百科

右旋樟脑磺内酰胺

右旋樟脑磺内酰胺

CAS号：108448-77-7

英文名：(+)-10,2-Camphorsultam

分子式

C10H17NO2S

熔点

181-185ºC

密度

1.28g/cm3

分子量

215.312

沸点

324.8ºC at 760mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

右旋樟脑磺内酰胺

英文名称

(+)-10,2-Camphorsultam

中文别名

(1R)-(+)-2,10-樟脑磺内酰胺、(+)-10,2-樟脑磺内酰胺、L-(+)-樟脑内磺酰胺、(1R,2S)-(+)-2,10-樟脑内磺酰胺、(1R,5S)-10,10-二甲基-3-硫代-4-氮杂三环[5.2.1.01,5]癸烷-3,3-二氧化物

英文别名

(1R)-(+)-2,10,Camphorsultam、(+)-exo-10,2-Bornanesultam、L-2,10-Camphorsultam、(2S)-Bornane-10,2-sultam、(1R,5S)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]decane 3,3-dioxide、(1R,5S)-10,10-Dimethyl-3-Thia-4-Azatricyclo[5.2.1.0(1,5)]Decane 3,3-Dioxide、(1R)-(+)-2,10-Camphorsultam

CAS号

108448-77-7

分子式

C10H17NO2S

分子量

215.312

精确质量

215.098

PSA

54.55

LOGP

2.5239

编号系统

MDL号

MFCD00151762

BRN号

4675755

物化性质

外观与性状

白色至淡黄色晶体粉末

密度

1.28g/cm3

沸点

324.8ºC at 760mmHg

熔点

181-185ºC

闪点

150.3ºC

储存条件

2-8ºC

蒸汽压

0.000239mmHg at 25°C

安全信息

安全说明

S26-S37/39

危险类别码

R36/37/38

WGK Germany

3

海关编码

2934991000

危险品标志

Xi

合成路线

共找到4条合成路线 >

94594-79-3

(R)-3-环己烯甲酸

(R)-3-环己烯甲酸

右旋樟脑磺内酰胺

右旋樟脑磺内酰胺

上游原料

共找到30个上游原料 >

右旋樟脑-10-磺酰氯

右旋樟脑-10-磺酰氯

<3aR<1<1S*,3(R*),5R*,6R*>,3aα,6α,7aβ>>-1-<<3-<2-<<(1,1-Dimwthylethyl)dimethylsilyl>oxy>-1-phenylethyl>-8-methyl-2,4-dioxo-3,8-diazabicyclo<3.2.1>oct-6-yl>carbonyl>hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide

<3aR<1<1S*,3(R*),5R*,6R*>,3aα,6α,7aβ>>-1-<<3-<2-<<(1,1-Dimwthylethyl)dimethylsilyl>oxy>-1-phenylethyl>-8-methyl-2,4-dioxo-3,8-diazabicyclo<3.2.1>oct-6-yl>carbonyl>hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide

(2R,2'R,3'aS,7'S)-N-(3',3'a,4',5',6',7'-hexahydro-2'-phenyl-2'H-isooxazolo(2,3a)-pyridine-7'-carbonyl)bornane-10,2-sultam

(2R,2'R,3'aS,7'S)-N-(3',3'a,4',5',6',7'-hexahydro-2'-phenyl-2'H-isooxazolo(2,3a)-pyridine-7'-carbonyl)bornane-10,2-sultam

methyl (2R,3R,5R)-5-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidohexahydro-3H-3a,6-methanobenzo[c]isothiazole-1-carbonyl)-2-phenethylpyrrolidine-3-carboxylate

methyl (2R,3R,5R)-5-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidohexahydro-3H-3a,6-methanobenzo[c]isothiazole-1-carbonyl)-2-phenethylpyrrolidine-3-carboxylate

(S)-2-((4R,5S,6S)-6-((S)-1-(1,3-dithiolan-2-yl)ethyl)-2,2-di-tert-butyl-5-methyl-1,3,2-dioxasilinan-4-yl)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)propan-1-one

(S)-2-((4R,5S,6S)-6-((S)-1-(1,3-dithiolan-2-yl)ethyl)-2,2-di-tert-butyl-5-methyl-1,3,2-dioxasilinan-4-yl)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)propan-1-one

(E)-(R)-1-((1R,5S,7S)-10,10-Dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-2,4-dimethyl-hept-4-en-1-one

(E)-(R)-1-((1R,5S,7S)-10,10-Dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-2,4-dimethyl-hept-4-en-1-one

下游产品

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N-乙酰基-(2R)-莰烷-10,2-磺内酰胺

N-乙酰基-(2R)-莰烷-10,2-磺内酰胺

(S)-(+)-(2-丁烯酰)-2,10-樟脑磺内酰胺

(S)-(+)-(2-丁烯酰)-2,10-樟脑磺内酰胺

(3aR,6S,7aS)-六氢-8,8-二甲基-1-(1-氧代丙基)-3H-3a,6-甲桥-2,1-苯并异噻唑 2,2-二氧化物

(3aR,6S,7aS)-六氢-8,8-二甲基-1-(1-氧代丙基)-3H-3a,6-甲桥-2,1-苯并异噻唑 2,2-二氧化物

上游原料

右旋樟脑-10-磺酰氯 <3aR<1<1S*,3(R*),5R*,6R*>,3aα,6α,7aβ>>-1-<<3-<2-<<(1,1-Dimwthylethyl)dimethylsilyl>oxy>-1-phenylethyl>-8-methyl-2,4-dioxo-3,8-diazabicyclo<3.2.1>oct-6-yl>carbonyl>hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide (2R,2'R,3'aS,7'S)-N-(3',3'a,4',5',6',7'-hexahydro-2'-phenyl-2'H-isooxazolo(2,3a)-pyridine-7'-carbonyl)bornane-10,2-sultam methyl (2R,3R,5R)-5-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidohexahydro-3H-3a,6-methanobenzo[c]isothiazole-1-carbonyl)-2-phenethylpyrrolidine-3-carboxylate (S)-2-((4R,5S,6S)-6-((S)-1-(1,3-dithiolan-2-yl)ethyl)-2,2-di-tert-butyl-5-methyl-1,3,2-dioxasilinan-4-yl)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)propan-1-one (E)-(R)-1-((1R,5S,7S)-10,10-Dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-2,4-dimethyl-hept-4-en-1-one (2S)-N-(acryloyl)bornane-10,2-sultam (2S,3R,4S,5S,6S)-1-((1R,5S,7S)-10,10-Dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-6-[1,3]dithiolan-2-yl-3,5-dihydroxy-2,4-dimethyl-heptan-1-one (1R,2S,4S)-N-(2,3-dibromopropionyl)-bornane-2,10-sultam (3R,3aS,4S,7R,7aR)-3-((1R,5S,7S)-10,10-Dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]decane-4-carbonyl)-2,3,3a,4,7,7a-hexahydro-4,7-methano-inden-1-one ((R)-3-(tert-butyl)-4,5-dihydroisoxazol-5-yl)((3aS,6R,7aR)-8,8-dimethyl-2,2-dioxidohexahydro-1H-3a,6-methanobenzo[c]isothiazol-1-yl)methanone dimethyl (2R,3S,4R,5R)-2-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidohexahydro-3H-3a,6-methanobenzo[c]isothiazole-1-carbonyl)-5-phenethylpyrrolidine-3,4-dicarboxylate (+)-10-樟脑内磺酰亚胺 (3aS,4S,7R,7aR)-3-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidohexahydro-3H-3a,6-methanobenzo[c]isothiazole-1-carbonyl)-2-(trimethylsilyl)-3a,4,7,7a-tetrahydro-1H-4,7-methanoinden-1-one (3aR,6S,7aS)-六氢-8,8-二甲基-1-(1-氧代丙基)-3H-3a,6-甲桥-2,1-苯并异噻唑 2,2-二氧化物乙醇 (S)-2-((4S,5R,6R)-2,2-di-tert-butyl-6-((S)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)-1-oxopropan-2-yl)-5-methyl-1,3,2-dioxasilinan-4-yl)propanal 二甲基{2-[(1S,5R,7R)-10,10-二甲基-3,3-二氧代-3-硫杂-4-氮杂三环[5.2.1.01,5]癸-4-基]-2-氧代乙基}碳o二硫代亚氨酸酯 (S)-2-[(4R,5R,6R)-2,2-Di-tert-butyl-6-((1R,2R)-2-hydroxy-1-methyl-butyl)-5-methyl-[1,3,2]dioxasilinan-4-yl]-1-((1R,5S,7S)-10,10-dimethyl-3,3-dioxo-3λ6-thia-4-aza-tricyclo[5.2.1.01,5]dec-4-yl)-propan-1-one 1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidohexahydro-1H-3a,6-methanobenzo[c]isothiazol-1-yl)-3-(trimethylsilyl)prop-2-yn-1-one [3aR-[(3aS*,4S*,6aR*),3aα,6α,7aβ]]-3H-3a,6-methano-2,1-benzisothiazole, hexahydro-8,8-dimethyl-4-[[tetrahydro-1,3-dioxolo-5-(phenylmethyl)-2-oxo-[4,5-c]-pyrrol-4-yl]carbonyl]-2,2-dioxide (S)-2-((4R,5R,6R)-2,2-di-tert-butyl-6-((2R,3S)-3-hydroxypentan-2-yl)-5-methyl-1,3,2-dioxasilinan-4-yl)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)propan-1-one 樟脑磺酸苄硫醇 [3aR-[(3aR*,4R*,6aS*),3aα,6α,7aβ]]-3H-3a,6-methano-2,1-benzisothiazole, hexahydro-8,8-dimethyl-4-[[tetrahydro-1,3-dioxolo-5-(phenylmethyl)-2-oxo-[4,5-c]-pyrrol-4-yl]carbonyl]-2,2-dioxide (1R)-10-樟脑磺酰胺 ((R)-1-benzylaziridin-2-yl)((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidohexahydro-1H-3a,6-methanobenzo[c]isothiazol-1-yl)methanone [3aR-[1(2R*,3R*),3aα,6α,7aβ]]-3-pyrrolidine-carboxylic acid, 1-(phenylmethyl)-2-[(tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazol-1(4H)-yl)-carbonyl]-methyl ester, S,S-dioxide

下游产品

N-乙酰基-(2R)-莰烷-10,2-磺内酰胺 (S)-(+)-(2-丁烯酰)-2,10-樟脑磺内酰胺 (3aR,6S,7aS)-六氢-8,8-二甲基-1-(1-氧代丙基)-3H-3a,6-甲桥-2,1-苯并异噻唑 2,2-二氧化物