百科

(2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-9-<2-(diethylphosphono)acetoxy>-6,8-dimethoxy-2,3-<<(4-methoxyphenyl)methylene>dioxy>-4,10-dimethylundecanoic acid methyl ester

CAS号：136358-60-6

英文名：(2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-9-<2-(diethylphosphono)acetoxy>-6,8-dimethoxy-2,3-<<(4-methoxyphenyl)methylene>dioxy>-4,10-dimethylundecanoic acid methyl ester

分子式：C36H63O13PSi

分子量：762.937

合成路线

136378-85-3

<2S,3R,5S,6S,6(1S,2S)>-2,5-dimethoxy-6-<2-(benzyloxy)-1-methoxy-3-methylbutyl>-3-methyltetrahydropyran

136358-60-6

(2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-9-<2-(diethylphosphono)acetoxy>-6,8-dimethoxy-2,3-<<(4-methoxyphenyl)methylene>dioxy>-4,10-dimethylundecanoic acid methyl ester

136358-56-0

(2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-2,3,9-trihydroxy-6,8-dimethoxy-4,10-dimethylundecanoic acid methyl ester

136358-60-6

(2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-9-<2-(diethylphosphono)acetoxy>-6,8-dimethoxy-2,3-<<(4-methoxyphenyl)methylene>dioxy>-4,10-dimethylundecanoic acid methyl ester

136358-37-7

(2E,6S,7S,8R,9S)-7-hydroxy-6,8-dimethoxy-4,10-dimethyl-9-(phenylmethoxy)-2-undecenoic acid methyl ester

136358-60-6

(2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-9-<2-(diethylphosphono)acetoxy>-6,8-dimethoxy-2,3-<<(4-methoxyphenyl)methylene>dioxy>-4,10-dimethylundecanoic acid methyl ester

136358-54-8

<2R,S,3R,5S,6S,6(1S,2S)>-2-hydroxy-6-<2-(benzyloxy)-1-methoxy-3-methylbutyl>-5-methoxy-3-methyltetrahydropyran

136358-60-6

(2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-9-<2-(diethylphosphono)acetoxy>-6,8-dimethoxy-2,3-<<(4-methoxyphenyl)methylene>dioxy>-4,10-dimethylundecanoic acid methyl ester

136358-55-9

(2E,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-6,8-dimethoxy-4,10-dimethyl-9-(phenylmethoxy)-2-undecenoic acid methyl ester

136358-60-6

(2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-9-<2-(diethylphosphono)acetoxy>-6,8-dimethoxy-2,3-<<(4-methoxyphenyl)methylene>dioxy>-4,10-dimethylundecanoic acid methyl ester

136378-84-2

(2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-2,3-dihydroxy-6,8-dimethoxy-4,10-dimethyl-9-(phenylmethoxy)undecanoic acid methyl ester

136358-60-6

(2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-9-<2-(diethylphosphono)acetoxy>-6,8-dimethoxy-2,3-<<(4-methoxyphenyl)methylene>dioxy>-4,10-dimethylundecanoic acid methyl ester

上游原料

(2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-2,3,9-trihydroxy-6,8-dimethoxy-4,10-dimethylundecanoic acid methyl ester (2S,3R,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-2,3-dihydroxy-6,8-dimethoxy-4,10-dimethyl-9-(phenylmethoxy)undecanoic acid methyl ester (2E,6S,7S,8R,9S)-7-hydroxy-6,8-dimethoxy-4,10-dimethyl-9-(phenylmethoxy)-2-undecenoic acid methyl ester (2E,4R,6S,7S,8S,9S)-7-<(tert-butyldimethylsilyl)oxy>-6,8-dimethoxy-4,10-dimethyl-9-(phenylmethoxy)-2-undecenoic acid methyl ester <2R,S,3R,5S,6S,6(1S,2S)>-2-hydroxy-6-<2-(benzyloxy)-1-methoxy-3-methylbutyl>-5-methoxy-3-methyltetrahydropyran <2S,3R,5S,6S,6(1S,2S)>-2,5-dimethoxy-6-<2-(benzyloxy)-1-methoxy-3-methylbutyl>-3-methyltetrahydropyran

下游产品

(E)-(1R,9S,12R,18S,19S,20S,21S,23R)-1-Hydroxy-12-[(E)-2-((1R,3R,4R)-4-hydroxy-3-methoxy-cyclohexyl)-1-methyl-vinyl]-18-isopropyl-19,21-dimethoxy-13,13,23-trimethyl-11,17,24-trioxa-4-aza-tricyclo[18.3.1.04,9]tetracos-14-ene-2,3,10,16-tetraone