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methyl 2-((1R,3S,7R,11S,15S,17R,21R,23S,E)-17-((R)-1-((benzyloxy)methoxy)ethyl)-11-methoxy-21-((4-methoxybenzyl)oxy)-10,10-dimethyl-5,25-dimethylene-12,19-dioxo-18,27,28,29-tetraoxatetracyclo[21.3.1.13,7.111,15]nonacos-8-en-13-yl)-2-hydroxyacetate

methyl 2-((1R,3S,7R,11S,15S,17R,21R,23S,E)-17-((R)-1-((benzyloxy)methoxy)ethyl)-11-methoxy-21-((4-methoxybenzyl)oxy)-10,10-dimethyl-5,25-dimethylene-12,19-dioxo-18,27,28,29-tetraoxatetracyclo[21.3.1.13,7.111,15]nonacos-8-en-13-yl)-2-hydroxyacetate

CAS号：1028481-90-4

英文名：methyl 2-((1R,3S,7R,11S,15S,17R,21R,23S,E)-17-((R)-1-((benzyloxy)methoxy)ethyl)-11-methoxy-21-((4-methoxybenzyl)oxy)-10,10-dimethyl-5,25-dimethylene-12,19-dioxo-18,27,28,29-tetraoxatetracyclo[21.3.1.13,7.111,15]nonacos-8-en-13-yl)-2-hydroxyacetate

分子式

C51H68O14

熔点

密度

分子量

905.077

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

methyl 2-((1R,3S,7R,11S,15S,17R,21R,23S,E)-17-((R)-1-((benzyloxy)methoxy)ethyl)-11-methoxy-21-((4-methoxybenzyl)oxy)-10,10-dimethyl-5,25-dimethylene-12,19-dioxo-18,27,28,29-tetraoxatetracyclo[21.3.1.13,7.111,15]nonacos-8-en-13-yl)-2-hydroxyacetate

英文名称

methyl 2-((1R,3S,7R,11S,15S,17R,21R,23S,E)-17-((R)-1-((benzyloxy)methoxy)ethyl)-11-methoxy-21-((4-methoxybenzyl)oxy)-10,10-dimethyl-5,25-dimethylene-12,19-dioxo-18,27,28,29-tetraoxatetracyclo[21.3.1.13,7.111,15]nonacos-8-en-13-yl)-2-hydroxyacetate

中文别名

英文别名

CAS号

1028481-90-4

分子式

C51H68O14

分子量

905.077

精确质量

904.461

PSA

163.74

LOGP

7.2864

合成路线

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ethyl (R)-4-((2R,6S)-6-((S)-4-(hydroxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-3-hydroxy-butanoate

ethyl (R)-4-((2R,6S)-6-((S)-4-(hydroxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-3-hydroxy-butanoate

methyl 2-((1R,3S,7R,11S,15S,17R,21R,23S,E)-17-((R)-1-((benzyloxy)methoxy)ethyl)-11-methoxy-21-((4-methoxybenzyl)oxy)-10,10-dimethyl-5,25-dimethylene-12,19-dioxo-18,27,28,29-tetraoxatetracyclo[21.3.1.13,7.111,15]nonacos-8-en-13-yl)-2-hydroxyacetate

methyl 2-((1R,3S,7R,11S,15S,17R,21R,23S,E)-17-((R)-1-((benzyloxy)methoxy)ethyl)-11-methoxy-21-((4-methoxybenzyl)oxy)-10,10-dimethyl-5,25-dimethylene-12,19-dioxo-18,27,28,29-tetraoxatetracyclo[21.3.1.13,7.111,15]nonacos-8-en-13-yl)-2-hydroxyacetate

上游原料

共找到12个上游原料 >

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enethioic acid S-ethyl ester

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enethioic acid S-ethyl ester

(S)-1-((2R,6S)-6-((S)-4-(tert-butyldiphenylsilyloxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-4-((trimethylsilyl)methyl)pent-4-en-2-ol

(S)-1-((2R,6S)-6-((S)-4-(tert-butyldiphenylsilyloxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-4-((trimethylsilyl)methyl)pent-4-en-2-ol

(E)-S-ethyl 4-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-(4-methoxybenzyloxy)butyl)-2-methoxy-3-oxo-tetrahydro-2H-pyran-2-yl)-4-methylpent-2-enethioate

(E)-S-ethyl 4-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-(4-methoxybenzyloxy)butyl)-2-methoxy-3-oxo-tetrahydro-2H-pyran-2-yl)-4-methylpent-2-enethioate

(E)-4-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-(tert-butyldimethylsilyloxy)butyl)-2-methoxy-3-oxo-tetrahydro-2H-pyran-2-yl)-4-methylpent-2-enal

(E)-4-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-(tert-butyldimethylsilyloxy)butyl)-2-methoxy-3-oxo-tetrahydro-2H-pyran-2-yl)-4-methylpent-2-enal

(R)-ethyl 4-((2R,6S)-6-((S)-4-(tert-butyldiphenylsilyloxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-3-(trimethylsilyloxy)butanoate

(R)-ethyl 4-((2R,6S)-6-((S)-4-(tert-butyldiphenylsilyloxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-3-(trimethylsilyloxy)butanoate

ethyl (R)-4-((2R,6S)-6-((S)-4-(tert-butyldiphenylsilyloxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-3-hydroxy-butanoate

ethyl (R)-4-((2R,6S)-6-((S)-4-(tert-butyldiphenylsilyloxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-3-hydroxy-butanoate

下游产品

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(1R,3S,7R,8E,11S,12S,13E,15S,17R,21R,23S)-11,21-dihydroxy-17-((R)-1-hydroxyethyl)-13-(2-methoxy-2-oxoethylidene)-10,10-dimethyl-5,25-dimethylene-19-oxo-18,27,28,29-tetraoxatetracyclo[21.3.1.13,7.111,15]nonacos-8-en-12-yl benzoate

(1R,3S,7R,8E,11S,12S,13E,15S,17R,21R,23S)-11,21-dihydroxy-17-((R)-1-hydroxyethyl)-13-(2-methoxy-2-oxoethylidene)-10,10-dimethyl-5,25-dimethylene-19-oxo-18,27,28,29-tetraoxatetracyclo[21.3.1.13,7.111,15]nonacos-8-en-12-yl benzoate

上游原料

(E)-4-{(S)-6-[(2R,3R)-3-Benzyloxymethoxy-2-(4-methoxy-benzyloxy)-butyl]-5,6-dihydro-4H-pyran-2-yl}-4-methyl-pent-2-enethioic acid S-ethyl ester (S)-1-((2R,6S)-6-((S)-4-(tert-butyldiphenylsilyloxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-4-((trimethylsilyl)methyl)pent-4-en-2-ol (E)-S-ethyl 4-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-(4-methoxybenzyloxy)butyl)-2-methoxy-3-oxo-tetrahydro-2H-pyran-2-yl)-4-methylpent-2-enethioate (E)-4-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-(tert-butyldimethylsilyloxy)butyl)-2-methoxy-3-oxo-tetrahydro-2H-pyran-2-yl)-4-methylpent-2-enal (R)-ethyl 4-((2R,6S)-6-((S)-4-(tert-butyldiphenylsilyloxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-3-(trimethylsilyloxy)butanoate ethyl (R)-4-((2R,6S)-6-((S)-4-(tert-butyldiphenylsilyloxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-3-hydroxy-butanoate ethyl (R)-4-((2R,6S)-6-((S)-4-(hydroxy)-2-(4-methoxybenzyloxy)butyl)-4-methylenetetrahydro-2H-pyran-2-yl)-3-hydroxy-butanoate S-ethyl (E)-4-((2S,6S)-6-((2R,3R)-3-(benzyloxymethoxy)-2-(4-methoxybenzyloxy)butyl)-2-(tert-butyldimethylsilyloxy)butyl-2-methoxy-3-oxo-tetrahydro-2H-pyran-2-yl)-4-methylpent-2-enethioate

下游产品

(1R,3S,7R,8E,11S,12S,13E,15S,17R,21R,23S)-11,21-dihydroxy-17-((R)-1-hydroxyethyl)-13-(2-methoxy-2-oxoethylidene)-10,10-dimethyl-5,25-dimethylene-19-oxo-18,27,28,29-tetraoxatetracyclo[21.3.1.13,7.111,15]nonacos-8-en-12-yl benzoate