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zaragozic acid C

zaragozic acid C

CAS号:146389-62-0
英文名:zaragozic acid C
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基本信息
上游原料
(R)-2-[(R)-Benzyloxy-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-methyl]-2-hydroxy-4-trimethylsilanyl-but-3-ynoic acid ethyl ester ethyl [2R,2(1R,2S),3S,4R]-5-benzyloxy-2-[1,2-(diethylmethylenedioxy)-3-(methoxymethoxy)propyl]-3,4-(dimethylmethylenedioxy)-2-hydroxy-3-(methylthio)carbonylpentanoate (1S,3S,4S,5R,6R,7R)-6,7-Diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-4-hydroxy-5-hydroxymethyl-4-vinyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carboxylic acid tert-butyl ester (1S,3R,4S,5R,6R,7R)-3,5-bis(((tert-butyldimethylsilyl)oxy)methyl)-4-ethynyl-1-((4R,5R)-4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-4,6,7-triol (1S,3S,4S,5R,6R,7R,4'R,5'R)-1-[4'-acetoxy-5'-methyl-6'-phenylhex-1'-yl]-3,4,5-tris(2,2-dimethylpropionyl)-4,6,7-trihydroxy-2,8-dioxabicyclo[3.2.1]octane 3-ethyl 1,2-dimethyl (1S,2S,3R,4R,5S)-4,5-(diethylmethylenedioxy)-1,2-(dimethylmethylenedioxy)-3,6-dihydroxyhexane-1,2,3-tricarboxylate (R)-9-phenyl-6-methyl-4-nonenoic acid tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,6(4E,6R),7R]-1-(4-acetoxy-5-methyl-6-phenylhexyl)-7-(tert-butoxycarbonyloxy)-4-hydroxy-6-(6-methyl-9-phenyl-4-nonenoyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate (1S,3R,4S,5R,6R,7R,4'R,5'R)-1-[4'-acetoxy-5'-methyl-6'-phenylhex-1'-yl]--6,7-bis(benzoyloxy)-4-hydroxy-3,4,5-trihydroxymethyl-2,8-dioxabicyclo[3.2.1]octane (-)-(R)-5-Phenyl-2-methylpentanal (1S,3R,4R,5S,6R,7R)-4-(benzyloxy)-3,5-bis(((tert-butyldimethylsilyl)oxy)methyl)-1-((4R,5R)-5-methyl-6-phenyl-4-(pivaloyloxy)hexyl)-2,8-dioxabicyclo[3.2.1]octane-6,7-diyl bis(2,2-dimethylpropanoate) tri-tert-butyl (1S,3S,4S,5R,6R,7R)-1-((4R,5R)-4-acetoxy-5-methyl-6-phenylhexyl)-6-(benzyloxy)-7-((tert-butoxycarbonyl)oxy)-4-hydroxy-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate di-tert-butyl (1S,3S,4S,5R,6R,7R)-6,7-diacetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenylhexyl)-4-hydroxy-4-vinyl-2,8-dioxabicyclo[3.2.1]octane-3,5-dicarboxylate (1S,3R,4S,5R,6R,7R,4'R,5'R)-1-[4'-acetoxy-5'-methyl-6'-phenylhex-1'-yl]--6,7-bis(benzoyloxy)-3,4,5-tris(benzyloxymethyl)-4-hydroxy-2,8-dioxabicyclo[3.2.1]octane (R,Z)-4-(benzyloxy)methyl-5-[methylthio(trimethylsilyloxy)methylene]-2,2-dimethyl-1,3-dioxolane (R)-4-[(1R,2S)-1-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-2-trimethylsilanyloxy-but-3-ynyl]-2,2-diethyl-[1,3]dioxolane tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-6,7-diacetoxy-1-(4-acetoxy-5-methyl-6-phenylhexyl)-4-hydroxy-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate (2S,3R)-4-benzyloxy-2,3-(dimethylmethylenedioxy)butanal 3-ethyl 1,2-dimethyl (1S,2S,3R,4R,5R,10R,11R)-10-benzyloxy-4,5-(diethylmethylenedioxy)-1,2-(dimethylmethylenedioxy)-11-methyl-6-oxo-12-phenyl-3-(trimethylsilyloxy)-7-dodecyne-1,2,3-tricarboxylate (1S,3R,4S,5R,6R,7R)-1-((4R,5R)-4-acetoxy-5-methyl-6-phenylhexyl)-4-hydroxy-3,5-bis(hydroxymethyl)-4-vinyl-2,8-dioxabicyclo[3.2.1]octane-6,7-diyl diacetate 3-ethyl 1,2-dimethyl (1S,2S,3R,4R,5R)-4,5-(diethylmethylenedioxy)-1,2-(dimethylmethylenedioxy)-5-formyl-3-(trimethylsilyloxy)pentane-1,2,3-tricarboxylate (-)-(R)-6-Methyl-9-phenyl-(E)-4-nonenoic acid ethyl ester Acetic acid (1S,3R,4S,5R,6R,7R)-7-acetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-3-hydroxymethyl-4-vinyl-2,8-dioxa-bicyclo[3.2.1]oct-6-yl ester (R)-3-((R)-(benzyloxy)((R)-2,2-diethyl-1,3-dioxolan-4-yl)methyl)-2-ethoxy-5-(trimethylsilyl)pent-1-en-4-yn-3-ol (S)-2-((R)-(benzyloxy)((R)-2,2-diethyl-1,3-dioxolan-4-yl)methyl)but-3-yne-1,2-diol (1S,3R,4S,5R,6R,7R)-3,5-bis(((tert-butyldimethylsilyl)oxy)methyl)-4-ethynyl-4-hydroxy-1-((4R,5R)-5-methyl-6-phenyl-4-(pivaloyloxy)hexyl)-2,8-dioxabicyclo[3.2.1]octane-6,7-diyl bis(2,2-dimethylpropanoate) Zaragozic acid C 3,4,5-tris-tert-butyl ester (1S,3R,4S,5R,6R,7R)-1-((4R,5R)-4-acetoxy-5-methyl-6-phenylhexyl)-3,5-bis(((tert-butyldimethylsilyl)oxy)methyl)-4-ethynyl-4-hydroxy-2,8-dioxabicyclo[3.2.1]octane-6,7-diyl diacetate S-methyl (2S,3R)-4-benzyloxy-2,3-(dimethylmethylenedioxy)butanethioate 3-ethyl 1,2-dimethyl (1S,2S,3R,4R,5S)-4,5-(diethylmethylenedioxy)-1,2-(dimethylmethylenedioxy)-6-hydroxy-3-(trimethylsilyloxy)hexane-1,2,3-tricarboxylate (1S,3R,5R,6R,7R)-3,5-bis(((tert-butyldimethylsilyl)oxy)methyl)-1-((4R,5R)-5-methyl-6-phenyl-4-(pivaloyloxy)hexyl)-4-oxo-2,8-dioxabicyclo[3.2.1]octane-6,7-diyl bis(2,2-dimethylpropanoate) (2S,3R)-4-benzyloxy-2,3-(dimethylmethylenedioxy)butyric acid tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-1-(4-acetoxy-5-methyl-6-phenylhexyl)-7-(tert-butoxycarbonyl)oxy-4,6-dihydroxy-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate (S)-2-((R)-(benzyloxy)((R)-2,2-diethyl-1,3-dioxolan-4-yl)methyl)-4-(trimethylsilyl)but-3-yne-1,2-diol (1S,3S,4S,5R,6R,7R)-1-((4R,5R)-4-acetoxy-5-methyl-6-phenylhexyl)-3,4,5-triformyl-4-hydroxy-2,8-dioxabicyclo[3.2.1]octane-6,7-diyl dibenzoate 2,2-Dimethyl-propionic acid (R)-4-[(1S,3R,4R,5R,6R,7R)-4-benzyloxy-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-6,7-dihydroxy-2,8-dioxa-bicyclo[3.2.1]oct-1-yl]-1-((R)-1-methyl-2-phenyl-ethyl)-butyl ester (1S,3R,4R,5S,6R,7R)-3,5-bis(((tert-butyldimethylsilyl)oxy)methyl)-4-hydroxy-1-((4R,5R)-5-methyl-6-phenyl-4-(pivaloyloxy)hexyl)-2,8-dioxabicyclo[3.2.1]octane-6,7-diyl bis(2,2-dimethylpropanoate) (2R,3R,10S,11R)-11-(benzyloxy)-10-(((tert-butyldimethylsilyl)oxy)methyl)-11-((R)-2,2-diethyl-1,3-dioxolan-4-yl)-2-methyl-7-oxo-1-phenyl-10-((trimethylsilyl)oxy)undec-8-yn-3-yl pivalate 2,2-Dimethyl-propionic acid (E)-(1R,8S,9R)-9-benzyloxy-9-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-8-hydroxy-8-hydroxymethyl-1-((R)-1-methyl-2-phenyl-ethyl)-5-oxo-non-6-enyl ester (1S,3S,4S,5R,6R,7R)-1-((4R,5R)-4-acetoxy-5-methyl-6-phenylhexyl)-3,5-diformyl-4-hydroxy-4-vinyl-2,8-dioxabicyclo[3.2.1]octane-6,7-diyl diacetate 3-ethyl 1,2-dimethyl (1S,2S,3R,4R,5R,10R,11R)-10-benzyloxy-4,5-(diethylmethylenedioxy)-1,2-(dimethylmethylenedioxy)-11-methyl-6-oxo-12-phenyl-3-(trimethylsilyloxy)dodecane-1,2,3-tricarboxylate (1S,3S,4S,5R,6R,7R)-1-((4R,5R)-4-acetoxy-5-methyl-6-phenylhexyl)-3-(tert-butoxycarbonyl)-5-formyl-4-hydroxy-4-vinyl-2,8-dioxabicyclo[3.2.1]octane-6,7-diyl diacetate