百科

tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

CAS号：191935-36-1

英文名：tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

分子式：C34H52O12

分子量：652.769

合成路线

3-ethyl 1,2-dimethyl (1S,2S,3R,4R,5R,10R,11R)-10-benzyloxy-4,5-(diethylmethylenedioxy)-1,2-(dimethylmethylenedioxy)-11-methyl-6-oxo-12-phenyl-3-(trimethylsilyloxy)dodecane-1,2,3-tricarboxylate

3-ethyl 1,2-dimethyl (1S,2S,3R,4R,5R,10R,11R)-10-benzyloxy-4,5-(diethylmethylenedioxy)-1,2-(dimethylmethylenedioxy)-11-methyl-6-oxo-12-phenyl-3-(trimethylsilyloxy)dodecane-1,2,3-tricarboxylate

tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

(2R,3R)-2-methyl-1-phenyl-hex-5-en-3-ol

(2R,3R)-2-methyl-1-phenyl-hex-5-en-3-ol

tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

tri(tert-butyl) [1S,1(4R,5R),3S,4S,5R,6R,7R]-4,6,7-trihydroxy-1-(4-hydroxy-5-methyl-6-phenylhexyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate

上游原料

(2R,3R)-2-methyl-1-phenyl-hex-5-en-3-ol 3-ethyl 1,2-dimethyl (1S,2S,3R,4R,5R,10R,11R)-10-benzyloxy-4,5-(diethylmethylenedioxy)-1,2-(dimethylmethylenedioxy)-11-methyl-6-oxo-12-phenyl-3-(trimethylsilyloxy)dodecane-1,2,3-tricarboxylate

下游产品

zaragozic acid C