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(1R,2S,4R,9R,13R,14S,E)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-ene-6,11-dione

(1R,2S,4R,9R,13R,14S,E)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-ene-6,11-dione

CAS号：1444350-56-4

英文名：(1R,2S,4R,9R,13R,14S,E)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-ene-6,11-dione

分子式

C22H30O6

熔点

密度

分子量

390.47

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(1R,2S,4R,9R,13R,14S,E)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-ene-6,11-dione

英文名称

(1R,2S,4R,9R,13R,14S,E)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-ene-6,11-dione

中文别名

英文别名

CAS号

1444350-56-4

分子式

C22H30O6

分子量

390.47

精确质量

390.204

PSA

74.36

LOGP

3.1208

合成路线

共找到2条合成路线 >

(R)-5-(tert-butyldimethylsilyloxy)pent-1-en-3-ol

(R)-5-(tert-butyldimethylsilyloxy)pent-1-en-3-ol

(1R,2S,4R,9R,13R,14S,E)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-ene-6,11-dione

(1R,2S,4R,9R,13R,14S,E)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-ene-6,11-dione

上游原料

共找到26个上游原料 >

ethyl 2-((2R,3S,6R)-2-methoxy-3-methyl-4-oxo-6-vinyltetrahydro-2H-pyran-2-yl)acetate

ethyl 2-((2R,3S,6R)-2-methoxy-3-methyl-4-oxo-6-vinyltetrahydro-2H-pyran-2-yl)acetate

(R)-5-(tert-butyldimethylsilyloxy)pent-1-en-3-ol

(R)-5-(tert-butyldimethylsilyloxy)pent-1-en-3-ol

2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetic acid

2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetic acid

(S,E)-4-((tert-butyldimethylsilyl)oxy)hepta-2,6-dienal

(S,E)-4-((tert-butyldimethylsilyl)oxy)hepta-2,6-dienal

(1R,2S)-2-((N-benzyl-2,4,6-trimethylphenyl)sulfonamido)-1-phenylpropyl (2R,3R,6S,E)-6-((tert-butyldimethylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)nona-4,8-dienoate

(1R,2S)-2-((N-benzyl-2,4,6-trimethylphenyl)sulfonamido)-1-phenylpropyl (2R,3R,6S,E)-6-((tert-butyldimethylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)nona-4,8-dienoate

(1R,2S,4R,6S,9R,13R,14S,15S,E)-6-((tert-butyldimethylsilyl)oxy)-15-hydroxy-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-((trimethylsilyl)methyl)-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one

(1R,2S,4R,6S,9R,13R,14S,15S,E)-6-((tert-butyldimethylsilyl)oxy)-15-hydroxy-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-((trimethylsilyl)methyl)-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one

下游产品

共找到2个下游商品 >

(-)-amphidinolide O

(-)-amphidinolide O

(-)-amphidinolide O

(-)-amphidinolide O

上游原料

ethyl 2-((2R,3S,6R)-2-methoxy-3-methyl-4-oxo-6-vinyltetrahydro-2H-pyran-2-yl)acetate (R)-5-(tert-butyldimethylsilyloxy)pent-1-en-3-ol 2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetic acid (S,E)-4-((tert-butyldimethylsilyl)oxy)hepta-2,6-dienal (1R,2S)-2-((N-benzyl-2,4,6-trimethylphenyl)sulfonamido)-1-phenylpropyl (2R,3R,6S,E)-6-((tert-butyldimethylsilyl)oxy)-2-methyl-3-((triethylsilyl)oxy)nona-4,8-dienoate (1R,2S,4R,6S,9R,13R,14S,15S,E)-6-((tert-butyldimethylsilyl)oxy)-15-hydroxy-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-((trimethylsilyl)methyl)-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one (S,E)-4-((tert-butyldimethylsilyl)oxy)hepta-2,6-dien-1-ol (3R)-3-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-4-penten-1-ol (S,E)-5-allyl-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodec-6-ene (4S,5E)-7-(tert-butyldimethylsilanyloxy)hepta-1,5-dien-4-ol (1R,5R,6E,8S,10E,12R,14S,15S)-8-((tert-butyldimethylsilyl)oxy)-14-hydroxy-5-((R)-3-hydroxy-3-methylbutan-2-yl)-1-methoxy-15-methyl-14-((trimethylsilyl)methyl)-4,16-dioxabicyclo[10.3.1]hexadeca-6,10-dien-3-one (2S,3R,5R)-3,5-bis((tert-butyldimethylsilyl)oxy)-N-methoxy-N,2-dimethylhept-6-enamide (1R,2S,4R,6S,9R,13R,14S,E)-6-((tert-butyldimethylsilyl)oxy)-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one ethyl 2-((2R,3S,4R,6R)-4-hydroxy-2-methoxy-3-methyl-6-vinyltetrahydro-2H-pyran-2-yl)acetate (2S,3R,5R)-5-((tert-butyldimethylsilyl)oxy)-3-hydroxy-N-methoxy-N,2-dimethylhept-6-enamide ethyl (4S,5R,7R)-5,7-bis((tert-butyldimethylsilyl)oxy)-4-methyl-3-oxonon-8-enoate (3R,4R,7S,E)-7-((tert-butyldimethylsilyl)oxy)-2,3-dimethyl-4-((triethylsilyl)oxy)deca-5,9-dien-2-ol ethyl 2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetate (1R,2S,4R,6S,9R,13R,14S,E)-6-hydroxy-13-methoxy-14-methyl-9-((S)-3-methylbut-3-en-2-yl)-15-methylene-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one (1R,2S,4R,6S,9R,13R,14S,15S,E)-6-((tert-butyldimethylsilyl)oxy)-15-hydroxy-9-((R)-3-hydroxy-3-methylbutan-2-yl)-13-methoxy-14-methyl-15-((trimethylsilyl)methyl)-3,10,17-trioxatricyclo[11.3.1.02,4]heptadec-7-en-11-one (R)-2,2,3,3,9,9,10,10-octamethyl-5-vinyl-4,8-dioxa-3,9-disilaundecane (3R,4R,7S,E)-7-((tert-butyldimethylsilyl)oxy)-2-hydroxy-2,3-dimethyldeca-5,9-dien-4-yl 2-((2R,3S,4S,6R)-4-hydroxy-2-methoxy-3-methyl-4-((trimethylsilyl)methyl)-6-vinyltetrahydro-2H-pyran-2-yl)acetate (1R,2S)-2-((N-benzyl-2,4,6-trimethylphenyl)sulfonamido)-1-phenylpropyl (2R,3R,6S,E)-6-((tert-butyldimethylsilyl)oxy)-3-hydroxy-2-methylnona-4,8-dienoate (3R,4R,7S,E)-7-((tert-butyldimethylsilyl)oxy)-2,3-dimethyldeca-5,9-diene-2,4-diol (S)-4-benzyl-3-((2S,3R,5R)-5-((tert-butyldimethylsilyl)oxy)-3-hydroxy-2-methylhept-6-enoyl)oxazolidin-2-one (2S,3R,5R)-3,5-bis((tert-butyldimethylsilyl)oxy)-2-methylhept-6-enal

下游产品

(-)-amphidinolide O (-)-amphidinolide O