百科

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(ethoxyacetylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(ethoxyacetylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

CAS号：105420-53-9

英文名：p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(ethoxyacetylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

分子式：C42H49N2O8PSSi

分子量：800.971

合成路线

(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(ethoxyacetylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(ethoxyacetylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate

上游原料

(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

下游产品

p-nitrobenzyl (5R,6S)-6-<(1R)-hydroxyethyl>-2-ethoxymethyl-2-penem-3-carboxylate