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(5R,6R)-5-[(2'E,4'E,6'S)-8'-(tert-butyldimethylsylanyloxy)-6'-(tert-butyldimethylsilanyloxymethyl)-4'-methyl-2',4'-octadienoyl]-6-[(1'S,3'R,5'E)-(1',3',5'-trimethyl-5'-heptenyl)]-5,6-dihydro-2-pyranone

(5R,6R)-5-[(2'E,4'E,6'S)-8'-(tert-butyldimethylsylanyloxy)-6'-(tert-butyldimethylsilanyloxymethyl)-4'-methyl-2',4'-octadienoyl]-6-[(1'S,3'R,5'E)-(1',3',5'-trimethyl-5'-heptenyl)]-5,6-dihydro-2-pyranone

CAS号：848737-95-1

英文名：(5R,6R)-5-[(2'E,4'E,6'S)-8'-(tert-butyldimethylsylanyloxy)-6'-(tert-butyldimethylsilanyloxymethyl)-4'-methyl-2',4'-octadienoyl]-6-[(1'S,3'R,5'E)-(1',3',5'-trimethyl-5'-heptenyl)]-5,6-dihydro-2-pyranone

分子式

C37H66O6Si2

熔点

密度

分子量

663.087

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(5R,6R)-5-[(2'E,4'E,6'S)-8'-(tert-butyldimethylsylanyloxy)-6'-(tert-butyldimethylsilanyloxymethyl)-4'-methyl-2',4'-octadienoyl]-6-[(1'S,3'R,5'E)-(1',3',5'-trimethyl-5'-heptenyl)]-5,6-dihydro-2-pyranone

英文名称

(5R,6R)-5-[(2'E,4'E,6'S)-8'-(tert-butyldimethylsylanyloxy)-6'-(tert-butyldimethylsilanyloxymethyl)-4'-methyl-2',4'-octadienoyl]-6-[(1'S,3'R,5'E)-(1',3',5'-trimethyl-5'-heptenyl)]-5,6-dihydro-2-pyranone

中文别名

英文别名

(2E,4E)-(S)-8-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-4-methyl-octa-2,4-dienoic acid (2R,3R)-6-oxo-2-((E)-(1S,3R)-1,3,5-trimethyl-hept-5-enyl)-3,6-dihydro-2H-pyran-3-yl ester、(-)-(S,2E,4E)-((2R,3R)-2-((2S,4R,E)-4,6-dimethyloct-6-en-2-yl)-6-oxo-3,6-dihydro-2H-pyran-3-yl)8-(tert-butyldimethylsilyloxy)-6-((tert-butyldimethylsilyloxy)methyl)-4-methylocta-2,4-dienoate

CAS号

848737-95-1

分子式

C37H66O6Si2

分子量

663.087

精确质量

662.44

PSA

71.06

LOGP

9.9508

合成路线

(5R)-5-[(1R,2S,4R,6E)-(2,4,6-trimethyl-1-trimethylsilanyloxy-6-octenyl)]-2,5-dihydrofuran-2-ol

(5R)-5-[(1R,2S,4R,6E)-(2,4,6-trimethyl-1-trimethylsilanyloxy-6-octenyl)]-2,5-dihydrofuran-2-ol

(5R,6R)-5-[(2'E,4'E,6'S)-8'-(tert-butyldimethylsylanyloxy)-6'-(tert-butyldimethylsilanyloxymethyl)-4'-methyl-2',4'-octadienoyl]-6-[(1'S,3'R,5'E)-(1',3',5'-trimethyl-5'-heptenyl)]-5,6-dihydro-2-pyranone

(5R,6R)-5-[(2'E,4'E,6'S)-8'-(tert-butyldimethylsylanyloxy)-6'-(tert-butyldimethylsilanyloxymethyl)-4'-methyl-2',4'-octadienoyl]-6-[(1'S,3'R,5'E)-(1',3',5'-trimethyl-5'-heptenyl)]-5,6-dihydro-2-pyranone

上游原料

共找到24个上游原料 >

(-)-(3R,5S)-6-(tert-butyl-diphenyl-silanyloxy)-3,5-dimethyl-hexanethioic acid S-ethyl ester

(-)-(3R,5S)-6-(tert-butyl-diphenyl-silanyloxy)-3,5-dimethyl-hexanethioic acid S-ethyl ester

(-)-(1R,2S,4R,E)-1-(furan-2-yl)-2,4,6-trimethyloct-6-en-1-ol

(-)-(1R,2S,4R,E)-1-(furan-2-yl)-2,4,6-trimethyloct-6-en-1-ol

(+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane

(+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane

(-)-tert-butyl-((2S,4R)-2,4-dimethylhept-6-ynyloxy)diphenylsilane

(-)-tert-butyl-((2S,4R)-2,4-dimethylhept-6-ynyloxy)diphenylsilane

(+)-(2S,4R,E)-1-(furan-2-yl)-2,4,6-trimethyloct-6-en-1-one

(+)-(2S,4R,E)-1-(furan-2-yl)-2,4,6-trimethyloct-6-en-1-one

(+)-(S)-6-ethynyl-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane

(+)-(S)-6-ethynyl-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane

上游原料

(-)-(3R,5S)-6-(tert-butyl-diphenyl-silanyloxy)-3,5-dimethyl-hexanethioic acid S-ethyl ester (-)-(1R,2S,4R,E)-1-(furan-2-yl)-2,4,6-trimethyloct-6-en-1-ol (+)-(S)-2,2,3,3,10,10,11,11-octamethyl-6-(prop-1-ynyl)-4,9-dioxa-3,10-disiladodecane (-)-tert-butyl-((2S,4R)-2,4-dimethylhept-6-ynyloxy)diphenylsilane (+)-(2S,4R,E)-1-(furan-2-yl)-2,4,6-trimethyloct-6-en-1-one (+)-(S)-6-ethynyl-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane (R)-6-((2S,4R,E)-4,6-dimethyloct-6-en-2-yl)-2H-pyran-2,5(6H)-dione (-)-tert-butyldiphenyl((2S,4R,E)-2,4,6-trimethyloct-6-enyloxy)silane (+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane Toluene-4-sulfonic acid (S)-3-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-propyl ester (-)-(2S,4R,E)-2,4,6-trimethyloct-6-en-1-ol (2R)-2-((2S,4R,E)-4,6-dimethyloct-6-en-2-yl)-6-hydroxy-2H-pyran-3(6H)-one (+)-(R)-2-(bis(phenylthio)methyl)butane-1,4-diol (S)-4-(tert-Butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-butyronitrile (5R)-5-[(1R,2S,4R,6E)-(2,4,6-trimethyl-1-trimethylsilanyloxy-6-octenyl)]-5H-furan-2-one (S)-1,4-Bis-(tert-butyl-dimethyl-silanyloxy)-butan-2-ol (2E,4E)-(S)-8-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-4-methyl-octa-2,4-dienoic acid ethyl ester (2S,4R)-2,4,6-trimethyl-(E)-oct-6-enal (-)-tert-butyl-((2S,4R,E)-7-iodo-2,4,6-trimethylhept-6-enyloxy)diphenylsilane (2S,4R,E)-1-(furan-2-yl)-2,4,6-trimethyloct-6-en-1-ol (-)-(4R,5R)-4-(bis(phenylthio)methyl)-5-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy)dihydrofuran-2(3H)-one (+)-(S,E)-6-(2-iodoprop-1-enyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane (5R)-5-[(1R,2S,4R,6E)-(2,4,6-trimethyl-1-trimethylsilanyloxy-6-octenyl)]-2,5-dihydrofuran-2-ol (-)-(S)-4-(tert-butyl-diphenyl-silanyloxy)-3-methyl-thiobutyric acid S-ethyl ester