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(1'R,2R,4a'R,5'R,8'S,11'R,12'R,12a'R)-11'-((tert-butyldimethylsilyl)oxy)-1'-isopropyl-4',11'-dimethyl-2',4a',5',6',8',9',10',11',12',12a'-decahydro-1'H-spiro[oxirane-2,7'-[5,12]epoxybenzo[10]annulen]-8'-ol

(1'R,2R,4a'R,5'R,8'S,11'R,12'R,12a'R)-11'-((tert-butyldimethylsilyl)oxy)-1'-isopropyl-4',11'-dimethyl-2',4a',5',6',8',9',10',11',12',12a'-decahydro-1'H-spiro[oxirane-2,7'-[5,12]epoxybenzo[10]annulen]-8'-ol

CAS号：321199-06-8

英文名：(1'R,2R,4a'R,5'R,8'S,11'R,12'R,12a'R)-11'-((tert-butyldimethylsilyl)oxy)-1'-isopropyl-4',11'-dimethyl-2',4a',5',6',8',9',10',11',12',12a'-decahydro-1'H-spiro[oxirane-2,7'-[5,12]epoxybenzo[10]annulen]-8'-ol

分子式

C26H46O4Si

熔点

密度

分子量

450.727

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(1'R,2R,4a'R,5'R,8'S,11'R,12'R,12a'R)-11'-((tert-butyldimethylsilyl)oxy)-1'-isopropyl-4',11'-dimethyl-2',4a',5',6',8',9',10',11',12',12a'-decahydro-1'H-spiro[oxirane-2,7'-[5,12]epoxybenzo[10]annulen]-8'-ol

英文名称

(1'R,2R,4a'R,5'R,8'S,11'R,12'R,12a'R)-11'-((tert-butyldimethylsilyl)oxy)-1'-isopropyl-4',11'-dimethyl-2',4a',5',6',8',9',10',11',12',12a'-decahydro-1'H-spiro[oxirane-2,7'-[5,12]epoxybenzo[10]annulen]-8'-ol

中文别名

英文别名

CAS号

321199-06-8

分子式

C26H46O4Si

分子量

450.727

精确质量

450.317

PSA

51.22

LOGP

5.7027

合成路线

共找到1条合成路线 >

(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol

(3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol

(1'R,2R,4a'R,5'R,8'S,11'R,12'R,12a'R)-11'-((tert-butyldimethylsilyl)oxy)-1'-isopropyl-4',11'-dimethyl-2',4a',5',6',8',9',10',11',12',12a'-decahydro-1'H-spiro[oxirane-2,7'-[5,12]epoxybenzo[10]annulen]-8'-ol

(1'R,2R,4a'R,5'R,8'S,11'R,12'R,12a'R)-11'-((tert-butyldimethylsilyl)oxy)-1'-isopropyl-4',11'-dimethyl-2',4a',5',6',8',9',10',11',12',12a'-decahydro-1'H-spiro[oxirane-2,7'-[5,12]epoxybenzo[10]annulen]-8'-ol

上游原料

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(Z)-(4-iodopent-3-enyloxy)triisopropylsilane

(Z)-(4-iodopent-3-enyloxy)triisopropylsilane

2,2-dimethylpropionic acid (1R,3R,3aR,7R,7aR)-3(R)-hydroxy-3-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)butyl ester

2,2-dimethylpropionic acid (1R,3R,3aR,7R,7aR)-3(R)-hydroxy-3-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)butyl ester

(Z)-2-methyl-5-(triisopropylsilyloxy)pent-2-enal

(Z)-2-methyl-5-(triisopropylsilyloxy)pent-2-enal

(1R,3R,3aS,7R,7aR)-1-((E)-4-Hydroxy-1-methyl-but-1-enyl)-7-isopropyl-4-methyl-3-(3-trimethylsilanyl-prop-2-ynyl)-1,6,7,7a-tetrahydro-isobenzofuran-3a-carbaldehyde

(1R,3R,3aS,7R,7aR)-1-((E)-4-Hydroxy-1-methyl-but-1-enyl)-7-isopropyl-4-methyl-3-(3-trimethylsilanyl-prop-2-ynyl)-1,6,7,7a-tetrahydro-isobenzofuran-3a-carbaldehyde

(R)-4-((R)-3-Isopropyl-6-methyl-cyclohexa-1,5-dienyl)-2-((Z)-1-methyl-4-triisopropylsilanyloxy-but-1-enyl)-5-(3-trimethylsilanyl-prop-2-ynyl)-[1,3]dioxolane

(R)-4-((R)-3-Isopropyl-6-methyl-cyclohexa-1,5-dienyl)-2-((Z)-1-methyl-4-triisopropylsilanyloxy-but-1-enyl)-5-(3-trimethylsilanyl-prop-2-ynyl)-[1,3]dioxolane

(1R,3R,3aS,7R,7aR)-7-isopropyl-4-methyl-1-[(E)-1-methyl-3-(triisopropylsilyloxy)propenyl]-3-[3-(trimethylsilyl)prop-2-ynyl]-1,6,7,7a-tetrahydroisobenzofuran-3a-carbaldehyde

(1R,3R,3aS,7R,7aR)-7-isopropyl-4-methyl-1-[(E)-1-methyl-3-(triisopropylsilyloxy)propenyl]-3-[3-(trimethylsilyl)prop-2-ynyl]-1,6,7,7a-tetrahydroisobenzofuran-3a-carbaldehyde

下游产品

共找到1个下游商品 >

(3R,7R,8R,10S,11S,14R,15R,16R)-14-(tert-butyldimethylsiloxy)-3-isopropyl-6,10,14-trimethyl-15-oxatricyclo[6.6.1.00,0]pentadec-5-ene-10,11-diol

(3R,7R,8R,10S,11S,14R,15R,16R)-14-(tert-butyldimethylsiloxy)-3-isopropyl-6,10,14-trimethyl-15-oxatricyclo[6.6.1.00,0]pentadec-5-ene-10,11-diol

上游原料

(Z)-(4-iodopent-3-enyloxy)triisopropylsilane 2,2-dimethylpropionic acid (1R,3R,3aR,7R,7aR)-3(R)-hydroxy-3-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)butyl ester (Z)-2-methyl-5-(triisopropylsilyloxy)pent-2-enal (1R,3R,3aS,7R,7aR)-1-((E)-4-Hydroxy-1-methyl-but-1-enyl)-7-isopropyl-4-methyl-3-(3-trimethylsilanyl-prop-2-ynyl)-1,6,7,7a-tetrahydro-isobenzofuran-3a-carbaldehyde (R)-4-((R)-3-Isopropyl-6-methyl-cyclohexa-1,5-dienyl)-2-((Z)-1-methyl-4-triisopropylsilanyloxy-but-1-enyl)-5-(3-trimethylsilanyl-prop-2-ynyl)-[1,3]dioxolane (1R,3R,3aS,7R,7aR)-7-isopropyl-4-methyl-1-[(E)-1-methyl-3-(triisopropylsilyloxy)propenyl]-3-[3-(trimethylsilyl)prop-2-ynyl]-1,6,7,7a-tetrahydroisobenzofuran-3a-carbaldehyde (E)-2-methyl-4-(triisopropylsilyloxy)-but-2-enal 2,2-dimethylpropionic acid (1R,3R,3aR,7R,7aR)-3(R)-(tert-butyldimethylsilyloxy)-3-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)-butyl ester (E)-2-methyl-5-(triisopropylsilyloxy)pent-2-enal (1R,3R,3aR,7R,7aR)-3-{7-isopropyl-4-methyl-3-[3-(trimethylsilyl)prop-2-ynyl]-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl}-3(2S,3R)-methyloxiranylmethanol (1R,3R,3aR,7R,7aR)-3-[7-isopropyl-4-methyl-3-[3-(trimethylsilyl)prop-2-ynyl]-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl]-(E)-but-2-en-1-ol (R)-3-(tert-Butyl-dimethyl-silanyloxy)-3-[(1R,3R,3aR,7R,7aR)-3-(2-iodo-allyl)-7-isopropyl-4-methyl-1,3,3a,6,7,7a-hexahydro-isobenzofuran-1-yl]-butan-1-ol 2,2-dimethlpropionic acid (1R,3R,3aR,7R,7aR)-3(R)-(tert-butyldimethylsilyloxy)-3-[3-(2-iodoallyl)-7-isopropyl-4-methyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl]butyl ester (5R)-3-iodo-5-isopropyl-2-methylcyclohexa-1,3-diene (1R,3R,3aS,7R,7aR)-7-isopropyl-4-methyl-1-[(Z)-1-methyl-4-(triisopropylsilyloxy)but-1-enyl]-3-[3-(trimethylsilyl)prop-2-ynyl]-1,6,7,7a-tetrahydroisobenzofuran-3a-carbaldehyde (1R,3R,3aR,7R,7aR)-2-(3-{7-isopropyl-4-methyl-3-[3-(trimethylsilyl)prop-2-ynyl]-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl}-3(2S,3R)-methyloxiranyl)ethanol (1R,3R,3aS,7R,7aR)-1-((E)-3-Hydroxy-1-methyl-propenyl)-7-isopropyl-4-methyl-3-(3-trimethylsilanyl-prop-2-ynyl)-1,6,7,7a-tetrahydro-isobenzofuran-3a-carbaldehyde (1R,3R,3aR,7R,7aR)-4-isopropyl-7-methyl-3-[(Z)-1-methyl-4-(triisopropylsilyloxy)-but-1-enyl]-1-[3-(trimethylsilyl)prop-2-ynyl]-1,3,3a,5,7a-hexahydroisobenzofuran 3-methyl-1-triisopropylsiloxy-2-butene (1R,3R,3aR,7R,7aR)-4-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,5,7a-hexahydroisobenzofuran-1-yl)-(Z)-pent-3-ene-1-ol (3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-ol (1R,3R,3aR,7R,7aR)-2-[3-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)-3(2R,3R)-methyloxiranyl]-ethanol (1R,3R,3aR,7R,7aR)-4(R)-(tert-butyldimethylsilyloxy)-4-[3-(2-iodoally)-7-isopropyl-4-methyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl]pentanal (1R,3R,3aS,7R,7aR)-7-isopropyl-4-methyl-1-[(E)-1-methyl-4-(triisopropylsilyloxy)but-1-enyl]-3-[3-(trimethylsilyl)prop-2-ynyl]-1,6,7,7a-tetrahydroisobenzofuran-3a-carbaldehyde (1R,3R,3aR,7R,7aR)-4(R)-(tert-butyldimethylsilyloxy)-4-[3-(2-iodoallyl)-7-isopropyl-4-methyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl]pentan-1-ol

下游产品

(3R,7R,8R,10S,11S,14R,15R,16R)-14-(tert-butyldimethylsiloxy)-3-isopropyl-6,10,14-trimethyl-15-oxatricyclo[6.6.1.00,0]pentadec-5-ene-10,11-diol