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首页百科 "(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one"

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one

CAS号：108906-56-5

英文名：(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one

分子式

C16H26O9

熔点

密度

1.48g/cm3

分子量

362.372

沸点

641.3ºC at 760 mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one

英文名称

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one

中文别名

英文别名

(-)-Gibboside

CAS号

108906-56-5

分子式

C16H26O9

分子量

362.372

精确质量

362.158

PSA

145.91

LOGP

-2.391

物化性质

密度

1.48g/cm3

沸点

641.3ºC at 760 mmHg

闪点

234ºC

折射率

1.592

蒸汽压

3.77E-19mmHg at 25°C

合成路线

(4R,4aS,6S,7S,7aS)-7-((benzyloxy)methyl)-4-methyl-6-(((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)hexahydrocyclopenta[c]pyran-3(1H)-one

(4R,4aS,6S,7S,7aS)-7-((benzyloxy)methyl)-4-methyl-6-(((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)hexahydrocyclopenta[c]pyran-3(1H)-one

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one

(4R,4aS,6S,7S,7aS)-7-(hydroxymethyl)-4-methyl-6-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-4,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyran-3-one

上游原料

共找到8个上游原料 >

methyl (E)-4-((4S,5S)-5-((E)-buta-1,3-dien-1-yl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl)but-2-enoate

methyl (E)-4-((4S,5S)-5-((E)-buta-1,3-dien-1-yl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl)but-2-enoate

2,3,4,6-四-O-苯基-Alpha-D-吡喃葡萄糖基三氯乙酰亚氨酸

2,3,4,6-四-O-苯基-Alpha-D-吡喃葡萄糖基三氯乙酰亚氨酸

(4R,4aS,6S,7S,7aS)-7-((benzyloxy)methyl)-4-methyl-6-(((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)hexahydrocyclopenta[c]pyran-3(1H)-one

(4R,4aS,6S,7S,7aS)-7-((benzyloxy)methyl)-4-methyl-6-(((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)hexahydrocyclopenta[c]pyran-3(1H)-one

(2S,3S)-2-((E)-Buta-1,3-dienyl)-5-triisopropylsilanyloxy-pentane-1,3-diol

(2S,3S)-2-((E)-Buta-1,3-dienyl)-5-triisopropylsilanyloxy-pentane-1,3-diol

(4R,4aS,6S,7S,7aS)-7-((benzyloxy)methyl)-6-((4-methoxybenzyl)oxy)-4-methylhexahydrocyclopenta[c]pyran-3(1H)-one

(4R,4aS,6S,7S,7aS)-7-((benzyloxy)methyl)-6-((4-methoxybenzyl)oxy)-4-methylhexahydrocyclopenta[c]pyran-3(1H)-one

(4R,4aS,6S,7S,7aS)-7-Benzyloxymethyl-6-hydroxy-4-methyl-hexahydro-cyclopenta[c]pyran-3-one

(4R,4aS,6S,7S,7aS)-7-Benzyloxymethyl-6-hydroxy-4-methyl-hexahydro-cyclopenta[c]pyran-3-one

上游原料

methyl (E)-4-((4S,5S)-5-((E)-buta-1,3-dien-1-yl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl)but-2-enoate 2,3,4,6-四-O-苯基-Alpha-D-吡喃葡萄糖基三氯乙酰亚氨酸 (4R,4aS,6S,7S,7aS)-7-((benzyloxy)methyl)-4-methyl-6-(((2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)hexahydrocyclopenta[c]pyran-3(1H)-one (2S,3S)-2-((E)-Buta-1,3-dienyl)-5-triisopropylsilanyloxy-pentane-1,3-diol (4R,4aS,6S,7S,7aS)-7-((benzyloxy)methyl)-6-((4-methoxybenzyl)oxy)-4-methylhexahydrocyclopenta[c]pyran-3(1H)-one (4R,4aS,6S,7S,7aS)-7-Benzyloxymethyl-6-hydroxy-4-methyl-hexahydro-cyclopenta[c]pyran-3-one

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