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Acetic acid (1S,3R,4S,5R,6R,7R)-7-acetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-3-hydroxymethyl-4-vinyl-2,8-dioxa-bicyclo[3.2.1]oct-6-yl ester

CAS号：164215-46-7

英文名：Acetic acid (1S,3R,4S,5R,6R,7R)-7-acetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-3-hydroxymethyl-4-vinyl-2,8-dioxa-bicyclo[3.2.1]oct-6-yl ester

分子式：C35H54O11Si

分子量：678.882

合成路线

164215-28-5

(R)-2-[(R)-Benzyloxy-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-methyl]-2-hydroxy-4-trimethylsilanyl-but-3-ynoic acid ethyl ester

164215-46-7

Acetic acid (1S,3R,4S,5R,6R,7R)-7-acetoxy-1-((4R,5R)-4-acetoxy-5-methyl-6-phenyl-hexyl)-5-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-3-hydroxymethyl-4-vinyl-2,8-dioxa-bicyclo[3.2.1]oct-6-yl ester

164215-30-9

(R)-4-[(1R,2S)-1-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-2-trimethylsilanyloxy-but-3-ynyl]-2,2-diethyl-[1,3]dioxolane

164215-46-7

164215-35-4

2,2-Dimethyl-propionic acid (E)-(1R,8S,9R)-9-benzyloxy-9-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-8-hydroxy-8-hydroxymethyl-1-((R)-1-methyl-2-phenyl-ethyl)-5-oxo-non-6-enyl ester

164215-46-7

164215-37-6

2,2-Dimethyl-propionic acid (R)-4-[(1S,3R,4R,5R,6R,7R)-4-benzyloxy-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-6,7-dihydroxy-2,8-dioxa-bicyclo[3.2.1]oct-1-yl]-1-((R)-1-methyl-2-phenyl-ethyl)-butyl ester

164215-46-7

上游原料

(R)-4-[(1R,2S)-1-Benzyloxy-2-(tert-butyl-dimethyl-silanyloxymethyl)-2-trimethylsilanyloxy-but-3-ynyl]-2,2-diethyl-[1,3]dioxolane 2,2-Dimethyl-propionic acid (E)-(1R,8S,9R)-9-benzyloxy-9-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-8-hydroxy-8-hydroxymethyl-1-((R)-1-methyl-2-phenyl-ethyl)-5-oxo-non-6-enyl ester 2,2-Dimethyl-propionic acid (R)-4-[(1S,3R,4R,5R,6R,7R)-4-benzyloxy-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-6,7-dihydroxy-2,8-dioxa-bicyclo[3.2.1]oct-1-yl]-1-((R)-1-methyl-2-phenyl-ethyl)-butyl ester (R)-2-[(R)-Benzyloxy-((R)-2,2-diethyl-[1,3]dioxolan-4-yl)-methyl]-2-hydroxy-4-trimethylsilanyl-but-3-ynoic acid ethyl ester

下游产品

zaragozic acid C tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,6(4E,6R),7R]-1-(4-acetoxy-5-methyl-6-phenylhexyl)-7-(tert-butoxycarbonyloxy)-4-hydroxy-6-(6-methyl-9-phenyl-4-nonenoyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate