(3R,3aR,6aS,8aR,11S,13aS,13bS,14S)-3,14-dihydroxy-4,4-dimethyl-10-methylenedecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromene-8,9(10H)-dione

(3R,3aR,6aS,8aR,11S,13aS,13bS,14S)-3,14-dihydroxy-4,4-dimethyl-10-methylenedecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromene-8,9(10H)-dione

CAS号：16763-48-7

英文名：(3R,3aR,6aS,8aR,11S,13aS,13bS,14S)-3,14-dihydroxy-4,4-dimethyl-10-methylenedecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromene-8,9(10H)-dione

分子式：C20H26O6

分子量：362.417

合成路线

ent-1α-O-acetyl-6β-hydroxy-7,14-isopropylidene ketal-15-oxo-7,20-epoxy-16-kaurene

ent-1α-O-acetyl-6β-hydroxy-7,14-isopropylidene ketal-15-oxo-7,20-epoxy-16-kaurene

(3R,3aR,6aS,8aR,11S,13aS,13bS,14S)-3,14-dihydroxy-4,4-dimethyl-10-methylenedecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromene-8,9(10H)-dione

(3R,3aR,6aS,8aR,11S,13aS,13bS,14S)-3,14-dihydroxy-4,4-dimethyl-10-methylenedecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromene-8,9(10H)-dione

上游原料

ent-1α-O-acetyl-6β-hydroxy-7,14-isopropylidene ketal-15-oxo-7,20-epoxy-16-kaurene

下游产品

(3aR,6aS,8aR,11S,13aS,13bS,14R)-4,4-dimethyl-10-methylene-3,8,9-trioxododecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromen-14-yl 2-chlorobenzoate (3aR,6aS,8aR,11S,13aS,13bS,14R)-4,4-dimethyl-10-methylene-3,8,9-trioxododecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromen-14-yl tetrahydrofuran-2-carboxylate (3aR,6aS,8aR,11S,13aS,13bS,14R)-4,4-dimethyl-10-methylene-3,8,9-trioxododecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromen-14-yl 3-phenylpropanoate (3aR,6aS,8aR,11S,13aS,13bS,14R)-4,4-dimethyl-10-methylene-3,8,9-trioxododecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromen-14-yl propionate (3aR,6aS,8aR,11S,13aS,13bS,14R)-4,4-dimethyl-10-methylene-3,8,9-trioxododecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromen-14-yl 4-(trifluoromethyl)benzoate (3aR,6aS,8aR,11S,13aS,13bS,14R)-4,4-dimethyl-10-methylene-3,8,9-trioxododecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromen-14-yl 4-chlorobenzoate (3aR,6aS,8aR,11S,13aS,13bS,14R)-4,4-dimethyl-10-methylene-3,8,9-trioxododecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromen-14-yl 2-(naphthalen-1-yl)acetate (3aR,6aS,8aR,11S,13aS,13bS,14R)-4,4-dimethyl-10-methylene-3,8,9-trioxododecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromen-14-yl 2-(1H-indol-3-yl)acetate (3aR,6aS,8aR,11S,13aS,13bS,14R)-4,4-dimethyl-10-methylene-3,8,9-trioxododecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromen-14-yl quinoline-2-carboxylate (3aR,6aS,8aR,11S,13aS,13bS,14R)-4,4-dimethyl-10-methylene-3,8,9-trioxododecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromen-14-yl 4-methylbenzoate (3aR,6aS,8aR,11S,13aS,13bS,14R)-4,4-dimethyl-10-methylene-3,8,9-trioxododecahydro-1H,8H-8a,11-methanocyclohepta[c]furo[3,4-e]chromen-14-yl (E)-3-(4-fluorophenyl)acrylate