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1-((1R,6R,8R,9S)-9-(benzyloxy)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-2,5,7-trioxabicyclo[4.2.1]nonan-8-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

1-((1R,6R,8R,9S)-9-(benzyloxy)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-2,5,7-trioxabicyclo[4.2.1]nonan-8-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

CAS号：1446748-45-3

英文名：1-((1R,6R,8R,9S)-9-(benzyloxy)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-2,5,7-trioxabicyclo[4.2.1]nonan-8-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

分子式

C48H48N2O10

熔点

密度

分子量

812.902

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

1-((1R,6R,8R,9S)-9-(benzyloxy)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-2,5,7-trioxabicyclo[4.2.1]nonan-8-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

英文名称

1-((1R,6R,8R,9S)-9-(benzyloxy)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-2,5,7-trioxabicyclo[4.2.1]nonan-8-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

中文别名

英文别名

CAS号

1446748-45-3

分子式

C48H48N2O10

分子量

812.902

精确质量

812.331

PSA

117.84

LOGP

6.7445

合成路线

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2-(((2R,3S,4R,5R)-3-(benzyloxy)-5-(3-((benzyloxy)methyl)-5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-2-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-4-hydroxytetrahydrofuran-2-yl)oxy)ethyl 4-methylbenzenesulfonate

2-(((2R,3S,4R,5R)-3-(benzyloxy)-5-(3-((benzyloxy)methyl)-5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-2-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-4-hydroxytetrahydrofuran-2-yl)oxy)ethyl 4-methylbenzenesulfonate

1-((1R,6R,8R,9S)-9-(benzyloxy)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-2,5,7-trioxabicyclo[4.2.1]nonan-8-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

1-((1R,6R,8R,9S)-9-(benzyloxy)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-2,5,7-trioxabicyclo[4.2.1]nonan-8-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

上游原料

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1-((2R,3R,4S,5R)-4-(benzyloxy)-5-(2-((tert-butyldimethylsilyl)oxy)ethoxy)-3-hydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

1-((2R,3R,4S,5R)-4-(benzyloxy)-5-(2-((tert-butyldimethylsilyl)oxy)ethoxy)-3-hydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

4,4'-dimethoxytrityl trifluoromethanesulfonate

4,4'-dimethoxytrityl trifluoromethanesulfonate

2-(((2R,3S,4R,5R)-3-(benzyloxy)-5-(3-((benzyloxy)methyl)-5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-2-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-4-hydroxytetrahydrofuran-2-yl)oxy)ethyl 4-methylbenzenesulfonate

2-(((2R,3S,4R,5R)-3-(benzyloxy)-5-(3-((benzyloxy)methyl)-5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-2-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-4-hydroxytetrahydrofuran-2-yl)oxy)ethyl 4-methylbenzenesulfonate

1-((2R,3R,4S)-4-(benzyloxy)-3-hydroxy-5-methylenetetrahydrofuran-2-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

1-((2R,3R,4S)-4-(benzyloxy)-3-hydroxy-5-methylenetetrahydrofuran-2-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

1-((2R,3R,4S,5R)-4-(benzyloxy)-5-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-5-(2-((tert-butyldimethylsilyl)oxy)ethoxy)-3-hydroxytetrahydrofuran-2-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

1-((2R,3R,4S,5R)-4-(benzyloxy)-5-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-5-(2-((tert-butyldimethylsilyl)oxy)ethoxy)-3-hydroxytetrahydrofuran-2-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

3-((benzyloxy)methyl)-1-((2R,3R,4S)-3,4-dihydroxy-5-methylenetetrahydrofuran-2-yl)-5-methylpyrimidine-2,4(1H,3H)-dione

3-((benzyloxy)methyl)-1-((2R,3R,4S)-3,4-dihydroxy-5-methylenetetrahydrofuran-2-yl)-5-methylpyrimidine-2,4(1H,3H)-dione

下游产品

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(1R,6R,8R,9S)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-8-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-2,5,7-trioxabicyclo[4.2.1]nonan-9-yl (2-cyanoethyl) diisopropylphosphoramidite

(1R,6R,8R,9S)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-8-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-2,5,7-trioxabicyclo[4.2.1]nonan-9-yl (2-cyanoethyl) diisopropylphosphoramidite

1-((1R,6R,8R,9S)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-9-hydroxy-2,5,7-trioxabicyclo[4.2.1]nonan-8-yl)-5-methylpyrimidine-2,4(1H,3H)-dione

1-((1R,6R,8R,9S)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-9-hydroxy-2,5,7-trioxabicyclo[4.2.1]nonan-8-yl)-5-methylpyrimidine-2,4(1H,3H)-dione

2'-O,4'-C-ethyleneoxy-5-methyluridine

2'-O,4'-C-ethyleneoxy-5-methyluridine

上游原料

1-((2R,3R,4S,5R)-4-(benzyloxy)-5-(2-((tert-butyldimethylsilyl)oxy)ethoxy)-3-hydroxy-5-(hydroxymethyl)tetrahydrofuran-2-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione 4,4'-dimethoxytrityl trifluoromethanesulfonate 2-(((2R,3S,4R,5R)-3-(benzyloxy)-5-(3-((benzyloxy)methyl)-5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-2-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-4-hydroxytetrahydrofuran-2-yl)oxy)ethyl 4-methylbenzenesulfonate 1-((2R,3R,4S)-4-(benzyloxy)-3-hydroxy-5-methylenetetrahydrofuran-2-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione 1-((2R,3R,4S,5R)-4-(benzyloxy)-5-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-5-(2-((tert-butyldimethylsilyl)oxy)ethoxy)-3-hydroxytetrahydrofuran-2-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione 3-((benzyloxy)methyl)-1-((2R,3R,4S)-3,4-dihydroxy-5-methylenetetrahydrofuran-2-yl)-5-methylpyrimidine-2,4(1H,3H)-dione 1-((2R,3R,4S,5R)-4-(benzyloxy)-5-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-3-hydroxy-5-(2-hydroxyethoxy)tetrahydrofuran-2-yl)-3-((benzyloxy)methyl)-5-methylpyrimidine-2,4(1H,3H)-dione

下游产品

(1R,6R,8R,9S)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-8-(5-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-2,5,7-trioxabicyclo[4.2.1]nonan-9-yl (2-cyanoethyl) diisopropylphosphoramidite 1-((1R,6R,8R,9S)-6-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-9-hydroxy-2,5,7-trioxabicyclo[4.2.1]nonan-8-yl)-5-methylpyrimidine-2,4(1H,3H)-dione 2'-O,4'-C-ethyleneoxy-5-methyluridine