百科

methyl (2S)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-[(2R,3R,4R,5R,6S)-3,4,5,6-tetraacetyloxyoxan-2-yl]acetate

CAS号：136489-92-4

英文名：methyl (2S)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-[(2R,3R,4R,5R,6S)-3,4,5,6-tetraacetyloxyoxan-2-yl]acetate

分子式

C21H31NO13

熔点

密度

1.29g/cm3

分子量

505.47

沸点

555.4ºC at 760mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

methyl (2S)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-[(2R,3R,4R,5R,6S)-3,4,5,6-tetraacetyloxyoxan-2-yl]acetate

英文名称

methyl (2S)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-[(2R,3R,4R,5R,6S)-3,4,5,6-tetraacetyloxyoxan-2-yl]acetate

中文别名

英文别名

CAS号

136489-92-4

分子式

C21H31NO13

分子量

505.47

精确质量

505.18

PSA

182.55

LOGP

0.3402

物化性质

密度

1.29g/cm3

沸点

555.4ºC at 760mmHg

闪点

289.7ºC

折射率

1.494

蒸汽压

2.24E-12mmHg at 25°C

合成路线

95715-87-0

(R)-(+)-3-Boc-2,2-二甲基噁唑啉-4-甲醛

136489-92-4

methyl (2S)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-[(2R,3R,4R,5R,6S)-3,4,5,6-tetraacetyloxyoxan-2-yl]acetate

上游原料

(S)-tert-butyl 2,2-dimethyl-4-((2S,3S,4R,5R,6R)-3,4,5,6-tetrahydroxytetrahydro-2H-pyran-2-yl)oxazolidine-3-carboxylate

136597-89-2

(R)-2,2-Dimethyl-4-((2R,3R,4R,5R,6S)-3,4,5,6-tetraacetoxy-tetrahydro-pyran-2-yl)-oxazolidine-3-carboxylic acid tert-butyl ester

127997-06-2

6,7-N,O-Isopropylidene-6-[(tert-butoxycarbonyl)amino]-2,3,6-trideoxy-D-ribo-hept-2-enono-1,4-lactone

135086-53-2

6-deoxy-6-tert-butoxycarbonylamino-α-D-glycero-D-talo-heptopyranose tetraacetate

127997-05-1

tert-butyl (4R)-4-[(R)-hydroxy-[(2R)-5-oxo-2H-furan-2-yl]methyl]-2,2-dimethyl-1,3-oxazolidine-3-carboxylate

上游原料

重氮甲烷 (S)-tert-butyl 2,2-dimethyl-4-((2S,3S,4R,5R,6R)-3,4,5,6-tetrahydroxytetrahydro-2H-pyran-2-yl)oxazolidine-3-carboxylate (R)-2,2-Dimethyl-4-((2R,3R,4R,5R,6S)-3,4,5,6-tetraacetoxy-tetrahydro-pyran-2-yl)-oxazolidine-3-carboxylic acid tert-butyl ester 6,7-N,O-Isopropylidene-6-[(tert-butoxycarbonyl)amino]-2,3,6-trideoxy-D-ribo-hept-2-enono-1,4-lactone 6-deoxy-6-tert-butoxycarbonylamino-α-D-glycero-D-talo-heptopyranose tetraacetate tert-butyl (4R)-4-[(R)-hydroxy-[(2R)-5-oxo-2H-furan-2-yl]methyl]-2,2-dimethyl-1,3-oxazolidine-3-carboxylate 1,2,3,4-tetra-O-acetyl-6-deoxy-6-tert-butoxycarbonylamino-α-D-glycero-D-talo-heptopyranuronic acid tert-butyl 2,2-dimethyl-4-[(R)-[(2S,3S,4S)-5-oxo-3,4-bis(trimethylsilyloxy)oxolan-2-yl]-trimethylsilyloxymethyl]-1,3-oxazolidine-3-carboxylate (R)-(+)-3-Boc-2,2-二甲基噁唑啉-4-甲醛 tert-butyl (4S)-4-((1S)-((2R,3R,4R)-5-hydroxy-3,4-bis((trimethylsilyl)oxy)tetrahydrofuran-2-yl)((trimethylsilyl)oxy)methyl)-2,2-dimethyloxazolidine-3-carboxylate