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(5S)-3-[(2S,13R)-2,13-二羟基-13-[(2R,5R)-5-[(2R,5R)-5-[(1R)-1-羟基十一烷基]四氢呋喃-2-基]四氢呋喃-2-基]十三烷基]-5-甲基-5H-呋喃-2-酮

(5S)-3-[(2S,13R)-2,13-二羟基-13-[(2R,5R)-5-[(2R,5R)-5-[(1R)-1-羟基十一烷基]四氢呋喃-2-基]四氢呋喃-2-基]十三烷基]-5-甲基-5H-呋喃-2-酮

CAS号:102989-24-2
英文名:(+)-asimicin
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上游原料
(cis,4R,5R,12R,13R)-5-hydroxy-12,13-isopropylidenedioxytricosa-8-en-1,4-olide (4R,5R,8R,9R,12R,13R)-1-hydroxy-4,13-di(methoxymethoxy)-5,8:9,12-dioxidotricosane 1,9-癸二烯 4-戊炔-1-醇 6-phenylmethoxyhex-1-en-3-ol (12R,16R)-12-(tert-butyldimethylsilanyloxy)-16-(tert-butyldiphenylsilanyloxy)heptadec-14-yn-1-ol (2R,2'R,5R,5'R)-5-[(1R)-1-hydroxyundecyl]-5'-[(1R,12R,16R)-1,12,16-trihydroxyheptadec-14-yne]octahydro-2,2'-bifuran (S)-3-((2R,13R)-2-((tert-butyldimethylsilyl)oxy)-13-((2R,2'R,5R,5'R)-5'-((R)-1-((tert-butyldimethylsilyl)oxy)undecyl)octahydro-[2,2'-bifuran]-5-yl)-13-hydroxytridecyl)-5-methylfuran-2(5H)-one (4R,5R,8R,9S,12R,13R)-9-hydroxy-12,13-isopropylidenedioxy-5,8-oxidotricosa-1,4-olide (4R,5R)-8-hydroxy-5-(tert-butyldiphenylsilyloxy)octan-1,4-olide (trans)-pentadec-4-en-1-al (S)-3-((2R,13R)-2,13-bis((2-(trimethylsilyl)ethoxy)methoxy)-13-((2R,2'R,5R,5'R)-5'-((R)-1-((2-(trimethylsilyl)ethoxy)methoxy)undecyl)octahydro-[2,2'-bifuran]-5-yl)tridecyl)-5-methylfuran-2(5H)-one (4R,5S)-1,4,5-trihydroxypentadecane (trans)-ethyl octa-4,7-dienoate (4R,5R)-8-(benzyloxy)-4,5-bis((tert-butyldimethylsilyl)oxy)octanal trans-1-iodopentadec-4-ene (2R,4R,5S)-5-[(1R)-1-(tert-butyldimethylsilanyloxy)undecyl]-4-(dimethylphanylsilanyl)tetrahydrofuran-2-carbaldehyde trans-pentadec-4-en-1-ol (2RS,4S,2'R)-2'-tert-butyldimethylsilyloxydec-9-en-1-yl-2-(phenylsulfanyl)pentan-1,4-olide (12R,16R)-2,2-dimethylpropionic acid 16-(tert-butyldiphenylsilanyloxy)-12-hydroxyheptadec-14-ynyl ester (5R,6S,9R,10R)-10-(3-(benzyloxy)propyl)-9-((tert-butyldimethylsilyl)oxy)-5-((E)-dec-1-en-1-yl)-12,12,13,13-tetramethyl-2,4,11-trioxa-12-silatetradecan-6-yl 4-methylbenzenesulfonate 11,12-dehydroasimicin-4-tert-butyldimethylsilyl-13,22-dimethoxymethyl-tris-ether (2R,2'R,4R,4'R,5S,5'S)-4,4'-bis-(dimethylphenylsilanyl)-5-[(1R)-1-(tert-butyldimethylsilanyloxy)undecyl]-5'-[(1R,12R,16R)-1,12-bis-(tert-butyldimethylsilanyloxy)-16-(tert-butyldiphenylsilanyloxy)heptadec-14-yne]octahydro-2,2'-bifuran pentadec-4-yn-1-ol (4R,5R,8R,9S)-9-hydroxy-5,8-oxidotricosa-12-en-1,4-olide (4S,2R')-2'-tert-butyldimethylsilyloxynonan-9-al-1-ylpent-2-en-1,4-olide (4R,5R,8R,9R,12R,13R)-1-iodo-4,13-di(methoxymethoxy)-5,8:9,12-dioxidotricosane N,N-dimethyl-P-phenylphosphonamidithionic chloride (4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide (12R,16R)-2,2-dimethylpropionic acid 16-(tert-butyldiphenylsilanyloxy)-12-(tert-budyldimethylsilanyloxy)heptadec-14-ynyl ester (4R,5R,12R,13R)-5,12,13-trihydroxytricosa-8-yn-1,4-olide (3S,4R,15R,19R)-15-(tert-butyldimethylsilanyloxy)-19-(tert-butyldiphenylsilanyloxy)-3-(dimethylphenylsilanyl)eicos-1-en-17-yn-4-ol (trans)-ethyl 8-oxooct-4-enoate (4R,5R)-8-benzyloxy-5-(tert-butyldiphenylsilyloxy)octan-1,4-olide (4R,5R,8R,9R,12R,13R)-1,4,13-trihydroxy-5,8:9,12-dioxidotricosane (4R,5R,12R,13R)-5-hydroxytricosa-12,13-isopropylidenedioxy-8-yn-1,4-olide ethyl (4E)-8-benzyloxy-4-enoctanoate (trans)-ethyl-8-hydroxyoct-4-enoate (4R,5R,8R,9R,12R,13R)-13-hydroxy-5,8:9,12-dioxidotricosa-1,4-olide (cis,4R,5R)-5-hydroxytricosa-8-en-12-yne-1,4-olide 2-(4-戊炔氧基)四氢-2H-吡喃 (2R,4R,5S)-[5-[(1R)-1-(tert-butyldimethylsilanyloxy)undecyl]-4-(dimethylphenylsilanyl)tetrahydrofuran-2-yl]methanol (3S,4R,15R,19R)-4,15-bis(tert-bytyldimethylsilanyloxy)-19-(tert-butyldiphenylsilanyloxy)-3-(dimethylphenylsilanyl)eicos-1-en-17-yne (trans,cis)-ethyl tricosa-4,8-dien-12-ynoate (2S,3R,5R)-5-(benzyloxymethyl)-2-[(1R)-1-(tert-butyldimethylsilanyloxy)undecyl]-3-(dimethylphenylsilanyl)tetrahydrofuran (4S,2R')-2'-tert-butyldimethylsilyloxydec-9-en-1-ylpent-2-en-1,4-olide (4R,5S)-5-hydroxy-pentadecan-4-olide