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多杀霉素 A

多杀霉素 A

CAS号:131929-60-7
英文名:spinosyn A
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化合物简介
Spinosad is an insecticide based on chemical compounds found in the bacterial species Saccharopolyspora spinosa. The genus Saccharopolyspora was discovered in 1985 in isolates from crushed sugarcane which produce yellowish-pink aerial hyphae, with bead-like chains of spores enclosed in a characteristic hairy sheath. This genus is defined as aerobic, Gram-positive, nonacid-fast actinomycetes with fragmenting substrate mycelium. S. spinosa was isolated from soil collected inside a nonoperational sugar mill rum still in the Virgin Islands. Spinosad is a mixture of chemical compounds in the spinosyn family that has a generalized structure consisting of a unique tetracyclic ring system attached to an amino sugar (D-forosamine) and a neutral sugar (tri-Ο-methyl-L-rhamnose). Spinosad is relatively nonpolar and not easily dissolved in water.
基本信息
编号系统
物化性质
安全信息
生产方法及用途
用途
微生物杀虫剂,对昆虫有胃毒和触杀作用,能使多种害虫如鳞翅目幼虫、蓟马和食叶甲虫迅速死亡。主要用于果树、茶树、蔬菜、草坪等各种作物,防治线虫、蓟马、潜叶虫等众多害虫。
上游原料
(R)-3-((2R,3S,7S)-7-((tert-butyldimethylsilyl)oxy)-3-hydroxy-2-methylnonanoyl)-4-isopropyloxazolidin-2-one tert-butyl(2-((3S,3aR,5aS,7R,8aR,8bS,E)-7-((tert-butyldimethylsilyl)oxy)-2-(((tert-butyldimethylsilyl)oxy)methylene)-1,2,3,3a,5a,6,7,8,8a,8b-decahydro-as-indacen-3-yl)ethoxy)dimethylsilane (2R,3S,7S)-7-(tert-Butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-2-methyl-nonanoyl chloride (S)-5-Hydroxy-heptanoic acid methyl ester (5S)-5-[tert-butyl(dimethyl)silyl]oxyheptanal (2R,3S,3aR,5aS,7R,8aR,8bS)-2-[(2R,3S,7S)-3-(tert-butyldiphenylsiloxy)-7-hydroxy-2-methylnonanoyl]-1,2,3,3a,5a,6,7,8,8a,8b-decahydro-7-hydroxy-as-indacene-3-acetic acid κ-lactone (S)-5-(tert-Butyl-dimethyl-silanyloxy)-heptanoic acid methyl ester (3S,3aR,5aS,7R,8aR,8bS)-2-[(2R,3S,7S)-3-(tert-butyldiphenylsiloxy)-7-hydroxy-2-methylnonanoyl]-3,3a,5a,6,7,8,8a,8b-octahydro-7-hydroxy-as-indacene-3-acetic acid κ-lactone pivalate 5-氧代戊酸甲酯 (S)-1-[(3S,3aR,5aS,7R,8aR,8bS)-7-(tert-Butyl-dimethyl-silanyloxy)-3-(2-hydroxy-ethyl)-1,2,3,3a,5a,6,7,8,8a,8b-decahydro-as-indacen-2-yl]-2-methyl-nonane-1,2,7-triol 13,14β-Dihydro A83543A aglycon 9α,17α-bis-O-(TBDMS) ether 2,2-Dimethyl-propionic acid (2R,3aS,5aR,6S,8aS,8bR)-6-(2-formyloxy-ethyl)-7-oxo-1,2,3,3a,5a,6,7,8,8a,8b-decahydro-as-indacen-2-yl ester 2,2-Dimethyl-propionic acid (2R,3aS,5aR,6S,8aS,8bR)-6-[2-(4-methoxy-benzyloxy)-ethyl]-7-trifluoromethanesulfonyloxy-1,2,3,3a,5a,6,8a,8b-octahydro-as-indacen-2-yl ester Formic acid 2-((3S,3aR,5aS,7R,8aR,8bS)-7-hydroxy-2-oxo-1,2,3,3a,5a,6,7,8,8a,8b-decahydro-as-indacen-3-yl)-ethyl ester (2R,3S,7S)-7-((tert-butyldimethylsilyl)oxy)-3-((tert-butyldiphenylsilyl)oxy)-2-methylnonanoic acid