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(2Z,4Z)-N-((E)-3-((3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-3-yl)prop-1-en-1-yl)hepta-2,4-dienamide

(2Z,4Z)-N-((E)-3-((3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-3-yl)prop-1-en-1-yl)hepta-2,4-dienamide

CAS号：1350979-07-5

英文名：(2Z,4Z)-N-((E)-3-((3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-3-yl)prop-1-en-1-yl)hepta-2,4-dienamide

分子式

C31H45NO6Si

熔点

密度

分子量

555.778

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(2Z,4Z)-N-((E)-3-((3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-3-yl)prop-1-en-1-yl)hepta-2,4-dienamide

英文名称

(2Z,4Z)-N-((E)-3-((3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-3-yl)prop-1-en-1-yl)hepta-2,4-dienamide

中文别名

英文别名

CAS号

1350979-07-5

分子式

C31H45NO6Si

分子量

555.778

精确质量

555.302

PSA

94.09

LOGP

6.7351

合成路线

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(2Z,4Z)-hepta-2,4-dienoic acid amide

(2Z,4Z)-hepta-2,4-dienoic acid amide

(3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-3-((E)-3-iodoallyl)-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate

(3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-3-((E)-3-iodoallyl)-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate

(2Z,4Z)-N-((E)-3-((3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-3-yl)prop-1-en-1-yl)hepta-2,4-dienamide

(2Z,4Z)-N-((E)-3-((3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-3-yl)prop-1-en-1-yl)hepta-2,4-dienamide

上游原料

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(3R,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-1-oxo-3-(2-oxoethyl)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate

(3R,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-1-oxo-3-(2-oxoethyl)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate

(3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-3-((E)-3-iodoallyl)-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate

(3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-3-((E)-3-iodoallyl)-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate

(3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-3-(2-hydroxyethyl)-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate

(3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-3-(2-hydroxyethyl)-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate

(3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-3-(2-hydroxyethyl)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-1-one

(3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-3-(2-hydroxyethyl)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-1-one

(2Z,4Z)-hepta-2,4-dienoic acid amide

(2Z,4Z)-hepta-2,4-dienoic acid amide

(3S,5R,8S,9S)-14-(benzyloxy)-3-(2-(benzyloxy)ethyl)-8-((tert-butyldimethylsilyl)oxy)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-1-one

(3S,5R,8S,9S)-14-(benzyloxy)-3-(2-(benzyloxy)ethyl)-8-((tert-butyldimethylsilyl)oxy)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-1-one

下游产品

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11-deoxy-10-α-hydroxyapicularen A

11-deoxy-10-α-hydroxyapicularen A

上游原料

(3R,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-1-oxo-3-(2-oxoethyl)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate (3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-3-((E)-3-iodoallyl)-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate (3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-3-(2-hydroxyethyl)-1-oxo-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-14-yl acetate (3S,5R,8S,9S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-3-(2-hydroxyethyl)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-1-one (2Z,4Z)-hepta-2,4-dienoic acid amide (3S,5R,8S,9S)-14-(benzyloxy)-3-(2-(benzyloxy)ethyl)-8-((tert-butyldimethylsilyl)oxy)-3,4,5,6,7,8,9,10-octahydro-1H-5,9-epoxybenzo[c][1]oxacyclododecin-1-one

下游产品

11-deoxy-10-α-hydroxyapicularen A