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(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate
CAS号:1352916-61-0
英文名:(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate
分子式:C22H20O8
分子量:412.389
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合成路线
1352916-53-0
(1R,2R,5S,6S)-5-((tert-butoxycarbonyl)oxy)-3-(((tert-butyldimethylsilyl)oxy)methyl)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate
1352916-61-0
(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate
1352916-56-3
(1R,2R,5S,6S)-2-acetoxy-5-((tert-butoxycarbonyl)oxy)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid
1352916-61-0
(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate
1352916-42-7
(1R,5R,6R)-4-(((tert-butyldimethylsilyl)oxy)methyl)-3-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-5-hydroxy-6-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-one
1352916-61-0
(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate
1352916-43-8
(1R,2R,6R)-3-(((tert-butyldimethylsilyl)oxy)methyl)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-5-oxo-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate
1352916-61-0
(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate
1352916-44-9
(1R,2R,5S,6S)-3-(((tert-butyldimethylsilyl)oxy)methyl)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-5-hydroxy-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate
1352916-61-0
(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate
1352916-54-1
(1R,2R,5S,6S)-5-((tert-butoxycarbonyl)oxy)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-3-(hydroxymethyl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate
1352916-61-0
(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate
1352916-55-2
(1R,2R,5S,6S)-5-((tert-butoxycarbonyl)oxy)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-3-formyl-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate
1352916-61-0
(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate
1352916-41-6
tributyl(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)stannane
1352916-61-0
(1aS,2S,10R,10aR)-2,7-dihydroxy-3,8-dimethoxy-10a-methyl-9-oxo-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate
上游原料
(1R,2R,5S,6S)-5-((tert-butoxycarbonyl)oxy)-3-(((tert-butyldimethylsilyl)oxy)methyl)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate
(1R,2R,5S,6S)-3-(((tert-butyldimethylsilyl)oxy)methyl)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-5-hydroxy-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate
(1R,2R,6R)-3-(((tert-butyldimethylsilyl)oxy)methyl)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-5-oxo-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate
(1R,5R,6R)-4-(((tert-butyldimethylsilyl)oxy)methyl)-3-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-5-hydroxy-6-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-one
(1R,2R,5S,6S)-2-acetoxy-5-((tert-butoxycarbonyl)oxy)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylic acid
tributyl(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)stannane
(1R,2R,5S,6S)-5-((tert-butoxycarbonyl)oxy)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-3-formyl-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate
(1R,2R,5S,6S)-5-((tert-butoxycarbonyl)oxy)-4-(1,4-dimethoxy-5-(methoxymethoxy)naphthalen-2-yl)-3-(hydroxymethyl)-1-methyl-7-oxabicyclo[4.1.0]hept-3-en-2-yl acetate
下游产品
(1aS,2S,10R,10aR)-2,7-bis((tert-butyldiphenylsilyl)oxy)-9-diazo-10a-methyl-3,8-dioxo-1a,3,8,9,10,10a-hexahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate
(1aS,2S,10R,10aR)-2,7-bis((tert-butyldiphenylsilyl)oxy)-3,8-dimethoxy-10a-methyl-9-(2-(methylsulfonyl)hydrazineylidene)-1a,9,10,10a-tetrahydro-2H-benzo[6,7]fluoreno[2,3-b]oxiren-10-yl acetate