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(4S,9R,10S,15R,16S)-9,15-dihydroxy-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione

(4S,9R,10S,15R,16S)-9,15-dihydroxy-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione

CAS号：172923-77-2

英文名：(4S,9R,10S,15R,16S)-9,15-dihydroxy-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione

分子式

C16H22O8

熔点

密度

分子量

342.341

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(4S,9R,10S,15R,16S)-9,15-dihydroxy-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione

英文名称

(4S,9R,10S,15R,16S)-9,15-dihydroxy-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione

中文别名

英文别名

CAS号

172923-77-2

分子式

C16H22O8

分子量

342.341

精确质量

342.131

PSA

119.36

LOGP

0.0194

合成路线

(4S,7E,9R,10S,13E,15R,16S)-9,15-bis(methoxymethoxy)-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione

(4S,7E,9R,10S,13E,15R,16S)-9,15-bis(methoxymethoxy)-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione

(4S,9R,10S,15R,16S)-9,15-dihydroxy-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione

(4S,9R,10S,15R,16S)-9,15-dihydroxy-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione

上游原料

共找到77个上游原料 >

methyl (4R,5S)-4-benzyloxy-5-hydroxy-2(E)-hexenoate

methyl (4R,5S)-4-benzyloxy-5-hydroxy-2(E)-hexenoate

(8R,9S)-8-((E)-2-iodovinyl)-9,11,11,12,12-pentamethyl-2,5,7,10-tetraoxa-11-silatridecane

(8R,9S)-8-((E)-2-iodovinyl)-9,11,11,12,12-pentamethyl-2,5,7,10-tetraoxa-11-silatridecane

(4R,5S)-(E)-5-hydroxy-4-(β-methoxyethoxy)methoxy-2-hexenoic acid tert-butyl ester

(4R,5S)-(E)-5-hydroxy-4-(β-methoxyethoxy)methoxy-2-hexenoic acid tert-butyl ester

(4R,5S)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-(β-methoxyethoxy)methoxy-2-hexenoic acid tert-butyl ester

(4R,5S)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-(β-methoxyethoxy)methoxy-2-hexenoic acid tert-butyl ester

(4R,5S,10R,11S)-(2E,8E)-11-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester

(4R,5S,10R,11S)-(2E,8E)-11-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester

(8R,9E,13S,14R,15E)-8-((S)-1-((S)-3-hydroxybutanoyloxy)ethyl)-14-((2-methoxyethoxy)methoxy)-13-methyl-11-oxo-2,5,7,12-tetraoxaheptadeca-9,15-dien-17-oic acid

(8R,9E,13S,14R,15E)-8-((S)-1-((S)-3-hydroxybutanoyloxy)ethyl)-14-((2-methoxyethoxy)methoxy)-13-methyl-11-oxo-2,5,7,12-tetraoxaheptadeca-9,15-dien-17-oic acid

上游原料

methyl (4R,5S)-4-benzyloxy-5-hydroxy-2(E)-hexenoate (8R,9S)-8-((E)-2-iodovinyl)-9,11,11,12,12-pentamethyl-2,5,7,10-tetraoxa-11-silatridecane (4R,5S)-(E)-5-hydroxy-4-(β-methoxyethoxy)methoxy-2-hexenoic acid tert-butyl ester (4R,5S)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-(β-methoxyethoxy)methoxy-2-hexenoic acid tert-butyl ester (4R,5S,10R,11S)-(2E,8E)-11-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester (8R,9E,13S,14R,15E)-8-((S)-1-((S)-3-hydroxybutanoyloxy)ethyl)-14-((2-methoxyethoxy)methoxy)-13-methyl-11-oxo-2,5,7,12-tetraoxaheptadeca-9,15-dien-17-oic acid (2E,5S)-5-(4-methoxybenzyloxy)-4-oxo-2-hexenoic acid (4S,7E,9R,10S,13E,15R,16S)-15-((4-methoxybenzyl)oxy)-9-((2-methoxyethoxy)methoxy)-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione (5R,6E,10S,14S,16E)-5-((S)-1-hydroxyethyl)-10,14-dimethyl-8,12,15-trioxo-2,4,9,13-tetraoxaoctadeca-6,16-dien-18-oic acid (4R,5S,E)-(S)-4-(((S,E)-3,6-dioxohex-4-en-2-yl)oxy)-4-oxobutan-2-yl 5-hydroxy-4-(methoxymethoxy)hex-2-enoate (-)-1-[3-(4-methoxybenzyloxy)-1-penten-4-yloxycarbonyl]prop-2-yl 5-(tert-butyldimethylsilyloxy)-4-[(2-methoxyethoxy)methoxy]-2-hexenoate (2S,6S,9E,11R,12S)-6,12-dimethyl-2-(2-furyl)-11-(methoxymethoxy)-14-(4-methoxyphenyl)-3,7,13-trioxa-9-tetradecene-4,8-dione 5-(tert-butyl-dimethyl-silanyloxy)-4-(2-methoxy-ethoxymethoxy)-hex-2-enoic acid ethyl ester (2E,5S)-5-(4-methoxybenzyloxy)-4-oxo-2-hexenal (2S,6S,9E,12S)-6,12-dimethyl-2-(2-furyl)-14-(4-methoxyphenyl)-3,7,13-trioxa-9-tetradecene-4,8,11-trione (3R,4S)-4-hydroxy-3-(4-methoxybenzyloxy)-1-pentene (4S,7E,9R,10S,13E,15S,16S)-15-hydroxy-9-(methoxymethoxy)-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione allyl (S,E)-4-oxo-5-(trityloxy)hex-2-enoate (-)-1-(3-hydroxy-1-penten-4-yloxycarbonyl)prop-2-yl 5-acryloyloxy-4-[(2-methoxyethoxy)methoxy]-2-hexenoate (3R,4S)-4-(tert-butyldimethylsilanyloxy)-pent-1-en-3-ol (4R,5S)-4-benzyloxy-5-tert-butyldimethylsilyloxy-2(E)-hexenoic acid (4R,5S,10R,11S)-(2E,8E)-11-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester (4R,5S,10R,11S,15S)-(2E,8E)-15-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid tert-butyl ester (4R,5S)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-hydroxy-2-hexenoic acid tert-butyl ester (8R,9S)-8-ethynyl-9,11,11,12,12-pentamethyl-2,5,7,10-tetraoxa-11-silatridecane (3R,4S)-4-((tert-butyldimethylsilyl)oxy)-1-(trimethylsilyl)pent-1-yn-3-ol (2S,6S)-6-[(tert-butyldimethylsilyl)oxy]-2-(2-furyl)-3-oxa-4-heptanone (4S,7E,9R,10S,13E,15R,16S)-9,15-bis(methoxymethoxy)-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione (S)-1-(2-furyl)-1-(4-methoxybenzyloxy)ethane methyl (S)-3-(4-methoxybenzyloxy)butanoate (-)-1-[3-(4-methoxybenzyloxy)-1-penten-4-yloxycarbonyl]prop-2-yl 5-acryloyloxy-4-[(2-methoxyethoxy)methoxy]-2-hexenoate DL-1-(2-呋喃基)乙醇 macrosphelide B (2S,6S,9E,11R,12S)-6-methyl-2-(2-furyl)-12-hydroxy-11-(methoxymethoxy)-3,7-dioxa-9-tridecene-4,8-dione (4S,5S)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-hydroxy-2-hexenoic acid tert-butyl ester (2S,6S)-2-(2-furyl)-6-hydroxy-3-oxa-4-heptanone (S)-4-((tert-butyldimethylsilyl)oxy)-1-(trimethylsilyl)pent-1-yn-3-one allyl (E,4R,5S)-4-(methoxymethoxy)-5-(trityloxy)hex-2-enoate (-)-1-[3-(4-methoxybenzyloxy)-1-penten-4-yloxycarbonyl]prop-2-yl 5-hydroxy-4-[(2-methoxyethoxy)methoxy]-2-hexenoate (3R,4S)-3-(4-methoxybenzyloxy)-1-penten-4-yl (3S)-3-hydroxybutanoate (4S,7E,9R,10S,13E,16S)-9-(methoxymethoxy)-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12,15-tetraone (3R,4S)-3-(4-methoxybenzyloxy)-1-penten-4-yl (3S)-3-(tert-butyldimethylsilyloxy)butanoate (2S,6S,9E,11R,12S)-6,12-dimethyl-2-(2-furyl)-11-hydroxy-14-(4-methoxyphenyl)-3,7,13-trioxa-9-tetradecene-4,8-dione 2-tosylethyl (4R,5S,E)-5-hydroxy-4-((4-methoxybenzyl)oxy)hex-2-enoate (3R,4S)-4-(tert-butyldimethylsilyloxy)-3-(4-methoxybenzyloxy)-1-pentene (4R,5S)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-(β-methoxyethoxy)methoxy-2-hexenoic acid