百科

(1R,4R,6R,7R,9R)-9-benzoyloxymethyl-7-(tert-butyldimethylsilyloxy)-4-hydroxy-2-oxa-tricyclo[4.2.1.0(4,9)]nonan-3-one

(1R,4R,6R,7R,9R)-9-benzoyloxymethyl-7-(tert-butyldimethylsilyloxy)-4-hydroxy-2-oxa-tricyclo[4.2.1.0(4,9)]nonan-3-one

CAS号：1361049-63-9

英文名：(1R,4R,6R,7R,9R)-9-benzoyloxymethyl-7-(tert-butyldimethylsilyloxy)-4-hydroxy-2-oxa-tricyclo[4.2.1.0(4,9)]nonan-3-one

分子式：C22H30O6Si

分子量：418.556

合成路线

methyl (3R,5R)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-6-heptenoate

methyl (3R,5R)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-6-heptenoate

(1R,4R,6R,7R,9R)-9-benzoyloxymethyl-7-(tert-butyldimethylsilyloxy)-4-hydroxy-2-oxa-tricyclo[4.2.1.0(4,9)]nonan-3-one

(1R,4R,6R,7R,9R)-9-benzoyloxymethyl-7-(tert-butyldimethylsilyloxy)-4-hydroxy-2-oxa-tricyclo[4.2.1.0(4,9)]nonan-3-one

(1R,3R,4R,6R,7R)-6-benzoyloxymethyl-3-(tert-butyldimethylsilyloxy)-7-hydroxy-9-oxa-tricyclo[4.3.0.0(4,7)]nonan-8-one

(1R,3R,4R,6R,7R)-6-benzoyloxymethyl-3-(tert-butyldimethylsilyloxy)-7-hydroxy-9-oxa-tricyclo[4.3.0.0(4,7)]nonan-8-one

上游原料

methyl (3R,5R)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-6-heptenoate

下游产品

((1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4S,5R,6R)-3-acetoxy-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate ((1aR,1a1R,3aR,5R,5aR)-1a-(((2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate