百科

(+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane

(+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane

CAS号：1353547-47-3

英文名：(+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane

分子式：C19H40O2Si2

分子量：356.691

合成路线

(-)-(4R,5R)-4-(bis(phenylthio)methyl)-5-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy)dihydrofuran-2(3H)-one

(-)-(4R,5R)-4-(bis(phenylthio)methyl)-5-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy)dihydrofuran-2(3H)-one

(+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane

(+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane

(+)-(R)-2-(bis(phenylthio)methyl)butane-1,4-diol

(+)-(R)-2-(bis(phenylthio)methyl)butane-1,4-diol

(+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane

(+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane

(+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane

(+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane

(+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane

(+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane

上游原料

(-)-(4R,5R)-4-(bis(phenylthio)methyl)-5-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy)dihydrofuran-2(3H)-one (+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane (+)-(R)-2-(bis(phenylthio)methyl)butane-1,4-diol

下游产品

(5R,6R)-5-[(2'E,4'E,6'S)-8'-(tert-butyldimethylsylanyloxy)-6'-(tert-butyldimethylsilanyloxymethyl)-4'-methyl-2',4'-octadienoyl]-6-[(1'S,3'R,5'E)-(1',3',5'-trimethyl-5'-heptenyl)]-5,6-dihydro-2-pyranone (+)-(S,E)-6-(2-iodoprop-1-enyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane (2E, 4E, 6S)-8-(tert-butyldimethylsilanyloxy)-6-(tert-butyldimethylsilanyloxymethyl)-4-methyl-2,4-octadienoic acid