(2S,3R,5R)-2-[[tert-butyl(dimethyl)silyl]oxymethyl]-5-(5-methyl-2,4-dioxopyrimidin-1-yl)oxolane-3-carbonitrile

CAS号：117174-39-7

英文名：(2S,3R,5R)-2-[[tert-butyl(dimethyl)silyl]oxymethyl]-5-(5-methyl-2,4-dioxopyrimidin-1-yl)oxolane-3-carbonitrile

分子式

C17H27N3O4Si

熔点

密度

1.15g/cm3

分子量

365.499

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(2S,3R,5R)-2-[[tert-butyl(dimethyl)silyl]oxymethyl]-5-(5-methyl-2,4-dioxopyrimidin-1-yl)oxolane-3-carbonitrile

英文名称

(2S,3R,5R)-2-[[tert-butyl(dimethyl)silyl]oxymethyl]-5-(5-methyl-2,4-dioxopyrimidin-1-yl)oxolane-3-carbonitrile

中文别名

英文别名

Bu2MeSiCNddT

CAS号

117174-39-7

分子式

C17H27N3O4Si

分子量

365.499

精确质量

365.177

PSA

97.37

LOGP

2.70638

物化性质

密度

1.15g/cm3

折射率

1.521

合成路线

117174-37-5

1-<3'-C-cyano-2',3'-dideoxy-5'-O-(t-butyldimethylsilyl)-β-D-threo-pentofuranosyl> thymine

117174-39-7

(2S,3R,5R)-2-[[tert-butyl(dimethyl)silyl]oxymethyl]-5-(5-methyl-2,4-dioxopyrimidin-1-yl)oxolane-3-carbonitrile

上游原料

(2R,4R,5R)-4-((tert-butyldimethylsilyl)oxy)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)tetrahydrofuran-3-carbonitrile

117174-37-5

1-<3'-C-cyano-2',3'-dideoxy-5'-O-(t-butyldimethylsilyl)-β-D-threo-pentofuranosyl> thymine

118222-09-6

O-((2R,3R,4S,5S)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-cyano-2-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)tetrahydrofuran-3-yl) O-phenyl carbonothioate

117174-34-2

1-(2',5'-di-O-(t-butyldimethylsilyl)-3'-C-cyano-3'-deoxy-β-D-xylo-pentoifuranosyl)thymine

117174-33-1

1-(2,5-bis-O-(tert-butyldimethylsilyl)-β-D-erythro-pentofuran-3-ulosyl)thymine

上游原料

叔丁基二甲基氯硅烷 (2R,4R,5R)-4-((tert-butyldimethylsilyl)oxy)-2-(((tert-butyldimethylsilyl)oxy)methyl)-3-hydroxy-5-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)tetrahydrofuran-3-carbonitrile 1-<3'-C-cyano-2',3'-dideoxy-5'-O-(t-butyldimethylsilyl)-β-D-threo-pentofuranosyl> thymine O-((2R,3R,4S,5S)-5-(((tert-butyldimethylsilyl)oxy)methyl)-4-cyano-2-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)tetrahydrofuran-3-yl) O-phenyl carbonothioate 1-(2',5'-di-O-(t-butyldimethylsilyl)-3'-C-cyano-3'-deoxy-β-D-xylo-pentoifuranosyl)thymine 1-(2,5-bis-O-(tert-butyldimethylsilyl)-β-D-erythro-pentofuran-3-ulosyl)thymine 5-甲基尿甙