百科

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

CAS号：172667-72-0

英文名：(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

分子式：C27H48O8S

分子量：532.73

合成路线

(R)-5-((R)-4-Benzyloxy-1-hydroxy-butyl)-dihydro-furan-2-one

(R)-5-((R)-4-Benzyloxy-1-hydroxy-butyl)-dihydro-furan-2-one

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(4R,5R)-Pentadecane-1,4,5-triol

(4R,5R)-Pentadecane-1,4,5-triol

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(E)-Henicosa-1,10-dien-6-yn-3-ol

(E)-Henicosa-1,10-dien-6-yn-3-ol

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(trans)-2-octadec-7-en-3-ynyl-[1,3]-dioxolane

(trans)-2-octadec-7-en-3-ynyl-[1,3]-dioxolane

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(trans)-1,1-dibromohexadeca-1,5-diene

(trans)-1,1-dibromohexadeca-1,5-diene

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(E)-Nonadec-8-en-4-ynal

(E)-Nonadec-8-en-4-ynal

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

(4R,5R,8R,9S,12R,13R)-12,13-isopropylidenedioxy-9-mesyloxy-5,8-oxidotricosa-1,4-olide

上游原料

(E)-Nonadec-8-en-4-ynal (R)-5-((R)-4-Benzyloxy-1-hydroxy-butyl)-dihydro-furan-2-one (trans)-1,1-dibromohexadeca-1,5-diene (trans)-2-octadec-7-en-3-ynyl-[1,3]-dioxolane (4R,5R)-Pentadecane-1,4,5-triol (E)-Henicosa-1,10-dien-6-yn-3-ol

下游产品

(4R,5R,8R,9R,12R,13S)-13-(4-nitrobenzoyloxy)-5,8:9,12-dioxidotricosa-1,4-olide (S)-3-{(E)-(2R,13R)-2,13-Bis-methoxymethoxy-13-[(2R,5R,2'R,5'R)-5'-((R)-1-methoxymethoxy-undecyl)-octahydro-[2,2']bifuranyl-5-yl]-tridec-9-enyl}-5-methyl-5H-furan-2-one (5S)-3-[(2S,13R)-2,13-二羟基-13-[(2R,5R)-5-[(2R,5R)-5-[(1R)-1-羟基十一烷基]四氢呋喃-2-基]四氢呋喃-2-基]十三烷基]-5-甲基-5H-呋喃-2-酮 (4R,5R,8R,9R,12R,13S)-1-hydroxy-4,13-di(methoxymethoxy)-5,8:9,12-dioxidotricosane