芒霉素

芒霉素

CAS号：19186-33-5

英文名：Aristeromycin

分子式

C11H15N5O3

熔点

密度

1.92g/cm3

分子量

265.269

沸点

595.1ºC at 760mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

芒霉素

英文名称

Aristeromycin

中文别名

芒雷素[讹误]

英文别名

carbocyclic adenosine、4\'-O-Carbaadenosine、Cycloadenosine

CAS号

19186-33-5

分子式

C11H15N5O3

分子量

265.269

精确质量

265.117

PSA

130.31

LOGP

-0.7352

编号系统

PubChem号

24847070

RTECS号

GY4250000

物化性质

密度

1.92g/cm3

沸点

595.1ºC at 760mmHg

闪点

313.7ºC

折射率

1.881

储存条件

2-8ºC

蒸汽压

5.19E-15mmHg at 25°C

安全信息

RTECS号

GY4250000

WGK Germany

3

合成路线

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(1'R,2'R,3'S,4'R)-4'-(6-aminopurin-9-yl)-1'-hydroxymethyl-2',3'-O-isopropylidenecyclopentane-2',3'-diol

(1'R,2'R,3'S,4'R)-4'-(6-aminopurin-9-yl)-1'-hydroxymethyl-2',3'-O-isopropylidenecyclopentane-2',3'-diol

芒霉素

上游原料

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(3S,3aS,6aR)-2-oxo-3,3a,4,6a-tetrahydro-2H-cyclopenta[b]furan-3-yl (S)-2-acetoxypropanoate

(3S,3aS,6aR)-2-oxo-3,3a,4,6a-tetrahydro-2H-cyclopenta[b]furan-3-yl (S)-2-acetoxypropanoate

(3aS,6aR)-2,2-二甲基-4,6a-二氢-3aH-环戊二烯并[d][1,3]二氧杂环戊烯-4-醇

(3aS,6aR)-2,2-二甲基-4,6a-二氢-3aH-环戊二烯并[d][1,3]二氧杂环戊烯-4-醇

二丙酮-D-葡萄糖

二丙酮-D-葡萄糖

((2R,3S)-3-(benzyloxy)-2-(formyloxy)-4-hydroxy-5-nitrocyclopentyl)methyl benzoate

((2R,3S)-3-(benzyloxy)-2-(formyloxy)-4-hydroxy-5-nitrocyclopentyl)methyl benzoate

(3aR,6R,6aR)-2,2-dimethyl-6-vinyltetrahydrocyclopenta[1,3]dioxol-4-one

(3aR,6R,6aR)-2,2-dimethyl-6-vinyltetrahydrocyclopenta[1,3]dioxol-4-one

(1R,2R)-1,2-二羟基-3-环丙烯-5-酮1,2-环己基缩酮

(1R,2R)-1,2-二羟基-3-环丙烯-5-酮1,2-环己基缩酮

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碳环肌苷

上游原料

(3S,3aS,6aR)-2-oxo-3,3a,4,6a-tetrahydro-2H-cyclopenta[b]furan-3-yl (S)-2-acetoxypropanoate (3aS,6aR)-2,2-二甲基-4,6a-二氢-3aH-环戊二烯并[d][1,3]二氧杂环戊烯-4-醇二丙酮-D-葡萄糖 ((2R,3S)-3-(benzyloxy)-2-(formyloxy)-4-hydroxy-5-nitrocyclopentyl)methyl benzoate (3aR,6R,6aR)-2,2-dimethyl-6-vinyltetrahydrocyclopenta[1,3]dioxol-4-one (1R,2R)-1,2-二羟基-3-环丙烯-5-酮1,2-环己基缩酮 ((1R,2S,3R,4S,5R)-3-(6-benzamido-9H-purin-9-yl)-4-(benzyloxy)-5-hydroxy-2-nitrocyclopentyl)methyl benzoate (1R,2S,3R,4R)-4-(acetoxymethyl)-1-[(tert-butoxycarbonyl)amino]-2,3-[(dimethylmethylene)dioxy]-cyclopentane (1R,2S,3R,4S)-2,3-isopropylidenedioxy-4-(1'-methoxycarbonyl-1'-oxomethyl)cyclopentane-1-carboxylic acid (1S,4S)-4-(hydroxymethyl)cyclopent-2-en-1-ol (+)-(1R,4S)-1-acetoxy-4-(nitromethyl)-2-cyclopentene (1S,4S)-4-(((tert-butyldiphenylsilyl)oxy)methyl)cyclopent-2-en-1-ol (3aS,4R,6R,6aR)-[6-(6-chloropurin-9-yl)-2,2-dimethyltetrahydrocyclopenta[1,3]dioxol-4-yl]methanol (3aS,4R,6R,6aR)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethyltetrahydro-4H-cyclopenta[d][1,3]dioxol-4-yl acetate (3aS,4R,6R,6aR)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethyltetrahydro-4H-cyclopenta[d][1,3]dioxol-4-ol 2-((3aR,5R,6R,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)-3-nitropropyl benzoate (1R,5R)-5-hydroxymethyl-2-cyclopenten-1-ol ((1R,4R,5R)-4-(benzyloxy)-5-(formyloxy)-2-nitrocyclopent-2-en-1-yl)methyl benzoate (1S,2S,3R,4R)-4-(tert-butoxymethyl)-2,3-(cyclohexylidenedioxy)cyclopentan-1-ol acetic acid,[(1R,5R)-5-(hydroxymethyl)cyclopent-2-en-1-yl] acetate 9-((1'R,2'S,3'R,4'R)-4-(tert-butoxymethyl)-2,3-(cyclohexylidenedioxy)cyclopentan-1-yl)adenine (1R,2S,3R,4R)-1-hydroxy-2,3-(isopropylidenedioxy)-4-(nitromethyl)cyclopentane (1R,2R,3S,4S)-1-[((tert-butyldiphenylsilyl)oxy)methyl]-4-hydroxy-2,3-(isopropylidenedioxy)cyclopentane (2R,3R,4R)-2,3-(isopropylidenedioxy)-4-(nitromethyl)cyclopentan-1-one (-)-3-(6-chloro-purin-9-yl)-5-hydroxymethyl-cyclopentane-1,2-diol 3-O-苄基-1,2:5,6-双-O-异丙亚基-alpha-D-呋喃半乳糖 (4R,5R)-1-(2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl)prop-2-en-1-ol (2R,3R,4R)-4-(tert-butoxymethyl)-2,3-(cyclohexylidenedioxy)-1-cyclopentanone 二丙酮-D-葡萄糖 9-<(1R,2S,3R)-4-t-butyldimethylsiloxymethyl-2,3-isopropylidenedioxycyclopentan-1-yl>adenine (1R,2S,3R,4R)-4-(acetoxymethyl)-2,3-[(dimethylmethylene)dioxy]-cyclopentane-1-carboxamide (2R,3R,4R)-4-(benzyloxy)-3-(formyloxy)-2-(nitromethyl)-5-oxopentyl benzoate (-)-(3Ar,6ar)-3a,6a-二氢-2,2-二甲基-4H-环戊并-1,3-二氧代-4-酮 ((1R,2S,3R,4S,5R)-3-(6-benzamido-9H-purin-9-yl)-4-(benzyloxy)-5-(formyloxy)-2-nitrocyclopentyl)methyl benzoate ((1R,2R,3S,4R)-4-(6-benzamido-9H-purin-9-yl)-3-(benzyloxy)-2-(2-ethoxyethoxy)cyclopentyl)methyl benzoate 6-chloro-9-((3aS,4R,6R,6aR)-2,2-dimethyl-6-vinyltetrahydro-4H-cyclopenta[d][1,3]dioxol-4-yl)-9H-purine (1S,2R)-2-Hydroxy-cyclopent-3-enecarbaldehyde (+/-)-(1R,4S)-1-acetoxy-4-(nitromethyl)-2-cyclopentene (1'R,2'R,3'S,4'R)-4'-(6-aminopurin-9-yl)-1'-hydroxymethyl-2',3'-O-isopropylidenecyclopentane-2',3'-diol ((1R,2R,3S,4R)-4-(6-benzamido-9H-purin-9-yl)-3-(benzyloxy)-2-hydroxycyclopentyl)methyl benzoate ((1R,2R,3S,4R)-4-(6-benzamido-9H-purin-9-yl)-2,3-dihydroxycyclopentyl)methyl acetate (1R,5S,1'S)-5-(1',2'-Dihydroxyethyl)cyclopent-2-en-1-ol (1S,2R,3R,4R)-4-(tert-butoxymethyl)-2,3-(cyclohexylidenedioxy)cyclopentan-1-ol trifluoromethanesulfonate (1α,4α)-4-(6-Amino-9H-purin-9-yl)-2-cyclopentenylcarbinol 6-O-benzoyl-3-O-benzyl-1,2-O-isopropylidene-5-oxo-D-glucofuranose ((1S,4R)-4-(6-benzamido-9H-purin-9-yl)cyclopent-2-en-1-yl)methyl acetate (3aS,4S,6R,6aR)-tetrahydro-2,2-dimethyl-6-vinyl-3aH-cyclopenta-[d][1,3]dioxo-4-ol

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