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2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetic acid

2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetic acid

CAS号：1444349-83-0

英文名：2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetic acid

分子式：C15H28O5Si

分子量：316.465

下游产品

(1R,2S,4R,6S,9R,13R,14S,E)-6-((tert-butyldimethylsilyl)oxy)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one

(1R,2S,4R,6S,9R,13R,14S,E)-6-((tert-butyldimethylsilyl)oxy)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one

(1R,2S,4R,9R,13R,14S,E)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-ene-6,11-dione

(1R,2S,4R,9R,13R,14S,E)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-ene-6,11-dione

(3R,4R,7S,E)-7-((tert-butyldimethylsilyl)oxy)-2-hydroxy-2,3-dimethyldeca-5,9-dien-4-yl 2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetate

(3R,4R,7S,E)-7-((tert-butyldimethylsilyl)oxy)-2-hydroxy-2,3-dimethyldeca-5,9-dien-4-yl 2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetate

(1R,5R,6E,8S,10E,12R,14S,15S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-5-((R)-3-hydroxy-3-methylbutan-2-yl)-1-methoxy-15-methyl-14-((trimethylsilyl)methyl)-4,16-dioxabicyclo[10.3.1]hexadeca-6,10-dien-3-one

(1R,5R,6E,8S,10E,12R,14S,15S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-5-((R)-3-hydroxy-3-methylbutan-2-yl)-1-methoxy-15-methyl-14-((trimethylsilyl)methyl)-4,16-dioxabicyclo[10.3.1]hexadeca-6,10-dien-3-one

(-)-amphidinolide O

(-)-amphidinolide O

(-)-amphidinolide O

(-)-amphidinolide O

(1R,2S,4R,6S,9R,13R,14S,E)-6-hydroxy-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one

(1R,2S,4R,6S,9R,13R,14S,E)-6-hydroxy-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one

(1R,2S,4R,6S,9R,13R,14S,15S,E)-6-((tert-butyldimethylsilyl)oxy)-15-hydroxy-9-((R)-3-hydroxy-3-methylbutan-2-yl)-13-methoxy-14-methyl-15-((trimethylsilyl)methyl)-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one

(1R,2S,4R,6S,9R,13R,14S,15S,E)-6-((tert-butyldimethylsilyl)oxy)-15-hydroxy-9-((R)-3-hydroxy-3-methylbutan-2-yl)-13-methoxy-14-methyl-15-((trimethylsilyl)methyl)-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one

(1R,2S,4R,6S,9R,13R,14S,15S,E)-6-((tert-butyldimethylsilyl)oxy)-15-hydroxy-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-((trimethylsilyl)methyl)-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one

(1R,2S,4R,6S,9R,13R,14S,15S,E)-6-((tert-butyldimethylsilyl)oxy)-15-hydroxy-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-((trimethylsilyl)methyl)-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one

上游原料

ethyl 2-((2R,3S,4R,6R)-4-hydroxy-2-methoxy-3-methyl-6-vinyltetrahydro-2H-pyran-2-yl)acetate ethyl 2-((2R,3S,6R)-2-methoxy-3-methyl-4-oxo-6-vinyltetrahydro-2H-pyran-2-yl)acetate (R)-5-(tert-butyldimethylsilyloxy)pent-1-en-3-ol (R)-2,2,3,3,9,9,10,10-octamethyl-5-vinyl-4,8-dioxa-3,9-disilaundecane (2S,3R,5R)-5-((tert-butyldimethylsilyl)oxy)-3-hydroxy-N-methoxy-N,2-dimethylhept-6-enamide ethyl (4S,5R,7R)-5,7-bis((tert-butyldimethylsilyl)oxy)-4-methyl-3-oxonon-8-enoate ethyl 2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetate (S)-4-benzyl-3-((2S,3R,5R)-5-((tert-butyldimethylsilyl)oxy)-3-hydroxy-2-methylhept-6-enoyl)oxazolidin-2-one (2S,3R,5R)-3,5-bis((tert-butyldimethylsilyl)oxy)-N-methoxy-N,2-dimethylhept-6-enamide (2S,3R,5R)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-methylhept-6-enal (3R)-3-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-4-penten-1-ol

下游产品

(1R,2S,4R,6S,9R,13R,14S,E)-6-((tert-butyldimethylsilyl)oxy)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one (1R,2S,4R,9R,13R,14S,E)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-ene-6,11-dione (3R,4R,7S,E)-7-((tert-butyldimethylsilyl)oxy)-2-hydroxy-2,3-dimethyldeca-5,9-dien-4-yl 2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetate (1R,5R,6E,8S,10E,12R,14S,15S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-5-((R)-3-hydroxy-3-methylbutan-2-yl)-1-methoxy-15-methyl-14-((trimethylsilyl)methyl)-4,16-dioxabicyclo[10.3.1]hexadeca-6,10-dien-3-one (-)-amphidinolide O (-)-amphidinolide O (1R,2S,4R,6S,9R,13R,14S,E)-6-hydroxy-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one (1R,2S,4R,6S,9R,13R,14S,15S,E)-6-((tert-butyldimethylsilyl)oxy)-15-hydroxy-9-((R)-3-hydroxy-3-methylbutan-2-yl)-13-methoxy-14-methyl-15-((trimethylsilyl)methyl)-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one (1R,2S,4R,6S,9R,13R,14S,15S,E)-6-((tert-butyldimethylsilyl)oxy)-15-hydroxy-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-((trimethylsilyl)methyl)-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one