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4-amino-1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ<sup>6</sup>-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidin-2-one

4-amino-1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ<sup>6</sup>-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidin-2-one

CAS号：142102-77-0

英文名：4-amino-1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ<sup>6</sup>-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidin-2-one

分子式

C24H44N4O7SSi2

熔点

密度

1.25g/cm3

分子量

588.865

沸点

620.9ºC at 760 mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

4-amino-1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ<sup>6</sup>-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidin-2-one

英文名称

4-amino-1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ<sup>6</sup>-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidin-2-one

中文别名

英文别名

TSAO-m5C、2\',5\'diSilyl-5MeSpiroC

CAS号

142102-77-0

分子式

C24H44N4O7SSi2

分子量

588.865

精确质量

588.247

PSA

167.36

LOGP

5.4659

物化性质

密度

1.25g/cm3

沸点

620.9ºC at 760 mmHg

闪点

329.3ºC

折射率

1.552

蒸汽压

2.44E-15mmHg at 25°C

合成路线

1,2-O-(异丙亚基)-alpha-D-赤式-呋喃戊-3-酮糖苯甲酸酯

1,2-O-(异丙亚基)-alpha-D-赤式-呋喃戊-3-酮糖苯甲酸酯

4-amino-1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ<sup>6</sup>-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidin-2-one

4-amino-1-[(6R,8R,9R)-4-amino-9-[tert-butyl(dimethyl)silyl]oxy-6-[[tert-butyl(dimethyl)silyl]oxymethyl]-2,2-dioxo-1,7-dioxa-2λ<sup>6</sup>-thiaspiro[4.4]non-3-en-8-yl]-5-methylpyrimidin-2-one

上游原料

共找到6个上游原料 >

(1-(β-D-ribofuranosyl)thymine)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole 2'',2''-dioxide)

(1-(β-D-ribofuranosyl)thymine)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole 2'',2''-dioxide)

1-(2'-O-acetyl-5'-O-benzoyl-3'-C-cyano-3'-O-mesyl-β-D-ribofuranosyl)thymine

1-(2'-O-acetyl-5'-O-benzoyl-3'-C-cyano-3'-O-mesyl-β-D-ribofuranosyl)thymine

1-[(5R,6R,7R,9R)-4-氨基-6-(叔丁基-二甲基硅烷基)氧基-9-[(叔丁基-二甲基硅烷基)氧基甲基]-2,2-二氧代-1,8-二氧杂-2-硫杂螺[4.4]壬-3-烯-7-基]-5-甲基嘧啶-2,4-二酮

1-[(5R,6R,7R,9R)-4-氨基-6-(叔丁基-二甲基硅烷基)氧基-9-[(叔丁基-二甲基硅烷基)氧基甲基]-2,2-二氧代-1,8-二氧杂-2-硫杂螺[4.4]壬-3-烯-7-基]-5-甲基嘧啶-2,4-二酮

1,2-O-(异丙亚基)-alpha-D-赤式-呋喃戊-3-酮糖苯甲酸酯

1,2-O-(异丙亚基)-alpha-D-赤式-呋喃戊-3-酮糖苯甲酸酯

[(6R,8R,9R)-9-acetyloxy-4-amino-8-(5-methyl-2,4-dioxopyrimidin-1-yl)-2,2-dioxo-1,7-dioxa-2λ<sup>6</sup>-thiaspiro[4.4]non-3-en-6-yl]methyl benzoate

[(6R,8R,9R)-9-acetyloxy-4-amino-8-(5-methyl-2,4-dioxopyrimidin-1-yl)-2,2-dioxo-1,7-dioxa-2λ<sup>6</sup>-thiaspiro[4.4]non-3-en-6-yl]methyl benzoate

((3aR,5R,6R,6aR)-6-cyano-6-hydroxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl benzoate

((3aR,5R,6R,6aR)-6-cyano-6-hydroxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl benzoate

上游原料

(1-(β-D-ribofuranosyl)thymine)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole 2'',2''-dioxide) 1-(2'-O-acetyl-5'-O-benzoyl-3'-C-cyano-3'-O-mesyl-β-D-ribofuranosyl)thymine 1-[(5R,6R,7R,9R)-4-氨基-6-(叔丁基-二甲基硅烷基)氧基-9-[(叔丁基-二甲基硅烷基)氧基甲基]-2,2-二氧代-1,8-二氧杂-2-硫杂螺[4.4]壬-3-烯-7-基]-5-甲基嘧啶-2,4-二酮 1,2-O-(异丙亚基)-alpha-D-赤式-呋喃戊-3-酮糖苯甲酸酯 [(6R,8R,9R)-9-acetyloxy-4-amino-8-(5-methyl-2,4-dioxopyrimidin-1-yl)-2,2-dioxo-1,7-dioxa-2λ<sup>6</sup>-thiaspiro[4.4]non-3-en-6-yl]methyl benzoate ((3aR,5R,6R,6aR)-6-cyano-6-hydroxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methyl benzoate