化合物简介
Dimethyl tetrachloroterephthalate (DCPA, Dacthal) is an organic compound with the formula C6Cl4(CO2CH3)2. It is a colourless solid, although commercial samples can be off white. DCPA is the dimethyl ester of tetrachloroterephthalic acid. It is used as a preemergent herbicide. It kills grass and many common weeds without killing sensitive plants such as flowers, fruits, vegetables, turf, and cotton. DCPA was first registered for use in the United States in 1958. Production of DCPA was eventually discontinued by ISK Biosciences in 1998, but the large manufacturing company AMVAC began producing the product in 2001 for use in America. Sigma-Aldrich also manufactures DCPA for use in the USA under the name Pestanal. In Australia, DCPA is the active ingredient in agchem company Farmalinx's herbicide called Dynamo 750. Currently, DCPA is only used for eggplant, kale, turnips, and sweet potatoes.
基本信息
中文名称
氯酞酸甲酯
英文名称
chlorthal-dimethyl
中文别名
TCTP、2,3,5,6-四氯-1,4-苯二甲酸甲酯、氯酞酸二甲酯、2,3,5,6-四氯对苯二甲酸二甲酯、四氯对苯二甲酸二甲酯、二甲基敌草索、敌草索
英文别名
DIMETHYL 2,3,5,6-TETRACHLOROTEREPHTHALATE、dimethyl tetrachloroterephthalate、Tetrachloroterephthalic Acid Dimethyl Ester、Tetral、Dacthalor、dimethyl 2,3,5,6-tetrachlorobenzene-1,4-dicarboxylate、Chlorthal-dimethyl,Dimethyl tetrachloroterephthalate、Tetrachloroterephthalic acid dimethyl ester、Chlorthal-methyl、Fatal、DCPA、1,4-dimethyl 2,3,5,6-tetrachloro-1,4-benzenedicarboxylate、chlorthal、Dimethyl Tetrachloroterephthalate、dacthal、Dimethyl tetrachloroterephthalate、dimethyl 2,3,5,6-tetra-chloroterephthalate、DIMETHYL TETRACHLOROTEREPHTHALATE、Chlorthal-dimethyl
CAS号
1861-32-1
分子式
C10H6Cl4O4
分子量
331.964
精确质量
329.902
PSA
52.6
LOGP
3.8734
编号系统
EINECS号
217-464-7
MDL号
MFCD00014902
BRN号
1888840
RTECS号
WZ1500000
物化性质
外观与性状
无色,结晶固体
密度
1.558g/cm3
沸点
422ºC at 760mmHg
熔点
155-156°C
闪点
174.7ºC
折射率
1.564
水溶解性
0.05 g/100 mL
稳定性
Stable in the pure state stable to UV irradiation.
储存条件
Keep closed in a cool, dry place. Store only with compatible chemicals.
蒸汽压
2.5E-07mmHg at 25°C
安全信息
RTECS号
WZ1500000
安全说明
S22-S24/25
海关编码
2917399090
生产方法及用途
生产方法
采用强甲基化剂(如重氮甲烷或硫酸二甲酯),使四氯对苯二甲酸烷基化;或由四氯对苯二甲酰氯与甲醇酯化而得。中间体四氯对苯二甲酰氯有两种主要合成方法。
(1)由对二甲苯侧链氯化、水解、环上氯化而得。
(2)由对苯二甲酸经酰氯化、氯化而得。
(1)由对二甲苯侧链氯化、水解、环上氯化而得。
(2)由对苯二甲酸经酰氯化、氯化而得。
用途
除草剂。对萌发至二叶期的稗草有显著的活性,对旱地马唐等芽前杂草也有良好的防除效果。
海关数据
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