百科

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

CAS号：174419-96-6

英文名：(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

分子式：C22H43IO3Si

分子量：510.565

合成路线

(2R,3R,4S)-2-methylpentane-1,3,4-triol

(2R,3R,4S)-2-methylpentane-1,3,4-triol

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

(2R,3S,4S)-2,4-dimethylhept-6-yne-1,3-diol

(2R,3S,4S)-2,4-dimethylhept-6-yne-1,3-diol

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

(2R,3S,4S,E)-7-iodo-2,4,6-trimethylhept-6-ene-1,3-diol

(2R,3S,4S,E)-7-iodo-2,4,6-trimethylhept-6-ene-1,3-diol

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

(2S,3R,4S)-4-methyl-5-oxopentane-2,3-diyl diacetate

(2S,3R,4S)-4-methyl-5-oxopentane-2,3-diyl diacetate

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

三甲基乙酰氯

三甲基乙酰氯

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

(2R,3S,4S,E)-3-((diethyl(isopropyl)silyl)oxy)-7-iodo-2,4,6-trimethylhept-6-en-1-yl pivalate

上游原料

(2S,3R,4S)-4-methyl-5-oxopentane-2,3-diyl diacetate 三甲基乙酰氯 (2R,3R,4S)-2-methylpentane-1,3,4-triol (2R,3S,4S,E)-7-iodo-2,4,6-trimethylhept-6-ene-1,3-diol (2R,3S,4S)-2,4-dimethylhept-6-yne-1,3-diol

下游产品

methyl (4E,6R,7S,8S,10E,12E,14S,15R,16S)-7-((diethyl(isopropyl)silyl)oxy)-15,17-dihydroxy-2,14-dimethoxy-4,6,8,10,16-pentamethylheptadeca-2,4,10,12-tetraenoate methyl (4E,6R,7S,8S,10E,12E,14S,15R,16S)-7-((diethyl(isopropyl)silyl)oxy)-15-hydroxy-2,14-dimethoxy-17-((4-methoxyphenyl)diphenylmethoxy)-4,6,8,10,16-pentamethylheptadeca-2,4,10,12-tetraenoate 巴佛洛霉素A1