百科

((1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4S,5R,6R)-3-acetoxy-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

((1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4S,5R,6R)-3-acetoxy-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

CAS号：1361049-80-0

英文名：((1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4S,5R,6R)-3-acetoxy-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

分子式

C51H60O12Si

熔点

密度

分子量

893.1

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

((1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4S,5R,6R)-3-acetoxy-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

英文名称

((1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4S,5R,6R)-3-acetoxy-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

中文别名

英文别名

CAS号

1361049-80-0

分子式

C51H60O12Si

分子量

893.1

精确质量

892.385

PSA

134.28

LOGP

8.3688

合成路线

Acetic acid (3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-(2,2,2-trifluoro-N-phenyl-acetimidoyloxy)-tetrahydro-pyran-3-yl ester

Acetic acid (3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-(2,2,2-trifluoro-N-phenyl-acetimidoyloxy)-tetrahydro-pyran-3-yl ester

(1R,4R,6R,7R,9R)-9-benzoyloxymethyl-7-(tert-butyldimethylsilyloxy)-4-hydroxy-2-oxa-tricyclo[4.2.1.0(4,9)]nonan-3-one

(1R,4R,6R,7R,9R)-9-benzoyloxymethyl-7-(tert-butyldimethylsilyloxy)-4-hydroxy-2-oxa-tricyclo[4.2.1.0(4,9)]nonan-3-one

((1aR,1a1R,3aR,5R,5aR)-1a-(((2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

((1aR,1a1R,3aR,5R,5aR)-1a-(((2R,3R,4S,5R,6R)-3-acetoxy-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

((1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4S,5R,6R)-3-acetoxy-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

((1aR,1a1R,3aR,5R,5aR)-1a-(((2S,3R,4S,5R,6R)-3-acetoxy-4,5-bis(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)-5-((tert-butyldimethylsilyl)oxy)-2-oxohexahydro-3-oxacyclobuta[cd]pentalen-1a1(1H)-yl)methyl benzoate

上游原料

共找到10个上游原料 >

methyl (R)-2-((R)-2-((tert-butyldimethylsilyl)oxy)but-3-en-1-yl)-4-hydroxy-5-oxo-2,5-dihydrofuran-3-carboxylate

methyl (R)-2-((R)-2-((tert-butyldimethylsilyl)oxy)but-3-en-1-yl)-4-hydroxy-5-oxo-2,5-dihydrofuran-3-carboxylate

(R)-4-(benzyloxy)-2-((R)-2-((tert-butyldimethylsilyl)oxy)but-3-en-1-yl)-5-oxo-2,5-dihydrofuran-3-carboxylic acid

(R)-4-(benzyloxy)-2-((R)-2-((tert-butyldimethylsilyl)oxy)but-3-en-1-yl)-5-oxo-2,5-dihydrofuran-3-carboxylic acid

methyl (5R)-5-hydroxy-3-oxo-6-heptenoate

methyl (5R)-5-hydroxy-3-oxo-6-heptenoate

methyl (3R,5R)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-6-heptenoate

methyl (3R,5R)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-6-heptenoate

Acetic acid (3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-(2,2,2-trifluoro-N-phenyl-acetimidoyloxy)-tetrahydro-pyran-3-yl ester

Acetic acid (3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-(2,2,2-trifluoro-N-phenyl-acetimidoyloxy)-tetrahydro-pyran-3-yl ester

(1R,4R,6R,7R,9R)-9-benzoyloxymethyl-7-(tert-butyldimethylsilyloxy)-4-hydroxy-2-oxa-tricyclo[4.2.1.0(4,9)]nonan-3-one

(1R,4R,6R,7R,9R)-9-benzoyloxymethyl-7-(tert-butyldimethylsilyloxy)-4-hydroxy-2-oxa-tricyclo[4.2.1.0(4,9)]nonan-3-one

上游原料

methyl (R)-2-((R)-2-((tert-butyldimethylsilyl)oxy)but-3-en-1-yl)-4-hydroxy-5-oxo-2,5-dihydrofuran-3-carboxylate (R)-4-(benzyloxy)-2-((R)-2-((tert-butyldimethylsilyl)oxy)but-3-en-1-yl)-5-oxo-2,5-dihydrofuran-3-carboxylic acid methyl (5R)-5-hydroxy-3-oxo-6-heptenoate methyl (3R,5R)-5-(tert-butyldimethylsilyloxy)-3-hydroxy-6-heptenoate Acetic acid (3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-(2,2,2-trifluoro-N-phenyl-acetimidoyloxy)-tetrahydro-pyran-3-yl ester (1R,4R,6R,7R,9R)-9-benzoyloxymethyl-7-(tert-butyldimethylsilyloxy)-4-hydroxy-2-oxa-tricyclo[4.2.1.0(4,9)]nonan-3-one (5R,2'R)-3-(benzyloxy)-5-[2'-(tert-butyldimethylsilyloxy)but-3'-enyl]-4-(benzoyloxymethyl)furan-2(5H)-one (5R,2'R)-3-(benzyloxy)-5-[2'-(tert-butyldimethylsilyloxy)but-3'-enyl]-4-(methoxycarbonyl)furan-2(5H)-one methyl (3R,5R)-3,5-dihydroxy-6-heptenoate (5R,2'R)-3-(benzyloxy)-5-[2'-(tert-butyldimethylsilyloxy)but-3'-enyl]-4-(hydroxymethyl)furan-2(5H)-one