百科

(2aR,2a1S,3S,4R,5S,5aS,8aS)-4,5-dihydroxy-2a1,6,6-trimethyl-3-((methylthio)methyl)decahydro-2H-naphtho[1,8-bc]furan-2-one

(2aR,2a1S,3S,4R,5S,5aS,8aS)-4,5-dihydroxy-2a1,6,6-trimethyl-3-((methylthio)methyl)decahydro-2H-naphtho[1,8-bc]furan-2-one

CAS号：114273-62-0

英文名：(2aR,2a1S,3S,4R,5S,5aS,8aS)-4,5-dihydroxy-2a1,6,6-trimethyl-3-((methylthio)methyl)decahydro-2H-naphtho[1,8-bc]furan-2-one

分子式：C16H26O4S

分子量：314.44

合成路线

2,2-dimethyl-4-(3-methyl-5-oxo-2,5-dihydrofuran-2-yl)butanal

2,2-dimethyl-4-(3-methyl-5-oxo-2,5-dihydrofuran-2-yl)butanal

(2aR,2a1S,3S,4R,5S,5aS,8aS)-4,5-dihydroxy-2a1,6,6-trimethyl-3-((methylthio)methyl)decahydro-2H-naphtho[1,8-bc]furan-2-one

(2aR,2a1S,3S,4R,5S,5aS,8aS)-4,5-dihydroxy-2a1,6,6-trimethyl-3-((methylthio)methyl)decahydro-2H-naphtho[1,8-bc]furan-2-one

5-((4Z,6E)-7-methoxy-3,3-dimethylhepta-4,6-dien-1-yl)-4-methylfuran-2(5H)-one

5-((4Z,6E)-7-methoxy-3,3-dimethylhepta-4,6-dien-1-yl)-4-methylfuran-2(5H)-one

(2aR,2a1S,3S,4R,5S,5aS,8aS)-4,5-dihydroxy-2a1,6,6-trimethyl-3-((methylthio)methyl)decahydro-2H-naphtho[1,8-bc]furan-2-one

(2aR,2a1S,3S,4R,5S,5aS,8aS)-4,5-dihydroxy-2a1,6,6-trimethyl-3-((methylthio)methyl)decahydro-2H-naphtho[1,8-bc]furan-2-one

(2aR,2a1R,3R,5aR,8aR)-3-methoxy-2a1,6,6-trimethyl-2a,2a1,3,5a,6,7,8,8a-octahydro-2H-naphtho[1,8-bc]furan-2-one

(2aR,2a1R,3R,5aR,8aR)-3-methoxy-2a1,6,6-trimethyl-2a,2a1,3,5a,6,7,8,8a-octahydro-2H-naphtho[1,8-bc]furan-2-one

(2aR,2a1S,3S,4R,5S,5aS,8aS)-4,5-dihydroxy-2a1,6,6-trimethyl-3-((methylthio)methyl)decahydro-2H-naphtho[1,8-bc]furan-2-one

(2aR,2a1S,3S,4R,5S,5aS,8aS)-4,5-dihydroxy-2a1,6,6-trimethyl-3-((methylthio)methyl)decahydro-2H-naphtho[1,8-bc]furan-2-one

上游原料

(2aR,2a1R,3R,5aR,8aR)-3-methoxy-2a1,6,6-trimethyl-2a,2a1,3,5a,6,7,8,8a-octahydro-2H-naphtho[1,8-bc]furan-2-one 2,2-dimethyl-4-(3-methyl-5-oxo-2,5-dihydrofuran-2-yl)butanal 5-((4Z,6E)-7-methoxy-3,3-dimethylhepta-4,6-dien-1-yl)-4-methylfuran-2(5H)-one

下游产品

毛喉素 (3aR,4S,5S,5aS,6R,9aR,9bR)-2,2,4,5a,9,9-hexamethyl-5-((trityloxy)methyl)decahydronaphtho[1,2-d][1,3]dioxole-4,5,6-triol