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(2S,4aS,5aR,6aS,8R,9S,10aR,11aS,13R,13aR)-9-(benzyloxy)-2-((2R,4R,5S)-4-(benzyloxy)-5-(2-(benzyloxy)ethyl)-5-methyltetrahydrofuran-2-yl)-8-((benzyloxy)methyl)-2,6a,13-trimethyltetradecahydro-2H-pyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepine

(2S,4aS,5aR,6aS,8R,9S,10aR,11aS,13R,13aR)-9-(benzyloxy)-2-((2R,4R,5S)-4-(benzyloxy)-5-(2-(benzyloxy)ethyl)-5-methyltetrahydrofuran-2-yl)-8-((benzyloxy)methyl)-2,6a,13-trimethyltetradecahydro-2H-pyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepine

CAS号：170706-83-9

英文名：(2S,4aS,5aR,6aS,8R,9S,10aR,11aS,13R,13aR)-9-(benzyloxy)-2-((2R,4R,5S)-4-(benzyloxy)-5-(2-(benzyloxy)ethyl)-5-methyltetrahydrofuran-2-yl)-8-((benzyloxy)methyl)-2,6a,13-trimethyltetradecahydro-2H-pyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepine

分子式

C54H68O9

熔点

密度

分子量

861.112

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(2S,4aS,5aR,6aS,8R,9S,10aR,11aS,13R,13aR)-9-(benzyloxy)-2-((2R,4R,5S)-4-(benzyloxy)-5-(2-(benzyloxy)ethyl)-5-methyltetrahydrofuran-2-yl)-8-((benzyloxy)methyl)-2,6a,13-trimethyltetradecahydro-2H-pyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepine

英文名称

(2S,4aS,5aR,6aS,8R,9S,10aR,11aS,13R,13aR)-9-(benzyloxy)-2-((2R,4R,5S)-4-(benzyloxy)-5-(2-(benzyloxy)ethyl)-5-methyltetrahydrofuran-2-yl)-8-((benzyloxy)methyl)-2,6a,13-trimethyltetradecahydro-2H-pyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepine

中文别名

英文别名

CAS号

170706-83-9

分子式

C54H68O9

分子量

861.112

精确质量

860.486

PSA

83.07

LOGP

9.9649

合成路线

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(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-2-hydroxymethyl-2,6-dimethyl-tetrahydro-pyran-3-ol

(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-2-hydroxymethyl-2,6-dimethyl-tetrahydro-pyran-3-ol

(2S,4aS,5aR,6aS,8R,9S,10aR,11aS,13R,13aR)-9-(benzyloxy)-2-((2R,4R,5S)-4-(benzyloxy)-5-(2-(benzyloxy)ethyl)-5-methyltetrahydrofuran-2-yl)-8-((benzyloxy)methyl)-2,6a,13-trimethyltetradecahydro-2H-pyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepine

(2S,4aS,5aR,6aS,8R,9S,10aR,11aS,13R,13aR)-9-(benzyloxy)-2-((2R,4R,5S)-4-(benzyloxy)-5-(2-(benzyloxy)ethyl)-5-methyltetrahydrofuran-2-yl)-8-((benzyloxy)methyl)-2,6a,13-trimethyltetradecahydro-2H-pyrano[3,2-b]pyrano[2',3':5,6]pyrano[2,3-f]oxepine

上游原料

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(2S,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-carbaldehyde

(2S,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-carbaldehyde

[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-methanol

[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-methanol

(2S,3R,5S,6R)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-5-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2,6-dimethyl-tetrahydro-pyran

(2S,3R,5S,6R)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-5-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2,6-dimethyl-tetrahydro-pyran

(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-2-hydroxymethyl-2,6-dimethyl-tetrahydro-pyran-3-ol

(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-2-hydroxymethyl-2,6-dimethyl-tetrahydro-pyran-3-ol

3-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-propionic acid

3-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-propionic acid

(2R,4aR,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

(2R,4aR,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine

下游产品

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2-((2S,3R,5R)-3-hydroxy-2-methyl-5-((4aR,5aS,6aR,7aS,10S,11aR,12R,13aS,14aR,15aS)-2,2,5a,10,12-pentamethylhexadecahydro-[1,3]dioxino[4'',5'':5',6']pyrano[2',3':5,6]pyrano[3,2-b]pyrano[2,3-f]oxepin-10-yl)tetrahydrofuran-2-yl)ethyl pivalate

2-((2S,3R,5R)-3-hydroxy-2-methyl-5-((4aR,5aS,6aR,7aS,10S,11aR,12R,13aS,14aR,15aS)-2,2,5a,10,12-pentamethylhexadecahydro-[1,3]dioxino[4'',5'':5',6']pyrano[2',3':5,6]pyrano[3,2-b]pyrano[2,3-f]oxepin-10-yl)tetrahydrofuran-2-yl)ethyl pivalate

(2S,4aS,5aR,6aS,8R,9S,10aR,11aS,13R,13aR)-2-[(2R,4R,5S)-4-Hydroxy-5-(2-hydroxy-ethyl)-5-methyl-tetrahydro-furan-2-yl]-8-hydroxymethyl-2,6a,13-trimethyl-tetradecahydro-1,5,7,11-tetraoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-ol

(2S,4aS,5aR,6aS,8R,9S,10aR,11aS,13R,13aR)-2-[(2R,4R,5S)-4-Hydroxy-5-(2-hydroxy-ethyl)-5-methyl-tetrahydro-furan-2-yl]-8-hydroxymethyl-2,6a,13-trimethyl-tetradecahydro-1,5,7,11-tetraoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-ol

(2S,3R,5R)-2-(2-hydroxyethyl)-2-methyl-5-((4aR,5aS,6aR,7aS,10S,11aR,12R,13aS,14aR,15aS)-2,2,5a,10,12-pentamethylhexadecahydro-[1,3]dioxino[4'',5'':5',6']pyrano[2',3':5,6]pyrano[3,2-b]pyrano[2,3-f]oxepin-10-yl)tetrahydrofuran-3-ol

(2S,3R,5R)-2-(2-hydroxyethyl)-2-methyl-5-((4aR,5aS,6aR,7aS,10S,11aR,12R,13aS,14aR,15aS)-2,2,5a,10,12-pentamethylhexadecahydro-[1,3]dioxino[4'',5'':5',6']pyrano[2',3':5,6]pyrano[3,2-b]pyrano[2,3-f]oxepin-10-yl)tetrahydrofuran-3-ol

上游原料

(2S,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-carbaldehyde [(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-methanol (2S,3R,5S,6R)-3-Benzyloxy-2-(2-benzyloxy-ethyl)-5-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2,6-dimethyl-tetrahydro-pyran (2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-2-hydroxymethyl-2,6-dimethyl-tetrahydro-pyran-3-ol 3-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-propionic acid (2R,4aR,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 3-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-propionic acid methyl ester (E)-3-[(2R,3S,5R,6S)-5-Benzyloxy-6-(2-benzyloxy-ethyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,6-dimethyl-tetrahydro-pyran-2-yl]-acrylic acid methyl ester 2-((2R,4aR,6S,7R,8aS)-7-Benzyloxy-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-ethanol (2R,4aR,6S,7R,8aS)-7-Benzyloxy-4a,6-dimethyl-2-phenyl-6-vinyl-hexahydro-pyrano[3,2-d][1,3]dioxine

下游产品

2-((2S,3R,5R)-3-hydroxy-2-methyl-5-((4aR,5aS,6aR,7aS,10S,11aR,12R,13aS,14aR,15aS)-2,2,5a,10,12-pentamethylhexadecahydro-[1,3]dioxino[4'',5'':5',6']pyrano[2',3':5,6]pyrano[3,2-b]pyrano[2,3-f]oxepin-10-yl)tetrahydrofuran-2-yl)ethyl pivalate (2S,4aS,5aR,6aS,8R,9S,10aR,11aS,13R,13aR)-2-[(2R,4R,5S)-4-Hydroxy-5-(2-hydroxy-ethyl)-5-methyl-tetrahydro-furan-2-yl]-8-hydroxymethyl-2,6a,13-trimethyl-tetradecahydro-1,5,7,11-tetraoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-ol (2S,3R,5R)-2-(2-hydroxyethyl)-2-methyl-5-((4aR,5aS,6aR,7aS,10S,11aR,12R,13aS,14aR,15aS)-2,2,5a,10,12-pentamethylhexadecahydro-[1,3]dioxino[4'',5'':5',6']pyrano[2',3':5,6]pyrano[3,2-b]pyrano[2,3-f]oxepin-10-yl)tetrahydrofuran-3-ol