百科

去氢木香内酯

去氢木香内酯

CAS号：477-43-0

英文名：dehydrocostus lactone

分子式：C15H18O2

分子量：230.302

合成路线

[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-acetic acid

[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-acetic acid

去氢木香内酯

去氢木香内酯

(S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-4-methylsulfanyl-butyric acid

(S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-4-methylsulfanyl-butyric acid

去氢木香内酯

去氢木香内酯

(S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-3-hydroxy-propionic acid

(S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-3-hydroxy-propionic acid

去氢木香内酯

去氢木香内酯

(S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-4-methyl-pentanoic acid

(S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-4-methyl-pentanoic acid

去氢木香内酯

去氢木香内酯

(S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-5-guanidino-pentanoic acid

(S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-5-guanidino-pentanoic acid

去氢木香内酯

去氢木香内酯

1-oxo-eudesm-4(15)-en-5α,6β,7α,11βH-12,6-olide

1-oxo-eudesm-4(15)-en-5α,6β,7α,11βH-12,6-olide

去氢木香内酯

去氢木香内酯

(R)-2-Amino-3-((3S,3aS,6aR,9aR,9bS)-6,9-dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethylsulfanyl)-propionic acid

(R)-2-Amino-3-((3S,3aS,6aR,9aR,9bS)-6,9-dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethylsulfanyl)-propionic acid

去氢木香内酯

去氢木香内酯

(S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-3-phenyl-propionic acid

(S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-3-phenyl-propionic acid

去氢木香内酯

去氢木香内酯

上游原料

(S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-4-methylsulfanyl-butyric acid 1-oxo-eudesm-4(15)-en-5α,6β,7α,11βH-12,6-olide (S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-3-hydroxy-propionic acid (R)-2-Amino-3-((3S,3aS,6aR,9aR,9bS)-6,9-dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethylsulfanyl)-propionic acid (S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-5-guanidino-pentanoic acid [((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-acetic acid (S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-3-phenyl-propionic acid (S)-2-[((3R,3aS,6aR,9aR,9bS)-6,9-Dimethylene-2-oxo-dodecahydro-azuleno[4,5-b]furan-3-ylmethyl)-amino]-4-methyl-pentanoic acid

下游产品

(11S,16R)-11-hydroxy-13-(1'-hydroxyethyl)mokkolactone (11R,16R)-11-hydroxy-13-(1'-hydroxyethyl)mokkolactone (3aS,6aR,8R,9aR,9bS)-3-Eth-(Z)-ylidene-8-hydroxy-6,9-dimethylene-decahydro-azuleno[4,5-b]furan-2-one (11S,16S)-11-hydroxy-13-(1'-(methylsulfonyloxy)ethyl)mokkolactone