百科

(4R,5S,10R,11S,15S)-(2E,8E)-15-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid tert-butyl ester

(4R,5S,10R,11S,15S)-(2E,8E)-15-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid tert-butyl ester

CAS号：196926-56-4

英文名：(4R,5S,10R,11S,15S)-(2E,8E)-15-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid tert-butyl ester

分子式：C34H62O13Si

分子量：706.934

合成路线

(4R,5S,10R,11S)-(2E,8E)-11-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester

(4R,5S,10R,11S)-(2E,8E)-11-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester

(S)-3-[(tert-butyldimethylsilyl)oxy]butyric acid

(S)-3-[(tert-butyldimethylsilyl)oxy]butyric acid

(4R,5S,10R,11S,15S)-(2E,8E)-15-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid tert-butyl ester

(4R,5S,10R,11S,15S)-(2E,8E)-15-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid tert-butyl ester

(4R,5S)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-(β-methoxyethoxy)methoxy-2-hexenoic acid

(4R,5S)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-(β-methoxyethoxy)methoxy-2-hexenoic acid

(4R,5S,10R,11S,15S)-(2E,8E)-15-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid tert-butyl ester

(4R,5S,10R,11S,15S)-(2E,8E)-15-(tert-butyl(dimethyl)silyloxy)-4,10-bis[(2-methoxyethoxy)methoxy]-5,11-dimethyl-6,12-dioxa-1,7,13-trioxo-2,8-hexadecadienoic acid tert-butyl ester

上游原料

(4R,5S,10R,11S)-(2E,8E)-11-hydroxy-4,10-bis[(2-methoxyethoxy)methoxy]-5-methyl-6-oxa-1,7-dioxo-2,8-dodecadienoic acid tert-butyl ester (S)-3-[(tert-butyldimethylsilyl)oxy]butyric acid (4R,5S)-(E)-5-(t-butyl(dimethyl)silyloxy)-4-(β-methoxyethoxy)methoxy-2-hexenoic acid

下游产品

(4S,9R,10S,15R,16S)-9,15-dihydroxy-4,10,16-trimethyl-1,5,11-trioxacyclohexadeca-7,13-diene-2,6,12-trione (5R,6S,11R,12S,16S)-(3E,9E)-5,11-bis[(2-methoxyethoxy)methyl]-6,12,16-trimethyl-1,7,13-trioxacyclohexadeca-3,9-diene-2,8,14-trione