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Toluene-4-sulfonic acid 2-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-ethyl ester

Toluene-4-sulfonic acid 2-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-ethyl ester

CAS号：195316-43-9

英文名：Toluene-4-sulfonic acid 2-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-ethyl ester

分子式

C42H48O10S

熔点

密度

分子量

744.89

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

Toluene-4-sulfonic acid 2-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-ethyl ester

英文名称

Toluene-4-sulfonic acid 2-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-ethyl ester

中文别名

英文别名

CAS号

195316-43-9

分子式

C42H48O10S

分子量

744.89

精确质量

744.297

PSA

116.36

LOGP

7.614

合成路线

共找到13条合成路线 >

{(2R,3S)-3-[(2R,3S,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-oxiranyl}-methanol

{(2R,3S)-3-[(2R,3S,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-oxiranyl}-methanol

Toluene-4-sulfonic acid 2-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-ethyl ester

Toluene-4-sulfonic acid 2-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-ethyl ester

上游原料

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{(2R,3S)-3-[(2R,3S,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-oxiranyl}-methanol

{(2R,3S)-3-[(2R,3S,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-oxiranyl}-methanol

{2-[(2R,3R,4S,5R)-4-Benzyloxy-5-((4S,5S)-2,2-dimethyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-3-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-ethoxy}-tert-butyl-dimethyl-silane

{2-[(2R,3R,4S,5R)-4-Benzyloxy-5-((4S,5S)-2,2-dimethyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-3-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-ethoxy}-tert-butyl-dimethyl-silane

(E)-3-[(2S,3R,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-acrylic acid ethyl ester

(E)-3-[(2S,3R,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-acrylic acid ethyl ester

(4R,5R)-5-[(2S,3R,4S,5R)-4-Methoxymethoxy-3-triethylsilanyloxy-5-(2-trityloxy-ethyl)-tetrahydro-furan-2-yl]-2,2-dimethyl-[1,3]dioxolane-4-carbaldehyde

(4R,5R)-5-[(2S,3R,4S,5R)-4-Methoxymethoxy-3-triethylsilanyloxy-5-(2-trityloxy-ethyl)-tetrahydro-furan-2-yl]-2,2-dimethyl-[1,3]dioxolane-4-carbaldehyde

(1S,2S)-1-[(2S,3S,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-propane-1,2,3-triol

(1S,2S)-1-[(2S,3S,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-propane-1,2,3-triol

[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-Methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-acetic acid ethyl ester

[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-Methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-acetic acid ethyl ester

下游产品

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[(2R,3S,3aS,4aS,7R,8aR,9S,9aS)-3,9-Dihydroxy-2-(2-trityloxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-7-yl]-acetic acid methyl ester

[(2R,3S,3aS,4aS,7R,8aR,9S,9aS)-3,9-Dihydroxy-2-(2-trityloxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-7-yl]-acetic acid methyl ester

(E)-5-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-Methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-pent-2-enoic acid methyl ester

(E)-5-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-Methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-pent-2-enoic acid methyl ester

(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-7-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,9-bis-triethylsilanyloxy-2-(2-trityloxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran

(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-7-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,9-bis-triethylsilanyloxy-2-(2-trityloxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran

{(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-7-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,9-bis-triethylsilanyloxy-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-2-yl}-acetic acid

{(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-7-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,9-bis-triethylsilanyloxy-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-2-yl}-acetic acid

3-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-Methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-propionaldehyde

3-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-Methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-propionaldehyde

[(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-3,9-Diacetoxy-2-(2-trityloxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-7-yl]-acetic acid methyl ester

[(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-3,9-Diacetoxy-2-(2-trityloxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-7-yl]-acetic acid methyl ester

上游原料

{(2R,3S)-3-[(2R,3S,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-oxiranyl}-methanol {2-[(2R,3R,4S,5R)-4-Benzyloxy-5-((4S,5S)-2,2-dimethyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-3-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-ethoxy}-tert-butyl-dimethyl-silane (E)-3-[(2S,3R,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-acrylic acid ethyl ester (4R,5R)-5-[(2S,3R,4S,5R)-4-Methoxymethoxy-3-triethylsilanyloxy-5-(2-trityloxy-ethyl)-tetrahydro-furan-2-yl]-2,2-dimethyl-[1,3]dioxolane-4-carbaldehyde (1S,2S)-1-[(2S,3S,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-propane-1,2,3-triol [(3aS,4S,5aR,6S,7R,8aR,8bR)-6-Methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-acetic acid ethyl ester (E)-3-{(4S,5S)-5-[(2S,3R,4S,5R)-4-Methoxymethoxy-3-triethylsilanyloxy-5-(2-trityloxy-ethyl)-tetrahydro-furan-2-yl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-acrylic acid ethyl ester {(4S,5S)-5-[(2S,3R,4S,5R)-4-Methoxymethoxy-3-triethylsilanyloxy-5-(2-trityloxy-ethyl)-tetrahydro-furan-2-yl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-methanol (2R,3R,4S,5R)-4-benzyloxy-5-(1,3-dithian-2-yl)-3-hydroxy-2-trityloxymethyltetrahydrofuran (2R,3R,4R,5S)-4-benzyloxy-5-(1,3-dithian-2-yl)-3-(4-methoxybenzyloxy)-2-trityloxymethyltetrahydrofuran (1S,2S)-1-[(2S,3S,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-3-trityloxy-propane-1,2-diol (2R,3R,4S,5R)-4-Benzyloxy-2-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-5-((4S,5S)-2,2-dimethyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-tetrahydro-furan-3-ol 6-O-benzoyl-3-O-benzyl-D-glucose propylene dithioacetal {2-[(2R,3S,4R,5R)-4-Benzyloxy-5-((4S,5S)-2,2-dimethyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-3-methoxymethoxy-tetrahydro-furan-2-yl]-ethoxy}-tert-butyl-dimethyl-silane [(2R,3R,4S,5R)-4-Benzyloxy-5-((4S,5S)-2,2-dimethyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-3-(4-methoxy-benzyloxy)-tetrahydro-furan-2-ylmethoxy]-tert-butyl-diphenyl-silane (2R,3R,4R,5R)-5-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-((4S,5S)-5-hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methoxymethoxy-tetrahydro-furan-3-ol Toluene-4-sulfonic acid (2R,3R,4S,5R)-4-benzyloxy-5-((4S,5S)-2,2-dimethyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-3-(4-methoxy-benzyloxy)-tetrahydro-furan-2-ylmethyl ester 2,2-Dimethyl-propionic acid (4S,5S)-5-{(2R,3R,4R,5R)-5-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3-hydroxy-4-methoxymethoxy-tetrahydro-furan-2-yl}-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester [(2R,3R,4S,5R)-4-Benzyloxy-5-((4S,5S)-2,2-dimethyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-3-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-acetaldehyde 2-[2-(2R,3R,4S,5S)-4-benzyloxy-5-((1S,2S)-1,2-isopropylidenedioxy-3-trityloxypropyl)-3-(4-methoxybenzyloxy)tetrahydrofuranyl]acetonitrile (2S,3S,4R,5R)-3-benzyloxy-5-hydroxymethyl-2-((1S,2S)-1,2-isopropylidenedioxy-3-trityloxypropyl)-4-(4-methoxybenzyloxy)tetrahydrofuran (E)-3-[(2S,3R,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-prop-2-en-1-ol (2R,3R,4S,5R)-4-Benzyloxy-5-[1,3]dithian-2-yl-2-hydroxymethyl-tetrahydro-furan-3-ol [(2R,3R,4S,5R)-4-Benzyloxy-5-[1,3]dithian-2-yl-3-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-methanol (2R,4R,5S)-4-Benzyloxy-2-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-5-((4S,5S)-2,2-dimethyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-dihydro-furan-3-one 2,2-Dimethyl-propionic acid (4S,5S)-5-[(2R,3R,4R,5R)-3-hydroxy-4-methoxymethoxy-5-(2-trityloxy-ethyl)-tetrahydro-furan-2-yl]-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester 2,2-Dimethyl-propionic acid (4S,5S)-5-[(2S,3R,4S,5R)-4-methoxymethoxy-3-triethylsilanyloxy-5-(2-trityloxy-ethyl)-tetrahydro-furan-2-yl]-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester 2,2-Dimethyl-propionic acid (4S,5S)-5-[(2R,3R,4R,5R)-3-hydroxy-5-(2-hydroxy-ethyl)-4-methoxymethoxy-tetrahydro-furan-2-yl]-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester (S)-4-{(S)-[(2S,3S,4R,5R)-3-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-yl]-hydroxy-methyl}-[1,3]dioxolan-2-one (2R,3S,4S,5R)-4-Benzyloxy-2-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-5-((4S,5S)-2,2-dimethyl-5-trityloxymethyl-[1,3]dioxolan-4-yl)-tetrahydro-furan-3-ol (2S,3S,4R,5R)-3-benzyloxy-5-(2-hydroxyethyl)-2-((1S,2S)-1,2-isopropylidenedioxy-3-trityloxypropyl)-4-(4-methoxybenzyloxy)tetrahydrofuran [(2R,3R,4S,5R)-4-Benzyloxy-5-[1,3]dithian-2-yl-3-(4-methoxy-benzyloxy)-tetrahydro-furan-2-ylmethoxy]-tert-butyl-diphenyl-silane

下游产品

[(2R,3S,3aS,4aS,7R,8aR,9S,9aS)-3,9-Dihydroxy-2-(2-trityloxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-7-yl]-acetic acid methyl ester (E)-5-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-Methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-pent-2-enoic acid methyl ester (2R,3S,3aR,4aS,7R,8aS,9S,9aR)-7-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,9-bis-triethylsilanyloxy-2-(2-trityloxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran {(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-7-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,9-bis-triethylsilanyloxy-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-2-yl}-acetic acid 3-[(3aS,4S,5aR,6S,7R,8aR,8bR)-6-Methoxymethoxy-2,2-dimethyl-7-(2-trityloxy-ethyl)-hexahydro-[1,3]dioxolo[4,5]furo[2,3-b]pyran-4-yl]-propionaldehyde [(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-3,9-Diacetoxy-2-(2-trityloxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-7-yl]-acetic acid methyl ester [(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-3,9-Diacetoxy-2-(2-hydroxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-7-yl]-acetic acid methyl ester [(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-3,9-Diacetoxy-2-(2-oxo-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-7-yl]-acetic acid methyl ester 2-{(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-7-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,9-bis-triethylsilanyloxy-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-2-yl}-ethanol (2R,3S,3aS,4aS,7R,8aR,9S,9aS)-7-(2-Hydroxy-ethyl)-2-(2-trityloxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-3,9-diol (2R,3S,3aS,4aS,7R,8aR,9S,9aS)-7-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-2-(2-trityloxy-ethyl)-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-3,9-diol (E)-5-[(2R,3S,3aS,5S,6R,7S,7aS)-3,6,7-Trihydroxy-2-(2-hydroxy-ethyl)-hexahydro-furo[3,2-b]pyran-5-yl]-pent-2-enoic acid methyl ester {(2R,3S,3aR,4aS,7R,8aS,9S,9aR)-7-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-3,9-bis-triethylsilanyloxy-decahydro-furo[3,2-b]pyrano[2,3-e]pyran-2-yl}-acetic acid methyl ester