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栗精胺

栗精胺

CAS号:79831-76-8
英文名:castanospermine
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化合物简介
Castanospermine is an indolizidine alkaloid first isolated from the seeds of Castanospermum australe. It is a potent inhibitor of some glucosidase enzymes and has antiviral activity in vitro and in mouse models.
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上游原料
benzyl benzyl((S)-1-((3aR,5R,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-oxoethyl)carbamate (1S,6S,7S,8R,8aS)-6-(methoxymethoxy)-1-((R)-1-(2,4,6-triisopropylphenyl)ethoxy)octahydroindolizine-7,8-diol N-benzyl-3-O-benzyl-5-deoxy-5-(hydroxylamino)-5-vinyl-1,2-O-isopropylidene-α-D-gluco-1,4-pentofuranoside 3-O-benzyl-1,2-O-isopropylidene-5,6,7-trideoxy-5-(N-benzyl-N-benzoxycarbonylamino)-α-D-gluco-6-eno-hepta-1,4-furanose 1,6,7,8-tetra-O-acetylcastanospermine 7,8,9-trideoxy-2,3,4,6-tetra-O-benzyl-L-glycero-D-gluco-non-8-enose dimethyl acetal (1R,2S)-1-Benzylamino-1-((3aR,5R,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-but-3-en-2-ol (3R,4R,5R,6S,7S)-1,8-Bis[(tert-butyldimethylsilyl)oxy]-4-(dibenzylamino)-6,7-(isopropylidenedioxy)-5-(methoxymethoxy)octan-3-ol (S,Z)-1-((tert-butyldiphenylsilyl)oxy)-6-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)hex-4-en-3-ol N-{(1S,2S)-4-(tert-Butyl-diphenyl-silanyloxy)-1-[(E)-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-vinyl]-2-hydroxy-butyl}-2,2,2-trichloro-acetamide (1S,6S,7S,8R,8aR)-1-Hydroxy-6,7-(isopropylidenedioxy)-8-(methoxymethoxy)indolizidine 2,2,2-trichloro-1-((2S,3S)-2-((E)-2-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)vinyl)-3-hydroxypyrrolidin-1-yl)ethanone (2R,3S)-1-benzyl-3-(benzyloxy)-2-((3aR,5R,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)pyrrolidine (1S,6S,7R,8R,8aR)-8-(Benzyloxy)-1,6,7-trihydroxyoctahydroindolizidine (1S,6S,7S,8R,8aS)-6,7-bis(benzyloxy)-octahydroindolizine-1,8-diol (2S,3S)-2-[(1R,2S,3R)-4-(tert-Butyl-diphenyl-silanyloxy)-1,2,3-trihydroxy-butyl]-3-methoxymethoxy-pyrrolidine-1-carboxylic acid benzyl ester (2R,3R,4S,5S)-6-((tert-Butyldimethylsilyl)oxy)-2-(dibenzylamino)-4,5-(isopropylidenedioxy)-3-(methoxymethoxy)hexanal (2R,3S)-2-((4R,5S)-2,2-Dimethyl-5-(S)-oxiranyl-[1,3]dioxolan-4-yl)-3-methoxymethoxy-pyrrolidine-1-carboxylic acid benzyl ester (2R,3R,4S,5S)-6-[(tert-Butyldimethylsilyl)oxy]-2-(dibenzylamino)-4,5-(isopropylidenedioxy)hexane-1,3-diol (1S,6S,7R,8R,8aR)-1-hydroxy-6,7,8-tris(benzyloxy)indolizidine 1,6,7,8-tetrahydroxy-7,8-O-isopropylideneindolizidine (2R,3R,4S,5S)-1-Acetoxy-6-((tert-butyldimethylsilyl)oxy)-2-(dibenzylamino)-4,5-(isopropylidenedioxy)hexan-3-ol (1S,6S,7R,8R,8aR)-1,6,7,8-tetrabenzyloxy-octahydro-indolizine (2S,4S)-4-((Z)-3-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)prop-1-en-1-yl)-2-(4-methoxyphenyl)-1,3-dioxane (3S,4R,5R,6S,7S)-3-Acetoxy-1,8-bis[(tert-butyldimethylsilyl)oxy]-4-(dibenzylamino)-6,7-(isopropylidenedioxy)-5-(methoxymethoxy)octane (3S)-3-((3aS,6R,7aR,7R)-5-benzyl-7-benzyloxy-2,2-dimethylhexahydro-1,3-dioxolo[4,5-c]pyridin-6-yl)-3-hydroxypropionaldehyde (1S,6S,7R,8R,8aR)-7,8-bis(benzyloxy)octahydroindolizine-1,6-diol 2,2,2-Trichloro-N-{(1S,2S)-1-[(E)-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-vinyl]-2,4-dihydroxy-butyl}-acetamide benzyl (2S,3S)-2-((E)-2-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)vinyl)-3-hydroxypyrrolidine-1-carboxylate (Z)-(S)-6-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-hex-4-ene-1,3-diol (R)-N-benzyl-1-((3aR,5R,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)prop-2-en-1-amine (2S,3R,4R,5S)-6-<(tert-butyldimethylsilyl)oxy>-2,3-epoxy-4,5-(isopropylidenedioxy)hexan-1-ol (1S,6S,7R,8R,8aR)-1-((tert-butyldimethylsilyl)oxy)-7,8-bis((trimethylsilyl)oxy)octahydroindolizin-6-ol (2S,3R,4R,5S)-1-Benzyl-3,4,5-tris-benzyloxy-piperidine-2-carbaldehyde 2-((9-phenylfluoren-9-yl)amino)-2-deoxy-3,4:5,6-di-O-isopropylidene-D-mannose N-{(1R,2S)-4-(tert-Butyl-diphenyl-silanyloxy)-1-[(R)-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-phenylselanyl-ethyl]-2-hydroxy-butyl}-2,2,2-trichloro-acetamide benzyl benzyl((1R)-1-((3aR,5R,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-2-hydroxybut-3-en-1-yl)carbamate (2S,3S)-2-[(E)-(S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-hydroxy-but-1-enyl]-3-methoxymethoxy-pyrrolidine-1-carboxylic acid benzyl ester Ethyl (3R/S,4R,5R,6S,7S)-8-[(tert-butyldimethylsilyl)oxy]-4-(dibenzylamino)-3-hydroxy-6,7-(isopropylidenedioxy)-5-(methoxymethoxy)octanoate (2R,3S)-benzyl 2-((4R,5R)-5-((R)-2-((tert-butyldiphenylsilyl)oxy)-1-hydroxyethyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-3-(methoxymethoxy)pyrrolidine-1-carboxylate benzyl (2R,3S)-3-hydroxy-2-((3aR,5R,6S,6aR)-6-hydroxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)pyrrolidine-1-carboxylate acetonide of (1S,6S,7S,8R,8aS)-6-(methoxymethoxy)-1-((R)-1-(2,4,6-triisopropylphenyl)ethoxy)octahydroindolizine-7,8-diol