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(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol
CAS号:170309-32-7
英文名:(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol
分子式:C26H46O3Si
分子量:434.727
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合成路线
368869-13-0
(1R,3R,3aR,7R,7aR)-2-(3-{7-isopropyl-4-methyl-3-[3-(trimethylsilyl)prop-2-ynyl]-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl}-3(2S,3R)-methyloxiranyl)ethanol
170309-32-7
(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol
170309-21-4
(5R)-3-iodo-5-isopropyl-2-methylcyclohexa-1,3-diene
170309-32-7
(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol
368869-09-4
(E)-2-methyl-5-(triisopropylsilyloxy)pent-2-enal
170309-32-7
(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol
368869-04-9
(1R,3R,3aR,7R,7aR)-3-{7-isopropyl-4-methyl-3-[3-(trimethylsilyl)prop-2-ynyl]-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl}-3(2S,3R)-methyloxiranylmethanol
170309-32-7
(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol
368869-21-0
(1R,3R,3aS,7R,7aR)-1-((E)-4-Hydroxy-1-methyl-but-1-enyl)-7-isopropyl-4-methyl-3-(3-trimethylsilanyl-prop-2-ynyl)-1,6,7,7a-tetrahydro-isobenzofuran-3a-carbaldehyde
170309-32-7
(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol
294674-48-9
(R)-4-((R)-3-Isopropyl-6-methyl-cyclohexa-1,5-dienyl)-2-((Z)-1-methyl-4-triisopropylsilanyloxy-but-1-enyl)-5-(3-trimethylsilanyl-prop-2-ynyl)-[1,3]dioxolane
170309-32-7
(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol
368869-10-7
(1R,3R,3aS,7R,7aR)-7-isopropyl-4-methyl-1-[(E)-1-methyl-4-(triisopropylsilyloxy)but-1-enyl]-3-[3-(trimethylsilyl)prop-2-ynyl]-1,6,7,7a-tetrahydroisobenzofuran-3a-carbaldehyde
170309-32-7
(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol
368869-14-1
(R)-4-((1R,3R,3aR,7R,7aR)-7-Isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydro-isobenzofuran-1-yl)-pentane-1,4-diol
170309-32-7
(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol
294674-54-7
2,2-Dimethyl-propionic acid (R)-4-(tert-butyl-dimethyl-silanyloxy)-4-((1R,3R,3aR,7R,7aR)-7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydro-isobenzofuran-1-yl)-pentyl ester
170309-32-7
(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol
上游原料
2,2-Dimethyl-propionic acid (R)-4-(tert-butyl-dimethyl-silanyloxy)-4-((1R,3R,3aR,7R,7aR)-7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydro-isobenzofuran-1-yl)-pentyl ester
(1R,3R,3aR,7R,7aR)-2-(3-{7-isopropyl-4-methyl-3-[3-(trimethylsilyl)prop-2-ynyl]-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl}-3(2S,3R)-methyloxiranyl)ethanol
(R)-4-((1R,3R,3aR,7R,7aR)-7-Isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydro-isobenzofuran-1-yl)-pentane-1,4-diol
(1R,3R,3aS,7R,7aR)-1-((E)-4-Hydroxy-1-methyl-but-1-enyl)-7-isopropyl-4-methyl-3-(3-trimethylsilanyl-prop-2-ynyl)-1,6,7,7a-tetrahydro-isobenzofuran-3a-carbaldehyde
(R)-4-((R)-3-Isopropyl-6-methyl-cyclohexa-1,5-dienyl)-2-((Z)-1-methyl-4-triisopropylsilanyloxy-but-1-enyl)-5-(3-trimethylsilanyl-prop-2-ynyl)-[1,3]dioxolane
(E)-2-methyl-5-(triisopropylsilyloxy)pent-2-enal
(1R,3R,3aR,7R,7aR)-3-{7-isopropyl-4-methyl-3-[3-(trimethylsilyl)prop-2-ynyl]-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl}-3(2S,3R)-methyloxiranylmethanol
(1R,3R,3aS,7R,7aR)-7-isopropyl-4-methyl-1-[(E)-1-methyl-4-(triisopropylsilyloxy)but-1-enyl]-3-[3-(trimethylsilyl)prop-2-ynyl]-1,6,7,7a-tetrahydroisobenzofuran-3a-carbaldehyde
(5R)-3-iodo-5-isopropyl-2-methylcyclohexa-1,3-diene
下游产品
(3R,7R,8R,10S,11S,14R,15R,16R)-14-(tert-butyldimethylsiloxy)-3-isopropyl-6,10,14-trimethyl-15-oxatricyclo[6.6.1.00,0]pentadec-5-ene-10,11-diol
(1'R,2R,4a'R,5'R,8'S,11'R,12'R,12a'R)-11'-((tert-butyldimethylsilyl)oxy)-1'-isopropyl-4',11'-dimethyl-2',4a',5',6',8',9',10',11',12',12a'-decahydro-1'H-spiro[oxirane-2,7'-[5,12]epoxybenzo[10]annulen]-8'-ol