百科

(S)-1-{2-[(2S,3R,6S)-6-((Z)-(S)-2-Methoxy-3-methyl-hex-3-en-5-ynyl)-3-methyl-2-triethylsilanyloxy-tetrahydro-pyran-2-yl]-2-oxo-acetyl}-piperidine-2-carboxylic acid methyl ester

(S)-1-{2-[(2S,3R,6S)-6-((Z)-(S)-2-Methoxy-3-methyl-hex-3-en-5-ynyl)-3-methyl-2-triethylsilanyloxy-tetrahydro-pyran-2-yl]-2-oxo-acetyl}-piperidine-2-carboxylic acid methyl ester

CAS号：186417-46-9

英文名：(S)-1-{2-[(2S,3R,6S)-6-((Z)-(S)-2-Methoxy-3-methyl-hex-3-en-5-ynyl)-3-methyl-2-triethylsilanyloxy-tetrahydro-pyran-2-yl]-2-oxo-acetyl}-piperidine-2-carboxylic acid methyl ester

分子式：C29H47NO7Si

分子量：549.771

合成路线

(Z)-(2R,5S,7S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-methoxy-2,8-dimethyl-11-trimethylsilanyl-undec-8-en-10-ynoic acid (1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-propyl ester

(Z)-(2R,5S,7S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-methoxy-2,8-dimethyl-11-trimethylsilanyl-undec-8-en-10-ynoic acid (1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-propyl ester

(S)-1-{2-[(2S,3R,6S)-6-((Z)-(S)-2-Methoxy-3-methyl-hex-3-en-5-ynyl)-3-methyl-2-triethylsilanyloxy-tetrahydro-pyran-2-yl]-2-oxo-acetyl}-piperidine-2-carboxylic acid methyl ester

(S)-1-{2-[(2S,3R,6S)-6-((Z)-(S)-2-Methoxy-3-methyl-hex-3-en-5-ynyl)-3-methyl-2-triethylsilanyloxy-tetrahydro-pyran-2-yl]-2-oxo-acetyl}-piperidine-2-carboxylic acid methyl ester

(S)-1-[(Z)-(4R,7S,9S)-7-(tert-Butyl-dimethyl-silanyloxy)-9-methoxy-4,10-dimethyl-2,3-dioxo-13-trimethylsilanyl-tridec-10-en-12-ynoyl]-piperidine-2-carboxylic acid methyl ester

(S)-1-[(Z)-(4R,7S,9S)-7-(tert-Butyl-dimethyl-silanyloxy)-9-methoxy-4,10-dimethyl-2,3-dioxo-13-trimethylsilanyl-tridec-10-en-12-ynoyl]-piperidine-2-carboxylic acid methyl ester

(S)-1-{2-[(2S,3R,6S)-6-((Z)-(S)-2-Methoxy-3-methyl-hex-3-en-5-ynyl)-3-methyl-2-triethylsilanyloxy-tetrahydro-pyran-2-yl]-2-oxo-acetyl}-piperidine-2-carboxylic acid methyl ester

(S)-1-{2-[(2S,3R,6S)-6-((Z)-(S)-2-Methoxy-3-methyl-hex-3-en-5-ynyl)-3-methyl-2-triethylsilanyloxy-tetrahydro-pyran-2-yl]-2-oxo-acetyl}-piperidine-2-carboxylic acid methyl ester

上游原料

(Z)-(2R,5S,7S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-methoxy-2,8-dimethyl-11-trimethylsilanyl-undec-8-en-10-ynoic acid (1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-propyl ester (S)-1-[(Z)-(4R,7S,9S)-7-(tert-Butyl-dimethyl-silanyloxy)-9-methoxy-4,10-dimethyl-2,3-dioxo-13-trimethylsilanyl-tridec-10-en-12-ynoyl]-piperidine-2-carboxylic acid methyl ester

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