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5-((tert-butyldiphenylsilyl)oxy)-1-((3aR,4S,5R,5aS,6R,9aR,9bR)-4,5-dihydroxy-6-((4-methoxybenzyl)oxy)-2,2,4,5a,9,9-hexamethyldecahydronaphtho[1,2-d][1,3]dioxol-5-yl)-3-methylpent-2-en-1-one

5-((tert-butyldiphenylsilyl)oxy)-1-((3aR,4S,5R,5aS,6R,9aR,9bR)-4,5-dihydroxy-6-((4-methoxybenzyl)oxy)-2,2,4,5a,9,9-hexamethyldecahydronaphtho[1,2-d][1,3]dioxol-5-yl)-3-methylpent-2-en-1-one

CAS号：114273-67-5

英文名：5-((tert-butyldiphenylsilyl)oxy)-1-((3aR,4S,5R,5aS,6R,9aR,9bR)-4,5-dihydroxy-6-((4-methoxybenzyl)oxy)-2,2,4,5a,9,9-hexamethyldecahydronaphtho[1,2-d][1,3]dioxol-5-yl)-3-methylpent-2-en-1-one

分子式：C47H64O8Si

分子量：785.092

合成路线

2,2-dimethyl-4-(3-methyl-5-oxo-2,5-dihydrofuran-2-yl)butanal

2,2-dimethyl-4-(3-methyl-5-oxo-2,5-dihydrofuran-2-yl)butanal

5-((tert-butyldiphenylsilyl)oxy)-1-((3aR,4S,5R,5aS,6R,9aR,9bR)-4,5-dihydroxy-6-((4-methoxybenzyl)oxy)-2,2,4,5a,9,9-hexamethyldecahydronaphtho[1,2-d][1,3]dioxol-5-yl)-3-methylpent-2-en-1-one

5-((tert-butyldiphenylsilyl)oxy)-1-((3aR,4S,5R,5aS,6R,9aR,9bR)-4,5-dihydroxy-6-((4-methoxybenzyl)oxy)-2,2,4,5a,9,9-hexamethyldecahydronaphtho[1,2-d][1,3]dioxol-5-yl)-3-methylpent-2-en-1-one

(3aβ,5aβ,6aα,9aα,9bα,9cβ)-Decahydro-1,1,8,8,9c-pentamethyl-6-methylene-5H-furo[4',3',2':4,5]naphtho[1,2-d][1,3]dioxol-5-one

(3aβ,5aβ,6aα,9aα,9bα,9cβ)-Decahydro-1,1,8,8,9c-pentamethyl-6-methylene-5H-furo[4',3',2':4,5]naphtho[1,2-d][1,3]dioxol-5-one

5-((tert-butyldiphenylsilyl)oxy)-1-((3aR,4S,5R,5aS,6R,9aR,9bR)-4,5-dihydroxy-6-((4-methoxybenzyl)oxy)-2,2,4,5a,9,9-hexamethyldecahydronaphtho[1,2-d][1,3]dioxol-5-yl)-3-methylpent-2-en-1-one

5-((tert-butyldiphenylsilyl)oxy)-1-((3aR,4S,5R,5aS,6R,9aR,9bR)-4,5-dihydroxy-6-((4-methoxybenzyl)oxy)-2,2,4,5a,9,9-hexamethyldecahydronaphtho[1,2-d][1,3]dioxol-5-yl)-3-methylpent-2-en-1-one

(3aβ,,6aα,9aα,9bβ,9cβ)-1,2,3,3a,6a,9a,9b,9c-Octahydro-1,1,6,8,8,9c-hexamethyl-5H-furo[4',3',2':4,5]naphtho[1,2-d][1,3]dioxol-5-one

(3aβ,,6aα,9aα,9bβ,9cβ)-1,2,3,3a,6a,9a,9b,9c-Octahydro-1,1,6,8,8,9c-hexamethyl-5H-furo[4',3',2':4,5]naphtho[1,2-d][1,3]dioxol-5-one

5-((tert-butyldiphenylsilyl)oxy)-1-((3aR,4S,5R,5aS,6R,9aR,9bR)-4,5-dihydroxy-6-((4-methoxybenzyl)oxy)-2,2,4,5a,9,9-hexamethyldecahydronaphtho[1,2-d][1,3]dioxol-5-yl)-3-methylpent-2-en-1-one

5-((tert-butyldiphenylsilyl)oxy)-1-((3aR,4S,5R,5aS,6R,9aR,9bR)-4,5-dihydroxy-6-((4-methoxybenzyl)oxy)-2,2,4,5a,9,9-hexamethyldecahydronaphtho[1,2-d][1,3]dioxol-5-yl)-3-methylpent-2-en-1-one

(2aR,2a1R,3R,5aR,8aR)-3-methoxy-2a1,6,6-trimethyl-2a,2a1,3,5a,6,7,8,8a-octahydro-2H-naphtho[1,8-bc]furan-2-one

(2aR,2a1R,3R,5aR,8aR)-3-methoxy-2a1,6,6-trimethyl-2a,2a1,3,5a,6,7,8,8a-octahydro-2H-naphtho[1,8-bc]furan-2-one

5-((tert-butyldiphenylsilyl)oxy)-1-((3aR,4S,5R,5aS,6R,9aR,9bR)-4,5-dihydroxy-6-((4-methoxybenzyl)oxy)-2,2,4,5a,9,9-hexamethyldecahydronaphtho[1,2-d][1,3]dioxol-5-yl)-3-methylpent-2-en-1-one

5-((tert-butyldiphenylsilyl)oxy)-1-((3aR,4S,5R,5aS,6R,9aR,9bR)-4,5-dihydroxy-6-((4-methoxybenzyl)oxy)-2,2,4,5a,9,9-hexamethyldecahydronaphtho[1,2-d][1,3]dioxol-5-yl)-3-methylpent-2-en-1-one

上游原料

(3aβ,,6aα,9aα,9bβ,9cβ)-1,2,3,3a,6a,9a,9b,9c-Octahydro-1,1,6,8,8,9c-hexamethyl-5H-furo[4',3',2':4,5]naphtho[1,2-d][1,3]dioxol-5-one (2aR,2a1R,3R,5aR,8aR)-3-methoxy-2a1,6,6-trimethyl-2a,2a1,3,5a,6,7,8,8a-octahydro-2H-naphtho[1,8-bc]furan-2-one (3aβ,5aβ,6aα,9aα,9bα,9cβ)-Decahydro-1,1,8,8,9c-pentamethyl-6-methylene-5H-furo[4',3',2':4,5]naphtho[1,2-d][1,3]dioxol-5-one 2,2-dimethyl-4-(3-methyl-5-oxo-2,5-dihydrofuran-2-yl)butanal

下游产品