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硼化钙

硼化钙

CAS号:12007-99-7
英文名:CALCIUM BORIDE
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化合物简介
Calcium hexaboride (sometimes calcium boride) is a compound of calcium and boron with the chemical formula CaB6. It is an important material due to its high electrical conductivity, hardness, chemical stability, and melting point. It is a black, lustrous, chemically inert powder with a low density. It has the cubic structure typical for metal hexaborides, with octahedral units of 6 boron atoms combined with calcium atoms. CaB6 and lanthanum-doped CaB6 both show weak ferromagnetic properties, which is a remarkable fact because calcium and boron are neither magnetic, nor have inner 3d or 4f electronic shells, which are usually required for ferromagnetism.
基本信息
编号系统
物化性质
安全信息
生产方法及用途
生产方法
本品可从单质直接化合、化合物转化、电解等方法制得。
1.单质化合将金属钙片和计算量的无定形硼在石英管中于真空下加热,此时发出火光,反应迅速完成。
2.化合物转化B2O3和Ca热至暗红色生成CaB6;2.5g B2O3和2g CaC2于1625℃加热,CaCl2或CaF2和计算量的B混匀加热均得CaB6,卤素作为卤硼化合物挥发。
3.电解将CaO与B2O3和CaF2在1000℃下,用7.0V和20A电流,在石墨坩埚中电解。冷却后的块状物即为CaB6,依次用稀和浓HCl溶解杂质而分离得本品。