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互变霉素

互变霉素

CAS号:109946-35-2
英文名:Tautomycin from Streptomyces spiroverticillatus
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基本信息
编号系统
物化性质
安全信息
上游原料
Ethyl <2Z,4R,8R,9S,10R,13S,14S,17R,17<2S,3S,6R,8S,8(3S),9R>>-4-<<diethyl(1-methylethyl)silyl>oxy>-14-<(triethylsilyl)oxy>-10-hydroxy-9-methoxy-2,13,17-trimethyl-3-<(1,1-dimethylethoxy)carbonyl>-8-(1-methylethyl)-17-<3,9-dimethyl-8-... (2R,3R)-2-Methoxy-4-methyl-1-(phenylthio)-3-pentyl (4Z,3R)-5-(ethoxycarbonyl)-3-((diethyl(1-methylethyl)silyl)oxy)-4-((1,1-dimethylethoxy)carbonyl)-4-hexenoate (2S,3S,6R)-6-[(2S,3S,6R,8S,9R)-3,9-Dimethyl-8-((S)-3-methyl-pent-4-enyl)-1,7-dioxa-spiro[5.5]undec-2-yl]-3-hydroxy-2-methyl-heptanoic acid methoxy-methyl-amide (4R)-((5-(Tetrahydropyran-2-yloxy)-4-methyl-1-pentyl)oxy)(1,1-dimethylethyl)diphenylsilane (1R,2R)-1-Formyl-1-methoxy-3-methyl-2-butyl (4Z,3R)-5-(ethoxycarbonyl)-3-<<diethyl(1-methylethyl)silyl>oxy>-4-<(1,1-dimethylethoxy)carbonyl>-4-hexenoate tris-O-(tert-butyldimethylsilyl)tautomycin Ethyl <2Z,4R,8R,9S,10R,13S,14S,17R,17<2S,3S,6R,8S,8(3S),9R>>-4,10,14-trihydroxy-9-methoxy-2,13,17-trimethyl-3-<(1,1-dimethylethoxy)carbonyl>-8-(1-methylethyl)-17-<3,9-dimethyl-8-(3-methyl-4-pentenyl)-1,7-dioxaspiro<5.5>undec-2-yl>-6,12-dioxo-7-oxa... (2R,3S,4R,6S)-4-benzyloxy-2-isopropyl-3,6-dimethoxy-3,4,5,6-tetrahydro-2H-pyran (δR,2R,5S,6S)-δ,5-Dimethyl-6-<<<(1,1-dimethylethyl)diphenylsilyl>oxy>methyl>tetrahydro-2-pyranylbutanol (2S,3S,6R,11R)-3,11-Dimethyl-2-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-1,7-dioxaspiro[5.5]undecane (δR,2R,5S,6S)-6-(Bromomethyl)-δ,5-dimethyltetrahydro-2-pyranylbutyl acetate dibenzyl 2-methyl-3-((E)-pent-3-enoyl)maleate (4R)-5-(Tetrahydropyran-2-yloxy)-4-methyl-1-pentanol (Z)-(R)-3-Benzyloxycarbonyl-2-methyl-4-triethylsilanyloxy-hex-2-enedioic acid 1-benzyl ester 6-((1R,2R)-1-isopropyl-2-methoxy-3-oxo-propyl) ester 1,1-Dimethylethyl (αS,2R,4R)-α-hydroxy-2-(3,4-dimethoxyphenyl)-1,3-dioxane-4-acetate (3R,4S,6R,7R,8R)-6-(benzyloxy)-8-hydroxy-7-methoxy-4-((4-methoxybenzyl)oxy)-3,9-dimethyldecan-2-one Ethyl (αZ,2R,4R)-2-(3,4-dimethoxyphenyl)-α-methyl-β-<(1,1-dimethylethoxy)carbonyl>-1,3-dioxane-4-prop-α-enoate (4R,5S,6S)-((5-(Methoxymethoxy)-4,6-dimethyl-8-(phenylsulfonyl)-1-octyl)oxy)(1,1-dimethylethyl)diphenylsilane [2R,2(2R,3S,6R,8S,8(3S),9R)]-2-{3,9-dimethyl-8-[3-(2-methyl-1,3-dithian-2-yl)butyl]-1,7-dioxaspiro[5.5]undecane-2-yl}-1-propanol (4R,5S,6S)-((5-(Methoxymethoxy)-4,6-dimethyl-8-(phenylthio)-1-octyl)oxy)(1,1-dimethylethyl)diphenylsilane 18,22,3'-Tris-O-(triethylsilyl)tautomycin (R)-4-((2S,3S,6R,8S,9R)-3,9-dimethyl-8-((S)-3-methylpent-4-en-1-yl)-1,7-dioxaspiro[5.5]undecan-2-yl)pentanal Ethyl (4R)-5-(Tetrahydropyran-2-yloxy)-4-methylpentanoate 3,4-dibenzyl 1-((3R,4S,5R,8S,9S,12R)-12-((2S,3S,6R,8S,9R)-3,9-dimethyl-8-((S)-3-methylpent-4-en-1-yl)-1,7-dioxaspiro[5.5]undecan-2-yl)-5,9-dihydroxy-4-methoxy-2,8-dimethyl-7-oxotridecan-3-yl) (R,Z)-2-hydroxypent-3-ene-1,3,4-tricarboxylate Ethyl <2Z,4R,8R,9S,10R,13S,14S,17R,17<2S,3S,6R,8S,8(3S),9R>>-4,10,14-trihydroxy-9-methoxy-2,13,17-trimethyl-3-<(1,1-dimethylethoxy)carbonyl>-8-(1-methylethyl)-17-<3,9-dimethyl-8-(3-methyl-4-oxopentyl)-1,7-dioxaspiro<5.5>undec-2-yl>-6,12-dioxo-7-oxa... (3S,4S,7R)-7-((2S,3S,6R,8S,9R)-3,9-dimethyl-8-((S)-3-methylpent-4-en-1-yl)-1,7-dioxaspiro[5.5]undecan-2-yl)-4-hydroxy-3-methyloctan-2-one (4R,5S,6S)-((5-(Methoxymethoxy)-4,6-dimethyl-7-octen-1-yl)oxy)(1,1-dimethylethyl)diphenylsilane (1R,2S,3R)-3-benzyloxy-4-formyl-1-isopropyl-2-methoxybutyl benzoate (2R,3R)-2-Methoxy-4-methyl-1-(phenylsulfoxy)-3-pentyl (4Z,3R)-5-(ethoxycarbonyl)-3-((diethyl(1-methylethyl)silyl)oxy)-4-((1,1-dimethylethoxy)carbonyl)-4-hexenoate [2S,2(1R,4S,5R),3S,6R,8S,8(3S),9R]-2-(4-Hydroxy-1,5-dimethyl-6-heptenyl)-3,9-dimethyl-8-(3-methyl-4-pentenyl)-1,7-dioxaspiro[5.5]undecane (2S,2(1R,4S,5S),3S,6R,8S,8(3S),9R)-2-(4-((Triethylsilyl)oxy)-1,5-dimethyl-6-oxoheptyl)-3,9-dimethyl-8-(3-methyl-4-pentenyl)-1,7-dioxaspiro(5.5)undecane (2R)-2-Methyl-5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-pentanol (δR,2R,5S,6S)-δ,5-Dimethyl-6-[[(methylsulfonyl)oxy]methyl]tetrahydro-2-pyranylbutyl acetate 3,4-dibenzyl 1-((3R,4S,5R,8S,9S,12R)-12-((2S,3S,6R,8S,9R)-3,9-dimethyl-8-((S)-3-methyl-4-oxopentyl)-1,7-dioxaspiro[5.5]undecan-2-yl)-5,9-dihydroxy-4-methoxy-2,8-dimethyl-7-oxotridecan-3-yl) (R,Z)-2-hydroxypent-3-ene-1,3,4-tricarboxylate (3R,4R,5R)-5-benzyloxy-6-(1,3-dithian-2-yl)-4-methoxy-2-methyl-3-hexanol (4R,5R,8S)-5-Hydroxy-4,8-dimethyl-9-decenyl acetate (2S,3S,5R,6S,11R)-3,11-Dimethyl-2-<<<(1,1-dimethylethyl)diphenylsilyl>oxy>methyl>-5-(phenylsulfonyl)-1,7-dioxaspiro<5.5>undecane (2R,3S,4R,6S)-2-isopropyl-3,6-dimethoxy-3,4,5,6-tetrahydro-2H-pyran-4-ol <2S,2(1R),3S,6R,8S,8(3S),9R>-2-(4-Hydroxy-1-methylbutyl)-3,9-dimethyl-8-(3-methyl-4-pentenyl)-1,7-dioxaspiro<5.5>undecane 3,4-dibenzyl 1-((2R,3R)-2-methoxy-1-(methoxy(methyl)amino)-4-methyl-1-oxopentan-3-yl) (R,Z)-2-((triethylsilyl)oxy)pent-3-ene-1,3,4-tricarboxylate (δR,2R,5S,6S)-δ,5-Dimethyl-6-<<<(1,1-dimethylethyl)diphenylsilyl>oxy>methyl>tetrahydro-2-pyranylbutyl acetate (3S,6S,7R,13S,14S,15R)-18-((tert-butyldiphenylsilyl)oxy)-10-hydroxy-14-(methoxymethoxy)-3,7,13,15-tetramethyl-11-(phenylsulfonyl)octadec-1-en-6-yl 4-nitrobenzoate 1,1-Dimethylethyl (2R,4R)-2-(3,4-dimethoxyphenyl)-α-oxo-1,3-dioxane-4-acetate (3R,4S,5R)-5-(benzyloxy)-6-(1,3-dithian-2-yl)-4-methoxy-2-methylhexan-3-yl benzoate (2R)-2-Methyl-5-<<(1,1-dimethylethyl)diphenylsilyl>oxy>pentanal (3(2R,3S,5R,6S,7R),4R)-3-(7-benzoyloxy-5-benzyloxy-6-methoxy-3-(4-methoxybenzyl)oxy-2,8-dimethyl-1-oxononyl)-4-isopropyl-2-oxazolidinone (3S,4S,5R)-3,5-Dimethyl-8-<<(1,1-dimethylethyl)diphenylsilyl>oxy>-1-octen-4-ol