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(3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,9-dioxo-10-triethylsilyloxy-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)diyl diacetate

(3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,9-dioxo-10-triethylsilyloxy-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)diyl diacetate

CAS号：155588-15-1

英文名：(3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,9-dioxo-10-triethylsilyloxy-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)diyl diacetate

分子式

C31H46O10Si

熔点

密度

分子量

606.776

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,9-dioxo-10-triethylsilyloxy-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)diyl diacetate

英文名称

(3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,9-dioxo-10-triethylsilyloxy-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)diyl diacetate

中文别名

英文别名

CAS号

155588-15-1

分子式

C31H46O10Si

分子量

606.776

精确质量

606.286

PSA

123.66

LOGP

5.0288

合成路线

共找到6条合成路线 >

(3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,5,9-trioxo-10-((triethylsilyl)oxy)-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)-diyl diacetate

(3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,5,9-trioxo-10-((triethylsilyl)oxy)-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)-diyl diacetate

(3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,9-dioxo-10-triethylsilyloxy-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)diyl diacetate

(3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,9-dioxo-10-triethylsilyloxy-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)diyl diacetate

上游原料

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(3aS,8R,9aS,10S,12S,13S,13aR,13bS)-12,13-dihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-13-(((trimethylsilyl)oxy)methyl)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-8-yl acetate

(3aS,8R,9aS,10S,12S,13S,13aR,13bS)-12,13-dihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-13-(((trimethylsilyl)oxy)methyl)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-8-yl acetate

(S)-3-(Chloromethyl-dimethyl-silanyloxy)-2,2-dimethyl-cyclohexanone

(S)-3-(Chloromethyl-dimethyl-silanyloxy)-2,2-dimethyl-cyclohexanone

(S)-7-Iodo-2,2,6,6,8-pentamethyl-1,3-dioxa-spiro[4.5]dec-7-ene

(S)-7-Iodo-2,2,6,6,8-pentamethyl-1,3-dioxa-spiro[4.5]dec-7-ene

(3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,5,9-trioxo-10-((triethylsilyl)oxy)-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)-diyl diacetate

(3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,5,9-trioxo-10-((triethylsilyl)oxy)-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)-diyl diacetate

((3aS,8R,9aS,10S,12S,13S,13aR,13bS)-8-acetoxy-13-hydroxy-6,9a,14,14-tetramethyl-12-((methylsulfonyl)oxy)-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-yl)methyl acetate

((3aS,8R,9aS,10S,12S,13S,13aR,13bS)-8-acetoxy-13-hydroxy-6,9a,14,14-tetramethyl-12-((methylsulfonyl)oxy)-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-yl)methyl acetate

3-bromo-2,2,4-trimethylcyclohex-3-ene carbonyl chloride

3-bromo-2,2,4-trimethylcyclohex-3-ene carbonyl chloride

下游产品

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(3aS,8R,9aS,10S,12S,13S,13aR,13bS)-12,13-dihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-13-(((trimethylsilyl)oxy)methyl)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-8-yl acetate

(3aS,8R,9aS,10S,12S,13S,13aR,13bS)-12,13-dihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-13-(((trimethylsilyl)oxy)methyl)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-8-yl acetate

((3aS,8R,9aS,10S,12S,13S,13aR,13bS)-8-acetoxy-12,13-dihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-yl)methyl acetate

((3aS,8R,9aS,10S,12S,13S,13aR,13bS)-8-acetoxy-12,13-dihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-yl)methyl acetate

(3aS,8R,9aS,10S,12S,13S,13aR,13bS)-13-hydroxy-13-(hydroxymethyl)-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-8,12-diyl diacetate

(3aS,8R,9aS,10S,12S,13S,13aR,13bS)-13-hydroxy-13-(hydroxymethyl)-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-8,12-diyl diacetate

(3aS,8R,9aS,10S,12S,13S,13aR,13bS)-13-hydroxy-6,9a,14,14-tetramethyl-13-(((methylsulfonyl)oxy)methyl)-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-8,12-diyl diacetate

(3aS,8R,9aS,10S,12S,13S,13aR,13bS)-13-hydroxy-6,9a,14,14-tetramethyl-13-(((methylsulfonyl)oxy)methyl)-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-8,12-diyl diacetate

((3aS,8R,9aS,10S,12S,13S,13aR,13bS)-8-acetoxy-10,12,13-trihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-yl)methyl acetate

((3aS,8R,9aS,10S,12S,13S,13aR,13bS)-8-acetoxy-10,12,13-trihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-yl)methyl acetate

(2S,3a'S,8'R,9a'S,10'S,12'S,13a'R,13b'S)-6',9a',14',14'-tetramethyl-2',9'-dioxo-10'-((triethylsilyl)oxy)-4',5',8',9',9a',10',11',12',13a',13b'-decahydrospiro[oxirane-2,13'-[3a,7]methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole]-8',12'-diyl diacetate

(2S,3a'S,8'R,9a'S,10'S,12'S,13a'R,13b'S)-6',9a',14',14'-tetramethyl-2',9'-dioxo-10'-((triethylsilyl)oxy)-4',5',8',9',9a',10',11',12',13a',13b'-decahydrospiro[oxirane-2,13'-[3a,7]methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole]-8',12'-diyl diacetate

上游原料

(3aS,8R,9aS,10S,12S,13S,13aR,13bS)-12,13-dihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-13-(((trimethylsilyl)oxy)methyl)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-8-yl acetate (S)-3-(Chloromethyl-dimethyl-silanyloxy)-2,2-dimethyl-cyclohexanone (S)-7-Iodo-2,2,6,6,8-pentamethyl-1,3-dioxa-spiro[4.5]dec-7-ene (3aS,8R,9aS,10S,11aR,13aS,13bR,13cS)-6,9a,14,14-tetramethyl-2,5,9-trioxo-10-((triethylsilyl)oxy)-4,5,8,9,9a,10,11,11a,13b,13c-decahydro-3a,7-methanooxeto[2'',3'':5',6']benzo[1',2':3,4]cyclodeca[1,2-d][1,3]dioxole-8,13a(13H)-diyl diacetate ((3aS,8R,9aS,10S,12S,13S,13aR,13bS)-8-acetoxy-13-hydroxy-6,9a,14,14-tetramethyl-12-((methylsulfonyl)oxy)-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-yl)methyl acetate 3-bromo-2,2,4-trimethylcyclohex-3-ene carbonyl chloride (5S)-7-iodo-6,6,8-trimethyl-2-phenyl-1,3-dioxaspiro[4.5]dec-7-ene (2aR,4S,4aS,6R,11S,12S,12aR,12bS)-12-benzoyloxy-11-hydroxy-4a,8,13,13-tetramethyl-5-oxo-4-triethylsilyloxy-3,4,4a,5,6,9,10,11,12,12a-decahydro-1H-7,11-methanocyclodeca[3,4]benzo[1,2-b]oxete-6,12b(2aH)diyl diacetate (1S,5S)-3,3,9,9-Tetramethyl-2-oxa-3-sila-bicyclo[3.3.1]nonan-5-ol (S)-1-Hydroxymethyl-3-iodo-2,2,4-trimethyl-cyclohex-3-enol (S)-1-(benzyloxy)-3-iodo-2,2,4-trimethylcyclohex-3-ene-1-carbaldehyde

下游产品

(3aS,8R,9aS,10S,12S,13S,13aR,13bS)-12,13-dihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-13-(((trimethylsilyl)oxy)methyl)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-8-yl acetate ((3aS,8R,9aS,10S,12S,13S,13aR,13bS)-8-acetoxy-12,13-dihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-yl)methyl acetate (3aS,8R,9aS,10S,12S,13S,13aR,13bS)-13-hydroxy-13-(hydroxymethyl)-6,9a,14,14-tetramethyl-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-8,12-diyl diacetate (3aS,8R,9aS,10S,12S,13S,13aR,13bS)-13-hydroxy-6,9a,14,14-tetramethyl-13-(((methylsulfonyl)oxy)methyl)-2,9-dioxo-10-((triethylsilyl)oxy)-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole-8,12-diyl diacetate ((3aS,8R,9aS,10S,12S,13S,13aR,13bS)-8-acetoxy-10,12,13-trihydroxy-6,9a,14,14-tetramethyl-2,9-dioxo-5,8,9,9a,10,11,12,13,13a,13b-decahydro-4H-3a,7-methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxol-13-yl)methyl acetate (2S,3a'S,8'R,9a'S,10'S,12'S,13a'R,13b'S)-6',9a',14',14'-tetramethyl-2',9'-dioxo-10'-((triethylsilyl)oxy)-4',5',8',9',9a',10',11',12',13a',13b'-decahydrospiro[oxirane-2,13'-[3a,7]methanobenzo[3,4]cyclodeca[1,2-d][1,3]dioxole]-8',12'-diyl diacetate