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(2E,4R,5S,6S,8E,10E,12S)-5-((diethyl(isopropyl)silyl)oxy)-12-methoxy-2,4,6,8-tetramethyl-12-((4R,5S)-2,2,5-trimethyl-1,3-dioxan-4-yl)dodeca-2,8,10-trien-1-ol

CAS号：174657-15-9

英文名：(2E,4R,5S,6S,8E,10E,12S)-5-((diethyl(isopropyl)silyl)oxy)-12-methoxy-2,4,6,8-tetramethyl-12-((4R,5S)-2,2,5-trimethyl-1,3-dioxan-4-yl)dodeca-2,8,10-trien-1-ol

分子式：C31H58O5Si

分子量：538.875

合成路线

174657-14-8

ethyl (2E,4R,5S,6S,8E,10E,12S)-5-((diethyl(isopropyl)silyl)oxy)-12-methoxy-2,4,6,8-tetramethyl-12-((4R,5S)-2,2,5-trimethyl-1,3-dioxan-4-yl)dodeca-2,8,10-trienoate

174657-15-9

(2E,4R,5S,6S,8E,10E,12S)-5-((diethyl(isopropyl)silyl)oxy)-12-methoxy-2,4,6,8-tetramethyl-12-((4R,5S)-2,2,5-trimethyl-1,3-dioxan-4-yl)dodeca-2,8,10-trien-1-ol

174513-81-6

(2R,3R,4S)-2-methylpentane-1,3,4-triol

174657-15-9

(2E,4R,5S,6S,8E,10E,12S)-5-((diethyl(isopropyl)silyl)oxy)-12-methoxy-2,4,6,8-tetramethyl-12-((4R,5S)-2,2,5-trimethyl-1,3-dioxan-4-yl)dodeca-2,8,10-trien-1-ol

174420-07-6

(2R,3S,4S)-2,4-dimethylhept-6-yne-1,3-diol

174657-15-9

(2E,4R,5S,6S,8E,10E,12S)-5-((diethyl(isopropyl)silyl)oxy)-12-methoxy-2,4,6,8-tetramethyl-12-((4R,5S)-2,2,5-trimethyl-1,3-dioxan-4-yl)dodeca-2,8,10-trien-1-ol

174420-08-7

(2R,3S,4S,E)-7-iodo-2,4,6-trimethylhept-6-ene-1,3-diol

174657-15-9

(2E,4R,5S,6S,8E,10E,12S)-5-((diethyl(isopropyl)silyl)oxy)-12-methoxy-2,4,6,8-tetramethyl-12-((4R,5S)-2,2,5-trimethyl-1,3-dioxan-4-yl)dodeca-2,8,10-trien-1-ol

174419-99-9

(2S,3R,4S)-4-methyl-5-oxopentane-2,3-diyl diacetate

174657-15-9

(2E,4R,5S,6S,8E,10E,12S)-5-((diethyl(isopropyl)silyl)oxy)-12-methoxy-2,4,6,8-tetramethyl-12-((4R,5S)-2,2,5-trimethyl-1,3-dioxan-4-yl)dodeca-2,8,10-trien-1-ol

上游原料

(2S,3R,4S)-4-methyl-5-oxopentane-2,3-diyl diacetate ethyl (2E,4R,5S,6S,8E,10E,12S)-5-((diethyl(isopropyl)silyl)oxy)-12-methoxy-2,4,6,8-tetramethyl-12-((4R,5S)-2,2,5-trimethyl-1,3-dioxan-4-yl)dodeca-2,8,10-trienoate (2R,3R,4S)-2-methylpentane-1,3,4-triol (2R,3S,4S,E)-7-iodo-2,4,6-trimethylhept-6-ene-1,3-diol (2R,3S,4S)-2,4-dimethylhept-6-yne-1,3-diol

下游产品

巴佛洛霉素A1