百科

benzyl ((3aR,4R,5R,7aR)-4-((tert-butyldimethylsilyl)oxy)-7-(2-((3aS,4S,6R,7R,7aS)-4-methoxy-7-(methoxymethoxy)-2,2-dimethyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl)ethyl)-2,2-dimethyl-3a,4,5,7a-tetrahydrobenzo[d][1,3]dioxol-5-yl)carbamate

benzyl ((3aR,4R,5R,7aR)-4-((tert-butyldimethylsilyl)oxy)-7-(2-((3aS,4S,6R,7R,7aS)-4-methoxy-7-(methoxymethoxy)-2,2-dimethyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl)ethyl)-2,2-dimethyl-3a,4,5,7a-tetrahydrobenzo[d][1,3]dioxol-5-yl)carbamate

CAS号：189825-39-6

英文名：benzyl ((3aR,4R,5R,7aR)-4-((tert-butyldimethylsilyl)oxy)-7-(2-((3aS,4S,6R,7R,7aS)-4-methoxy-7-(methoxymethoxy)-2,2-dimethyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl)ethyl)-2,2-dimethyl-3a,4,5,7a-tetrahydrobenzo[d][1,3]dioxol-5-yl)carbamate

分子式

C36H57NO11Si

熔点

密度

分子量

707.923

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

benzyl ((3aR,4R,5R,7aR)-4-((tert-butyldimethylsilyl)oxy)-7-(2-((3aS,4S,6R,7R,7aS)-4-methoxy-7-(methoxymethoxy)-2,2-dimethyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl)ethyl)-2,2-dimethyl-3a,4,5,7a-tetrahydrobenzo[d][1,3]dioxol-5-yl)carbamate

英文名称

benzyl ((3aR,4R,5R,7aR)-4-((tert-butyldimethylsilyl)oxy)-7-(2-((3aS,4S,6R,7R,7aS)-4-methoxy-7-(methoxymethoxy)-2,2-dimethyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl)ethyl)-2,2-dimethyl-3a,4,5,7a-tetrahydrobenzo[d][1,3]dioxol-5-yl)carbamate

中文别名

英文别名

CAS号

189825-39-6

分子式

C36H57NO11Si

分子量

707.923

精确质量

707.37

PSA

121.4

LOGP

6.1835

合成路线

methyl 2,3-O-isopropylidene-4-O-(methoxymethyl)-α-D-mannopyranoside

methyl 2,3-O-isopropylidene-4-O-(methoxymethyl)-α-D-mannopyranoside

benzyl ((3aR,4R,5R,7aR)-4-((tert-butyldimethylsilyl)oxy)-7-(2-((3aS,4S,6R,7R,7aS)-4-methoxy-7-(methoxymethoxy)-2,2-dimethyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl)ethyl)-2,2-dimethyl-3a,4,5,7a-tetrahydrobenzo[d][1,3]dioxol-5-yl)carbamate

benzyl ((3aR,4R,5R,7aR)-4-((tert-butyldimethylsilyl)oxy)-7-(2-((3aS,4S,6R,7R,7aS)-4-methoxy-7-(methoxymethoxy)-2,2-dimethyltetrahydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl)ethyl)-2,2-dimethyl-3a,4,5,7a-tetrahydrobenzo[d][1,3]dioxol-5-yl)carbamate

上游原料

共找到4个上游原料 >

methyl 2,3-O-isopropylidene-4-O-(methoxymethyl)-6-methylene-α-D-mannopyranoside

methyl 2,3-O-isopropylidene-4-O-(methoxymethyl)-6-methylene-α-D-mannopyranoside

(1R,2R,5S,6S)-2-azido-4-bromo-5,6-(O-isopropylidenedioxy)cyclohex-3-en-1-ol

(1R,2R,5S,6S)-2-azido-4-bromo-5,6-(O-isopropylidenedioxy)cyclohex-3-en-1-ol

[(3aR,4R,5R,7aS)-7-Bromo-4-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-3a,4,5,7a-tetrahydro-benzo[1,3]dioxol-5-yl]-carbamic acid benzyl ester

[(3aR,4R,5R,7aS)-7-Bromo-4-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-3a,4,5,7a-tetrahydro-benzo[1,3]dioxol-5-yl]-carbamic acid benzyl ester

methyl 2,3-O-isopropylidene-4-O-(methoxymethyl)-α-D-mannopyranoside

methyl 2,3-O-isopropylidene-4-O-(methoxymethyl)-α-D-mannopyranoside

上游原料

methyl 2,3-O-isopropylidene-4-O-(methoxymethyl)-6-methylene-α-D-mannopyranoside (1R,2R,5S,6S)-2-azido-4-bromo-5,6-(O-isopropylidenedioxy)cyclohex-3-en-1-ol [(3aR,4R,5R,7aS)-7-Bromo-4-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-3a,4,5,7a-tetrahydro-benzo[1,3]dioxol-5-yl]-carbamic acid benzyl ester methyl 2,3-O-isopropylidene-4-O-(methoxymethyl)-α-D-mannopyranoside