4,5-c>pyran-7-ethanol<<(1,1-dimethylethyl)dimethylsilyl>oxy>acetate <3aR-(3aα,4α,7α,7aα)>-tetrahydro-2,2-dimethyl-4-<2-<<(1,1-dimethylethyl)diphenylsilyl>oxy>ethyl>-4H-1,3-dioxolo<4,5-c>pyran-7-acetaldehyde (5S-cis)-5,6-dihydro-6-[2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]ethyl]-2H-pyran-5-ol (E)-4-((2S,3S,4R,5S)-3,4-bis(benzyloxy)-5-((4R,5S,E)-5-((benzyloxy)methoxy)-4-methylhex-2-en-1-yl)tetrahydro-2H-pyran-2-yl)-3-methylbut-2-en-1-ol 3,5-hexadienoic acid chloride (2R,3R,4R,5S)-3,4-bis(benzyloxy)-5-((4R,5S,E)-5-((benzyloxy)methoxy)-4-methylhex-2-en-1-yl)-2-((1S,E)-1-bromo-2-methyl-4-((tetrahydro-2H-pyran-2-yl)oxy)but-2-en-1-yl)tetrahydro-2H-pyran (2S,3S)-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-methyl-1-(phenylsulfonyl)butane (3aR,7S,7aR)-7-allyl-4-(benzyloxy)-2,2-dimethyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran tert-butyl(2-((3aS,4S,7S,7aR)-7-((4R,5R,E)-5-((tert-butyldimethylsilyl)oxy)-6-iodo-4-methylhex-2-en-1-yl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-4-yl)ethoxy)diphenylsilane 1-((3aS,4S,7S,7aR)-7-((4R,5S,E)-5-((tert-butyldimethylsilyl)oxy)-4-methylhex-2-en-1-yl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-4-yl)propan-2-ol O-((3aR,7S,7aR)-4-(benzyloxy)-2,2-dimethyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-7-yl) O-phenyl carbonothioate 2-((3aS,4S,7S,7aR)-7-((4R,5S,E)-5-((tert-butyldimethylsilyl)oxy)-4-methylhex-2-en-1-yl)-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-4-yl)ethanol (S-(R*,S*))-3-(((1,1-dimethylethyl)dimethylsilyl)oxy)-2-methylbutanoic acid ethyl ester 1,5-Anhydro-D-arabinitol (1S,E)-1-((2S,3R,4R,5S)-3,4-bis(benzyloxy)-5-((4R,5S,E)-5-((benzyloxy)methoxy)-4-methylhex-2-en-1-yl)tetrahydro-2H-pyran-2-yl)-2-methyl-4-((tetrahydro-2H-pyran-2-yl)oxy)but-2-en-1-ol (R,E)-N-(1-phenylethyl)hexa-3,5-dienamide (2S,3R,4R)-4-(benzyloxy)-4-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-(3-methylbut-2-en-1-yl)butane-1,3-diol