百科

5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde oxime

5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde oxime

CAS号：102487-55-8

英文名：5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde oxime

分子式：C18H35NO6Si

分子量：389.559

合成路线

2,3:5,6-Di-O-isopropylidene-4-O-(tert-butyldimethylsilyl)-aldehydo-D-glucose

2,3:5,6-Di-O-isopropylidene-4-O-(tert-butyldimethylsilyl)-aldehydo-D-glucose

5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde oxime

5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde oxime

((4R,5R)-5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol

((4R,5R)-5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol

5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde oxime

5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde oxime

4-O-(tert-butyldimethylsilyl)-2,3:5,6-di-O-isopropylidene-aldehydo-D-mannose

4-O-(tert-butyldimethylsilyl)-2,3:5,6-di-O-isopropylidene-aldehydo-D-mannose

5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde oxime

5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde oxime

上游原料

((4R,5R)-5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol 4-O-(tert-butyldimethylsilyl)-2,3:5,6-di-O-isopropylidene-aldehydo-D-mannose 2,3:5,6-Di-O-isopropylidene-4-O-(tert-butyldimethylsilyl)-aldehydo-D-glucose

下游产品

benzyl (((4S,5R)-5-((1R,2R)-1-((tert-butyldimethylsilyl)oxy)-2,3-dihydroxypropyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)carbamate (3aS,8S,8aS,9R,9aS)-8-((tert-butyldimethylsilyl)oxy)-9-hydroxy-2,2-dimethylhexahydro-[1,3]dioxolo[4,5-f]indolizin-6(7H)-one 栗精胺 benzyl (((4S,5R)-5-((R)-((tert-butyldimethylsilyl)oxy)((R)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl)carbamate