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(-)-sanglifehrin A

(-)-sanglifehrin A

CAS号：187148-13-6

英文名：(-)-sanglifehrin A

分子式

C60H91N5O13

熔点

142 - 145 °C

密度

分子量

1090.39

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(-)-sanglifehrin A

英文名称

(-)-sanglifehrin A

中文别名

英文别名

Sanglifehrin A、SFA

CAS号

187148-13-6

分子式

C60H91N5O13

分子量

1090.39

精确质量

1089.66

PSA

273.39

LOGP

6.6604

物化性质

熔点

142 - 145 °C

合成路线

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(S)-methyl 2-((benzyloxycarbonyl)amino)-3-(3-hydroxyphenyl)propanoate

(S)-methyl 2-((benzyloxycarbonyl)amino)-3-(3-hydroxyphenyl)propanoate

(-)-sanglifehrin A

(-)-sanglifehrin A

上游原料

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(S)-1-[(S)-2-Benzyloxycarbonylamino-3-(3-hydroxy-phenyl)-propionyl]-hexahydro-pyridazine-3-carboxylic acid methyl ester

(S)-1-[(S)-2-Benzyloxycarbonylamino-3-(3-hydroxy-phenyl)-propionyl]-hexahydro-pyridazine-3-carboxylic acid methyl ester

(2S,3R)-3-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-5-triethylsilanyl-pent-4-ynal

(2S,3R)-3-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-5-triethylsilanyl-pent-4-ynal

1-[3-(3-tert-butoxycarbonyloxy-phenyl)-2-(2-{[3-(6-hydroxy-8-iodo-7-methyl-octa-1,3,7-trienyl)-1,4-dimethyl-2,9-dioxa-bicyclo[3.3.1]nonane-6-carbonyl]-amino}-3-methyl-butyrylamino)-propionyl]-hexahydro-pyridazine-3-carboxylic acid

1-[3-(3-tert-butoxycarbonyloxy-phenyl)-2-(2-{[3-(6-hydroxy-8-iodo-7-methyl-octa-1,3,7-trienyl)-1,4-dimethyl-2,9-dioxa-bicyclo[3.3.1]nonane-6-carbonyl]-amino}-3-methyl-butyrylamino)-propionyl]-hexahydro-pyridazine-3-carboxylic acid

(S)-4-Benzyl-3-{(6E,8E,12E)-(2R,3R,4S,5S,11S)-11-(tert-butyl-dimethyl-silanyloxy)-3,5-dihydroxy-13-iodo-4,12-dimethyl-2-[2-(2-methyl-[1,3]dithian-2-yl)-ethyl]-trideca-6,8,12-trienoyl}-oxazolidin-2-one

(S)-4-Benzyl-3-{(6E,8E,12E)-(2R,3R,4S,5S,11S)-11-(tert-butyl-dimethyl-silanyloxy)-3,5-dihydroxy-13-iodo-4,12-dimethyl-2-[2-(2-methyl-[1,3]dithian-2-yl)-ethyl]-trideca-6,8,12-trienoyl}-oxazolidin-2-one

(2E,4E,8E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-9-iodo-8-methyl-nona-2,4,8-trienal

(2E,4E,8E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-9-iodo-8-methyl-nona-2,4,8-trienal

(E)-(4R,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-7-triethylsilanyl-hept-2-en-6-yn-1-ol

(E)-(4R,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-7-triethylsilanyl-hept-2-en-6-yn-1-ol

下游产品

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sanglifehrin A ketal

sanglifehrin A ketal

(E)-3-[(13E,15E)-(3S,6S,9R,10R,11S,12S,18S,21S)-10,12-Dihydroxy-3-(3-hydroxy-benzyl)-6-isopropyl-11-methyl-2,5,8,20-tetraoxo-9-(3-oxo-butyl)-19-oxa-1,4,7,25-tetraaza-bicyclo[19.3.1]pentacosa-13,15-dien-18-yl]-but-2-enal

(E)-3-[(13E,15E)-(3S,6S,9R,10R,11S,12S,18S,21S)-10,12-Dihydroxy-3-(3-hydroxy-benzyl)-6-isopropyl-11-methyl-2,5,8,20-tetraoxo-9-(3-oxo-butyl)-19-oxa-1,4,7,25-tetraaza-bicyclo[19.3.1]pentacosa-13,15-dien-18-yl]-but-2-enal

53-iodo sanglifehrin A

53-iodo sanglifehrin A

上游原料

(S)-1-[(S)-2-Benzyloxycarbonylamino-3-(3-hydroxy-phenyl)-propionyl]-hexahydro-pyridazine-3-carboxylic acid methyl ester (2S,3R)-3-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-5-triethylsilanyl-pent-4-ynal 1-[3-(3-tert-butoxycarbonyloxy-phenyl)-2-(2-{[3-(6-hydroxy-8-iodo-7-methyl-octa-1,3,7-trienyl)-1,4-dimethyl-2,9-dioxa-bicyclo[3.3.1]nonane-6-carbonyl]-amino}-3-methyl-butyrylamino)-propionyl]-hexahydro-pyridazine-3-carboxylic acid (S)-4-Benzyl-3-{(6E,8E,12E)-(2R,3R,4S,5S,11S)-11-(tert-butyl-dimethyl-silanyloxy)-3,5-dihydroxy-13-iodo-4,12-dimethyl-2-[2-(2-methyl-[1,3]dithian-2-yl)-ethyl]-trideca-6,8,12-trienoyl}-oxazolidin-2-one (2E,4E,8E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-9-iodo-8-methyl-nona-2,4,8-trienal (E)-(4R,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-7-triethylsilanyl-hept-2-en-6-yn-1-ol (S)-4-Benzyl-3-[4-(2-methyl-[1,3]dithian-2-yl)-butyryl]-oxazolidin-2-one (3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-6-triethylsilanyl-hex-1-en-5-yne (S)-1-[(S)-2-Benzyloxycarbonylamino-3-(3-tert-butoxycarbonyloxy-phenyl)-propionyl]-hexahydro-pyridazine-3-carboxylic acid methyl ester (R)-1-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-2-[2-(2-methyl-[1,3]dithian-2-yl)-ethyl]-pentane-1,3-dione (E)-(4R,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-7-triethylsilanyl-hept-2-en-6-ynoic acid ethyl ester (S)-4-Benzyl-3-{(3S,4S,5R,6R)-3-[(1E,3E,7E)-(S)-6-(tert-butyl-dimethyl-silanyloxy)-8-iodo-7-methyl-octa-1,3,7-trienyl]-1,4-dimethyl-2,9-dioxa-bicyclo[3.3.1]nonane-6-carbonyl}-oxazolidin-2-one (E)-(4R,5R)-6-Benzyloxy-4-methyl-5-triisopropylsilanyloxy-hex-2-enoic acid ethyl ester 1-(4(S)-Benzyl-2-oxo-oxazolidin-3-yl)-hexane-1,5-dione (3R,4R)-4-Methyl-1-triethylsilanyl-hex-5-en-1-yn-3-ol (S)-methyl 2-((benzyloxycarbonyl)amino)-3-(3-hydroxyphenyl)propanoate

下游产品

sanglifehrin A ketal (E)-3-[(13E,15E)-(3S,6S,9R,10R,11S,12S,18S,21S)-10,12-Dihydroxy-3-(3-hydroxy-benzyl)-6-isopropyl-11-methyl-2,5,8,20-tetraoxo-9-(3-oxo-butyl)-19-oxa-1,4,7,25-tetraaza-bicyclo[19.3.1]pentacosa-13,15-dien-18-yl]-but-2-enal 53-iodo sanglifehrin A