百科

(2S,2aS,2bR)-2-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester

(2S,2aS,2bR)-2-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester

CAS号：194931-30-1

英文名：(2S,2aS,2bR)-2-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester

分子式：C21H33NO4SSi

分子量：423.642

合成路线

[(3S,4S)-3-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-oxo-4-((R)-4-oxo-tetrahydro-thiopyran-3-yl)-azetidin-1-yl]-oxo-acetic acid allyl ester

[(3S,4S)-3-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-oxo-4-((R)-4-oxo-tetrahydro-thiopyran-3-yl)-azetidin-1-yl]-oxo-acetic acid allyl ester

(2S,2aS,2bR)-2-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester

(2S,2aS,2bR)-2-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester

4-乙酰氧基氮杂环丁酮

4-乙酰氧基氮杂环丁酮

(2S,2aS,2bR)-2-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester

(2S,2aS,2bR)-2-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester

3-{(2S,3S)-3-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-oxo-azetidin-2-yl}-4-oxo-tetrahydro-thiopyran-3-carboxylic acid allyl ester

3-{(2S,3S)-3-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-oxo-azetidin-2-yl}-4-oxo-tetrahydro-thiopyran-3-carboxylic acid allyl ester

(2S,2aS,2bR)-2-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester

(2S,2aS,2bR)-2-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester

(3S,4S)-3-((R)-(1-(tert-butyldimethylsilyl)oxy)ethyl)-4-((3R)-4-oxotetrahydro-4H-thiopyrane-3-yl)azetidine-2-one

(3S,4S)-3-((R)-(1-(tert-butyldimethylsilyl)oxy)ethyl)-4-((3R)-4-oxotetrahydro-4H-thiopyrane-3-yl)azetidine-2-one

(2S,2aS,2bR)-2-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester

(2S,2aS,2bR)-2-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester

上游原料

3-{(2S,3S)-3-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-oxo-azetidin-2-yl}-4-oxo-tetrahydro-thiopyran-3-carboxylic acid allyl ester [(3S,4S)-3-[(R)-1-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-oxo-4-((R)-4-oxo-tetrahydro-thiopyran-3-yl)-azetidin-1-yl]-oxo-acetic acid allyl ester (3S,4S)-3-((R)-(1-(tert-butyldimethylsilyl)oxy)ethyl)-4-((3R)-4-oxotetrahydro-4H-thiopyrane-3-yl)azetidine-2-one 4-乙酰氧基氮杂环丁酮

下游产品

(2S,2aS,2bR)-2-((R)-1-Methanesulfonyloxy-ethyl)-1-oxo-2,2a,2b,3,5,6-hexahydro-1H-4-thia-7a-aza-cyclobuta[a]indene-7-carboxylic acid allyl ester