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(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

CAS号：81225-41-4

英文名：(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

分子式

C17H30BrNO4SSi

熔点

54 °C

密度

分子量

452.479

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

英文名称

(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

中文别名

英文别名

CAS号

81225-41-4

分子式

C17H30BrNO4SSi

分子量

452.479

精确质量

451.085

PSA

81.14

LOGP

3.7036

物化性质

熔点

54 °C

合成路线

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130550-20-8

(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

(2S,5R,6S)-6-Bromo-6-[1-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid methyl ester

下游产品

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(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(propionylthio)azetidin-2-one

(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(propionylthio)azetidin-2-one

(5R,6S)-6-<(1R)-hydroxyethyl>-2-(3-aminopropan-1-yl)-2-penem-3-carboxylic acid

(5R,6S)-6-<(1R)-hydroxyethyl>-2-(3-aminopropan-1-yl)-2-penem-3-carboxylic acid

p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-(3-p-nitrobenzyloxycarbonylaminopropan-1-yl)-2-penem-3-carboxylate

p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-(3-p-nitrobenzyloxycarbonylaminopropan-1-yl)-2-penem-3-carboxylate

p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-(tert-butyldimethylsiloxymethyl)-2-penem-3-carboxylate

p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-(tert-butyldimethylsiloxymethyl)-2-penem-3-carboxylate

(5R,6S)-6-<(1R)-hydroxyethyl>-2-<<(2S)-pyrrolidin-2-yl>-methyl>-2-penem-3-carboxyic acid

(5R,6S)-6-<(1R)-hydroxyethyl>-2-<<(2S)-pyrrolidin-2-yl>-methyl>-2-penem-3-carboxyic acid

(5R,6S)-6-<(1R)-hydroxyethyl>-2-<<(2S)-azeitidin-2-yl>methyl>-2-penem-3-carboxylic acid

(5R,6S)-6-<(1R)-hydroxyethyl>-2-<<(2S)-azeitidin-2-yl>methyl>-2-penem-3-carboxylic acid

下游产品

(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(propionylthio)azetidin-2-one (5R,6S)-6-<(1R)-hydroxyethyl>-2-(3-aminopropan-1-yl)-2-penem-3-carboxylic acid p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-(3-p-nitrobenzyloxycarbonylaminopropan-1-yl)-2-penem-3-carboxylate p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-(tert-butyldimethylsiloxymethyl)-2-penem-3-carboxylate (5R,6S)-6-<(1R)-hydroxyethyl>-2-<<(2S)-pyrrolidin-2-yl>-methyl>-2-penem-3-carboxyic acid (5R,6S)-6-<(1R)-hydroxyethyl>-2-<<(2S)-azeitidin-2-yl>methyl>-2-penem-3-carboxylic acid p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(4-p-nitrobenzyloxycarbonylaminobutyrylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate (3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(ethoxyacetylthio)azetidin-2-one p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(propionylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate (5R,6S)-6-<(1R)-hydroxyethyl>-2-ethyl-2-penem-3-carboxylic acid sodium salt (5R,6S)-6-<(1R)-hydroxyethyl>-2-(2-aminoethyl)-2-penem-3-carboxylic acid p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-(2-p-nitrobenzyloxycarbonylaminoethyl)-2-penem-3-carboxylate p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(3-p-nitrobenzyloxycarbonylaminopropionylthio)-2-oxoazetidin-1-yl>-2-hydroxyacetate p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-<((RS)-N-p-nitrobenzyloxycarbonylpiperidin-2-yl)methyl>-2-penem-3-carboxylate p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-ethoxymethyl-2-penem-3-carboxylate p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-propionylthio-2-oxoazetidin-1-yl>-2-hydroxyacetate (5R,6S)-6-<(1R)-hydroxyethyl>-2-<(RS-piperidin-2-yl)methyl>-2-penem-3-carboxylic acid p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(ethoxyacetylthio)-2-oxoazetidin-1-yl>-2-hydroxyacetate p-nitrobenzyl (5R,6S)-6-<(1R)-hydroxyethyl>-2-ethoxymethyl-2-penem-3-carboxylate <4R,3S(R)>-3-<1(R)-1-<(tert-butyldimethylsilyl)oxy>ethyl>-4-<<<(tert-butyldimethylsilyl)oxy>acetyl>thio>-2-azetidinone p-nitrobenzyl (5R,6S)-6-<(1R)-hydroxyethyl>-2-<<(2S)-N-p-nitrobenzyloxycarbonylazeitidin-2-yl>methyl>-2-penem-3-carboxylate p-nitrobenzyl (5R,6S)-6-<(1R)-hydroxyethyl>-2-(3-p-nitrobenzyloxycarbonylaminopropan-1-yl)-2-penem-3-carboxylate (3R,4R)-3-<(R)-1-(tert-butyldimethylsilyloxy)ethyl>-4-methylsulfonyl-2-azetidinone p-nitrobenzyl (5R,6S)-6-<(1R)-(tert-butyldimethylsiloxy)ethyl>-2-ethyl-2-penem-3-carboxylate (5R,6S)-6-<(1R)-hydroxyethyl>-2-<(2R)-pyrrolidin-2-yl>methyl-2-penem-3-carboxylic acid (5R,6S)-6-<(1R)-hydroxyethyl>-2-<(2S)-pyrrolidin-2-yl>-2-penem-3-carboxylic acid p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(4-p-nitrobenzyloxycarbonylaminobutyrylthio)-2-oxoazetidin-1-yl>-2-hydroxyacetate (3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-<4-(p-nitrobenzyloxycarbonylamino)butyrylthio>azetidin-2-one p-nitrobenzyl (5R,6S)-6-<(1R)-hydroxyethyl>-2-(2-p-nitrobenzyloxycarbonylaminoethyl)-2-penem-3-carboxylate p-nitrobenzyl(5R,6S)-6-[1(R)-hydroxyethyl]-2-hydroxymethyl-penem-3-carboxylate (5R,6S)-6-<(1R)-hydroxyethyl>-2-ethoxymethyl-2-penem-3-carboxylic acid sodium salt p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(3-p-nitrobenzyloxycarbonylaminopropionylthio)-2-oxoazetidin-1-yl>-2-triphenylphosphoranylideneacetate (5R,6S)-6-<(1R)-hydroxyethyl>-2-(4-aminobutan-1-yl)-2-penem-3-carboxylic acid (3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-<3-(p-nitrobenzyloxycarbonylamino)propionylthio>azetidin-2-one p-nitrobenzyl 2-<(3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-(tert-butyldimethylsiloxyacetylthio)-2-oxoazetidin-1-yl>-2-hydroxyacetate p-nitrobenzyl (5R,6S)-6-<(1R)-hydroxyethyl>-2-ethyl-2-penem-3-carboxylate (5R,6S)-6-<(1R)-hydroxyethyl>-2-<(2R)-pyrrolidin-2-yl>-2-penem-3-carboxylic acid 4-乙酰氧基氮杂环丁酮 p-nitrobenzyl (5R,6S)-6-<(1R)-hydroxyethyl>-2-<((RS)-N-p-nitrobenzyloxycarbonylpiperidin-2-yl)methyl>-2-penem-3-carboxylate (3S,4R)-3-<(1R)-(tert-butyldimethylsiloxy)ethyl>-4-<<(2R)-N-p-nitrobenzyloxycarbonylazetidin-2-yl>acetylthio>azetidin-2-one